Concept explainers
(a)
Interpretation:
To identify the given compound as primary, secondary or tertiary alkyl halide and give a common name to the given compound.
Concept introduction:
Alkyl halide refers to those organic compounds that consist of halogen atom as a
In primary alkyl halide, the halogen group is attached to a carbon atom that is connected to two hydrogen atoms and the other carbon atom.
In secondary alkyl halide, the halogen group is attached to a carbon atom that is connected to two carbon atoms and one hydrogen atom.
In tertiary alkyl halide, the halogen group is attached to a carbon atom that is connected to three carbon atoms.
Answer to Problem 8.1P
The common name of the given compound is isobutyl fluoride. It is a primary alkyl halide.
Explanation of Solution
The given compound is
The fluorine atom is attached to a carbon atom that is connected to two hydrogen atoms and the other carbon atom. Therefore, it is a primary alkyl halide.
The common name of the given compound is isobutyl fluoride. It is a primary alkyl halide.
(b)
Interpretation:
To identify the given compound as primary, secondary or tertiary alkyl halide and give a common name to the given compound.
Concept introduction:
Alkyl halide refers to those organic compounds that consist of halogen atom as a functional group attached to the alkyl chain. The general formula is
In primary alkyl halide, the halogen group is attached to a carbon atom that is connected to two hydrogen atoms and the other carbon atom.
In secondary alkyl halide, the halogen group is attached to a carbon atom that is connected to two carbon atoms and one hydrogen atom.
In tertiary alkyl halide, the halogen group is attached to a carbon atom that is connected to three carbon atoms.
Answer to Problem 8.1P
The common name of the given compound is n-hexyl iodide. It is a primary alkyl halide.
Explanation of Solution
The given compound is
The iodine atom is attached to a carbon atom that is connected to two hydrogen atoms and the other carbon atom. Therefore, it is a primary alkyl halide.
The common name of the given compound is n-hexyl iodide. It is a primary alkyl halide.
(c)
Interpretation:
To identify the given compound as primary, secondary or tertiary alkyl halide and give a common name to the given compound.
Concept introduction:
Alkyl halide refers to those organic compounds that consist of halogen atom as a functional group attached to the alkyl chain. The general formula is
In primary alkyl halide, the halogen group is attached to a carbon atom that is connected to two hydrogen atoms and the other carbon atom.
In secondary alkyl halide, the halogen group is attached to a carbon atom that is connected to two carbon atoms and one hydrogen atom.
In tertiary alkyl halide, the halogen group is attached to a carbon atom that is connected to three carbon atoms.
Answer to Problem 8.1P
The common name of the given compound is cyclopentyl bromide. It is a secondary alkyl halide.
Explanation of Solution
The given compound is shown below.
Figure 1
It contains a ring of five carbon atoms. Bromine is attached to the second carbon atom. Therefore, the common name of this compound is cyclopentyl bromide.
The bromine atom is attached to a carbon atom that is connected to two carbon atoms and one hydrogen atom. Therefore, it is a secondary alkyl halide.
The common name of the given compound is cyclopentyl bromide. It is a secondary alkyl halide.
(d)
Interpretation:
To identify the given compound as primary, secondary or tertiary alkyl halide and give a common name to the given compound.
Concept introduction:
Alkyl halide refers to those organic compounds that consist of halogen atom as a functional group attached to the alkyl chain. The general formula is
In primary alkyl halide, the halogen group is attached to a carbon atom that is connected to two hydrogen atoms and the other carbon atom.
In secondary alkyl halide, the halogen group is attached to a carbon atom that is connected to two carbon atoms and one hydrogen atom.
In tertiary alkyl halide, the halogen group is attached to a carbon atom that is connected to three carbon atoms.
Answer to Problem 8.1P
The common name of the given compound is neopentyl chloride. It is a primary alkyl halide.
Explanation of Solution
The given compound is shown below.
Figure 2
It contains five carbon atoms. Chlorine is attached to the first carbon atom and three methyl groups are attached to the second carbon atom. Therefore, the prefix –neo is used before the name of an alkyl halide. Therefore, the common name of this compound is neopentyl chloride.
The chloride atom is attached to a carbon atom that is connected to two hydrogen atoms and the other carbon atom. Therefore, it is a primary alkyl halide.
The common name of the given compound is neopentyl chloride. It is a primary alkyl halide.
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Chapter 8 Solutions
Organic Chemistry
- Write the reagent or draw structures of the starting material or organic product(s) in the following reactions. If more than one product is formed, identify the major product where possible. (a) (b) HO OH OH H2SO4 ? Cl₂ ? FeCl3arrow_forwardName and draw structural formulas for the two possible products of each alkene addition reaction. Use Markovnikov's rule to predict which is the major product.arrow_forwardWrite the bond line formula of the following compounds: (a) 4-methyl-2-hexene, two geometrical (stereoisomers) isomers (b) 3-fluoro-2-methylheptanol (3-fluoro-2-methylheptan-1-ol) (c) 4-methyl-hex-1-yn-3-olarrow_forward
- (b) Draw structural formulas of at least two alkynes of each molecular formula.(1) C6H10arrow_forwardGive the systematic (IUPAC) names of the following alkenes. (а) СH— CH— CH— CH(CH3)2 (b) CH3(CH2)3¬C-CH2CH3 CH2 (c) CH2=CH-CH,–CH=CH2 (d) CH, —С—CH—CH—СH, CH3 (е) (f) (g) CH3 CH2 CH3 (h) .CH3 (j)arrow_forwardIdentify which of the following statement(s) is/are true. (f) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group. (g) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid. (h) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°. (i) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O. (j) The molecular formula of the smallest carboxylic acid is C2H4O2.arrow_forward
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- Which of the following alkenes can exist as cis-trans isomers? Write their structures. (a) CH2=CHCH2CH3 (c) CH2=C(CH3)2 (b) CH3CH=CHCH3 (d) CH3CH2CH=CHCIarrow_forward[10] 10] Q1. Do the following conversions as directed. Write the complete reaction equation. (a) Benzaldehyde to Benzoic Acid. (b) Propanal to 1-propanal (c) Cyclohexanone to Cyclohexanol (d) Acetaldehyde to Ethyl alcohol (e) Acetone to Iso-propyl alcoholarrow_forward10) 11)arrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning