(a)
Interpretation:
The stabilizing interactions between DMSO solvent molecules and a dissolved sodium ion are to be shown.
Concept introduction:
The dipole moment is defined as the charge separation between two atoms in a covalent bond or between two ions in an ionic bond. It is used to determine the polarity of atoms or ions. If the value of dipole moment is zero, then the molecule is said to be non-polar, and if the value of dipole moment is not zero, then the molecule is said to be polar and possess permanent dipole moment.
The solvent dimethyl sulfoxide (DMSO) is polar aprotic in nature. In the solution when an ionic compound is dissolved, this polar solvent shows charge-dipole interactions and donor interactions with it.
(b)
Interpretation:
The stabilizing interactions between DMSO solvent molecules and dissolved water are to be shown.
Concept introduction:
The dipole moment is defined as the charge separation between two atoms in a covalent bond or between two ions in an ionic bond. It is used to determine the polarity of atoms or ions. If the value of dipole moment is zero, then the molecule is said to be non-polar, and if the value of dipole moment is not zero, then the molecule is said to be polar and possess permanent dipole moment.
The solvent dimethyl sulfoxide (DMSO) is polar aprotic in nature. In the solution when an ionic compound is dissolved, this polar solvent shows charge-dipole interactions and donor interactions with it.
(c)
Interpretation:
The stabilizing interactions between DMSO solvent molecules and a dissolved chloride ion are to be shown.
Concept introduction:
The dipole moment is defined as the charge separation between two atoms in a covalent bond or between two ions in an ionic bond. It is used to determine the polarity of atoms or ions. If the value of dipole moment is zero, then the molecule is said to be non-polar, and if the value of dipole moment is not zero, then the molecule is said to be polar and possess permanent dipole moment.
The solvent dimethyl sulfoxide (DMSO) is polar aprotic in nature. In the solution when an ionic compound is dissolved, this polar solvent shows charge-dipole interactions and donor interactions with it.
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Chapter 8 Solutions
Organic Chemistry
- CH3O OH OH O hemiacetal O acetal O neither O 0 O hemiacetal acetal neither OH hemiacetal O acetal O neither CH2 O-CH2-CH3 CH3-C-OH O hemiacetal O acetal CH3-CH2-CH2-0-c-O-CH2-CH2-CH3 O neither HO-CH2 ? 000 Ar Barrow_forwardWhat would be the best choices for the missing reagents 1 and 3 in this synthesis? 1. PPh3 2 2. n-BuLi 3 Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Explanation Check Click and drag to start drawing a structure.arrow_forwardPredict the products of this organic reaction: NaBH3CN + NH2 ? H+ Click and drag to start drawing a structure. ×arrow_forward
- Predict the organic products that form in the reaction below: + OH +H H+ ➤ ☑ X - Y Note: You may assume you have an excess of either reactant if the reaction requires more than one of those molecules to form the products. In the drawing area below, draw the skeletal ("line") structures of the missing organic products X and Y. You may draw the structures in any arrangement that you like, so long as they aren't touching. Click and drag to start drawing a structure. Garrow_forwardPredict the organic products that form in the reaction below: OH H+ H+ + ☑ Y Note: You may assume you have an excess of either reactant if the reaction requires more than one of those molecules to form the products. In the drawing area below, draw the skeletal ("line") structures of the missing organic products X and Y. You may draw the structures in any arrangement that you like, so long as they aren't touching. Click and drag to start drawing a structure. ✓ marrow_forwardDetermine the structures of the missing organic molecules in the following reaction: + H₂O +H H+ Y Z ☑ ☑ Note: Molecules that share the same letter have the exact same structure. In the drawing area below, draw the skeletal ("line") structures of the missing organic molecules X, Y, and Z. You may draw the structures in any arrangement that you like, so long as they aren't touching. Molecule X shows up in multiple steps, but you only have to draw its structure once. Click and drag to start drawing a structure. AP +arrow_forward
- Please help, this is all the calculations i got!!! I will rate!!!Approx mass of KMnO in vial: 3.464 4 Moss of beaker 3×~0. z Nax200: = 29.9219 Massof weacerv after remosimgain N2C2O4. Need to fill in all the missing blanks. ง ง Approx mass of KMnO4 in vials 3.464 Mass of beaker + 3x ~0-304: 29.9219 2~0.20 Miss of beaker + 2x- 29.7239 Mass of beaker + 1x~0.2g Naz (204 29-5249 Mass of beaver after removing as qa Na₂ C₂O T1 T2 T3 Final Buiet reading Initial butet reading (int)) Hass of NaOr used for Titration -reading (mL) calculation Results: 8.5ml 17mL 27.4mL Oml Om Oml T1 T2 T3 Moles of No CO Moles of KMO used LOF KM. O used Molenty of KMNO Averagem Of KMOWLarrow_forwardDraw the skeletal ("line") structure of 2-hydroxy-4-methylpentanal. Click and drag to start drawing a structure. Xarrow_forwardDetermine whether the following molecule is a hemiacetal, acetal, or neither and select the appropriate box below. Also, highlight the hemiacetal or acetal carbon if there is one. hemiacetal acetal Oneither OHarrow_forward
- What is the missing reactant R in this organic reaction? ་ ་ ་ ་ ་ ་ ་ ་ ་ ་ +R H3O+ • Draw the structure of R in the drawing area below. N • Be sure to use wedge and dash bonds if it's necessary to draw one particular enantiomer. Click and drag to start drawing a structure.arrow_forwardWrite the systematic name of each organic molecule: H structure H OH OH H OH name ☐ OHarrow_forwardDetermine whether each of the following molecules is a hemiacetal, acetal, or neither and select the appropriate box in the table. CH3O OH OH OH hemiacetal acetal neither hemiacetal acetal neither Xarrow_forward
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