EBK CHEMISTRY
4th Edition
ISBN: 8220102797864
Author: Burdge
Publisher: YUZU
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Chapter 8, Problem 73QP
Write a Lewis structure for
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Write Lewis structures for molecule or ion. Use expanded octets as necessary. PF5
Write the Lewis structure for H3PO4. If necessary, expand the octet on any appropriate atoms to lower formal charge.
Oxygen gas reacts with sulfur tetrafluoride to slowly form sulfur tetrafluoride monoxide gas.
Balance the equation for the formation of sulfur tetrafluoride monoxide.
chemical reaction:
0,(g) + SF (g) → OSF,(g)
Draw the Lewis structure of OSF, where the formal charge is zero on each atom. The sulfur atom is the central atom in the
structure, and it is bonded to the oxygen atom and each of the four fluorine atoms.
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Use the bond energies in the table to estimate the enthalpy of reaction for the formation of sulfur tetrafluoride monoxide.
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Chapter 8 Solutions
EBK CHEMISTRY
Ch. 8.1 - Practice ProblemATTEMPT Write Lewis dot symbols...Ch. 8.1 - Practice Problem BUILD
Indicate the charge on...Ch. 8.1 - Practice ProblemCONCEPTUALIZE For each of the...Ch. 8.1 - 8.1.1 Using only a periodic table, determine the...Ch. 8.1 - 8.1.2 Using only a periodic table, determine the...Ch. 8.1 - To which group does element X belong if its Lewis...Ch. 8.1 - Prob. 4CPCh. 8.2 - Prob. 1PPACh. 8.2 - Practice ProblemBUILD Arrange the compounds NaF,...Ch. 8.2 - Practice ProblemCONCEPTUALIZE Common ions of four...
Ch. 8.2 - 8.2.1 Will the lattice energy of KF be larger or...Ch. 8.2 - 8.2.2 Using the following data, calculate the...Ch. 8.2 - 8.2.3 Lattice energies are graphed for three...Ch. 8.3 - Practice ProblemATTEMPT Using data from Figures...Ch. 8.3 - Prob. 1PPBCh. 8.3 - Prob. 1PPCCh. 8.4 - Practice Problem ATTEMPT Classify the following...Ch. 8.4 - Prob. 1PPBCh. 8.4 - Prob. 1PPCCh. 8.4 - In which of the following molecules are the bonds...Ch. 8.4 - Using data from Table 8.5, calculate the magnitude...Ch. 8.4 - Prob. 3CPCh. 8.4 - Prob. 4CPCh. 8.5 - Prob. 1PPACh. 8.5 - Prob. 1PPBCh. 8.5 - Prob. 1PPCCh. 8.5 - Identify the correct Lewis structure for formic...Ch. 8.5 - Identity the correct Lewis structure for hydrogen...Ch. 8.6 - Prob. 1PPACh. 8.6 - Prob. 1PPBCh. 8.6 - Prob. 1PPCCh. 8.6 - Determine the formal charges on H, C, and N,...Ch. 8.6 - 8.6.2 Which of the Lewis structures shown is most...Ch. 8.7 - Prob. 1PPACh. 8.7 - Practice ProblemBUILD Draw the Lewis structure for...Ch. 8.7 - Practice Problem CONCEPTUALIZE
Of the three Lewis...Ch. 8.7 - Indicate which of the following are resonance...Ch. 8.7 - 8.7.2 How many resonance structures can be drawn...Ch. 8.8 - Prob. 1PPACh. 8.8 - Prob. 1PPBCh. 8.8 - Practice Problem CONCEPTUALIZE
The hypothetical...Ch. 8.8 - In which of the following species does the central...Ch. 8.8 - Prob. 2CPCh. 8.8 - In which species does the central atom obey the...Ch. 8.8 - 8.8.4 How many lone pairs are there on the central...Ch. 8.9 - Prob. 1PPACh. 8.9 - Practice ProblemBUILD Use Lewis structures and...Ch. 8.9 - Prob. 1PPCCh. 8.9 - 8.9.1 Use data from Table 8.6 to estimate for the...Ch. 8.9 - Use data from Table 8.6 to estimate Δ H rxn for...Ch. 8.9 - Use bond enthalpies to determine Δ H rxn for the...Ch. 8.9 - Prob. 4CPCh. 8.10 - Practice ProblemATTEMPT Draw all possible...Ch. 8.10 - Prob. 1PPBCh. 8.10 - Practice ProblemCONCEPTUALIZE The Lewis structure...Ch. 8.11 - Prob. 1PPACh. 8.11 - Prob. 1PPBCh. 8.11 - Prob. 1PPCCh. 8.12 - Prob. 1PPACh. 8.12 - Prob. 1PPBCh. 8.12 - Prob. 1PPCCh. 8.13 - Prob. 1PPACh. 8.13 - Practice Problem BUILD
Using the following...Ch. 8.13 - Prob. 1PPCCh. 8 - 8.1
Which of the following atoms must always obey...Ch. 8 - Prob. 2KSPCh. 8 - Prob. 3KSPCh. 8 - Prob. 4KSPCh. 8 - What is a Lewis dot symbol? What elements do we...Ch. 8 - Use the second member of each group from Group 1A...Ch. 8 - Prob. 3QPCh. 8 - 8.4 Write Lewis dot symbols for the following...Ch. 8 - Write Lewis dot symbols for the following atoms...Ch. 8 - Prob. 6QPCh. 8 - Prob. 7QPCh. 8 - Name five metals and five nonmetals that are very...Ch. 8 - Prob. 9QPCh. 8 - Prob. 10QPCh. 8 - Prob. 11QPCh. 8 - The term molar mass was introduced in Chapter 3....Ch. 8 - Prob. 13QPCh. 8 - Prob. 14QPCh. 8 - Prob. 15QPCh. 8 - Explain how the lattice energy of an ionic...Ch. 8 - Prob. 17QPCh. 8 - Prob. 18QPCh. 8 - 8.19 Use the Born-Haber cycle outlined in Section...Ch. 8 - Calculate the lattice energy of CaCl 2 . Use data...Ch. 8 - An ionic bond is formed between a cation A + and...Ch. 8 - Prob. 22QPCh. 8 - Use Lewis dot symbols to show the transfer of...Ch. 8 - Write the Lewis dot symbols of the reactants and...Ch. 8 - 8.25 Describe Lewis’s contribution to our...Ch. 8 - Prob. 26QPCh. 8 - Prob. 27QPCh. 8 - Prob. 28QPCh. 8 - Prob. 29QPCh. 8 - Prob. 30QPCh. 8 - Prob. 31QPCh. 8 - Prob. 32QPCh. 8 - Prob. 33QPCh. 8 - Define electronegativity, and explain the...Ch. 8 - Prob. 35QPCh. 8 - Prob. 36QPCh. 8 - Prob. 37QPCh. 8 - Using information in Table 8.5. calculate the...Ch. 8 - List the following bonds in order of increasing...Ch. 8 - Classify the following bonds as covalent, polar...Ch. 8 - 8.41 Classify the following bonds as covalent,...Ch. 8 - 8.42 List the following bonds in order of...Ch. 8 - Prob. 43QPCh. 8 - Prob. 44QPCh. 8 - Prob. 45QPCh. 8 - Prob. 46QPCh. 8 - Draw Lewis structures for the following molecules...Ch. 8 - Draw Lewis structures for the following molecules:...Ch. 8 - Prob. 49QPCh. 8 - Prob. 50QPCh. 8 - 8.51 Draw Lewis structures for the following ions:...Ch. 8 - Draw Lewis structures for the following ions: (a)...Ch. 8 - Prob. 53QPCh. 8 - Prob. 54QPCh. 8 - Prob. 55QPCh. 8 - Prob. 56QPCh. 8 - Prob. 57QPCh. 8 - 8.58 Draw three resonance structures for the...Ch. 8 - Prob. 59QPCh. 8 - Prob. 60QPCh. 8 - Draw three reasonable resonance structures for the...Ch. 8 - Draw three resonance structures for the molecule N...Ch. 8 - Prob. 63QPCh. 8 - Prob. 64QPCh. 8 - Prob. 65QPCh. 8 - Prob. 66QPCh. 8 - Prob. 67QPCh. 8 - Prob. 68QPCh. 8 - Prob. 69QPCh. 8 - The AlI 3 molecule has an incomplete octet around...Ch. 8 - Prob. 71QPCh. 8 - Prob. 72QPCh. 8 - 8.73 Write a Lewis structure for Does this...Ch. 8 - Prob. 74QPCh. 8 - Prob. 75QPCh. 8 - 8.76 Draw two resonance structures for the bromate...Ch. 8 - Prob. 77QPCh. 8 - What is bond enthalpy? Bond enthalpies of...Ch. 8 - Prob. 79QPCh. 8 - Prob. 80QPCh. 8 - Prob. 81QPCh. 8 - Prob. 82QPCh. 8 - For the reaction 2 C 2 H 6 ( g ) + 7 O 2 ( g ) → 4...Ch. 8 - Prob. 84QPCh. 8 - 8.85. Use average bond enthalpies from Table 8.6...Ch. 8 - Prob. 86APCh. 8 - Prob. 87APCh. 8 - Prob. 88APCh. 8 - Prob. 89APCh. 8 - Prob. 90APCh. 8 - 8.91 Describe some characteristics of an ionic...Ch. 8 - Prob. 92APCh. 8 - Prob. 93APCh. 8 - Prob. 94APCh. 8 - Prob. 95APCh. 8 - Prob. 96APCh. 8 - Prob. 97APCh. 8 - Prob. 98APCh. 8 - Prob. 99APCh. 8 - Prob. 100APCh. 8 - Prob. 101APCh. 8 - Prob. 102APCh. 8 - Prob. 103APCh. 8 - Prob. 104APCh. 8 - Which of the following species are isoelectronic:...Ch. 8 - Prob. 106APCh. 8 - 8.107 Draw two resonance structures for each...Ch. 8 - The following species have been detected in...Ch. 8 - The amide ion ( NH 2 − ) is a Brø�nsted base. Use...Ch. 8 - Prob. 110QPCh. 8 - The triiodide ion ( I 3 − ) in which the I atoms...Ch. 8 - Prob. 112APCh. 8 - In 1999, an unusual cation containing only...Ch. 8 - Prob. 114APCh. 8 - Prob. 115APCh. 8 - Prob. 116APCh. 8 - In the gas phase, aluminum chloride exists as a...Ch. 8 - Prob. 118APCh. 8 - Calculate Δ H º for the reaction H 2 ( g ) + I 2 (...Ch. 8 - Draw Lewis structures for the following organic...Ch. 8 - Prob. 121APCh. 8 - Prob. 122APCh. 8 - Prob. 123APCh. 8 - Write three resonance structures for (a) the...Ch. 8 - Prob. 125APCh. 8 - Prob. 126APCh. 8 - Prob. 127APCh. 8 - Prob. 128APCh. 8 - Prob. 129APCh. 8 - Prob. 130APCh. 8 - Prob. 131APCh. 8 - Among the common inhaled anesthetics are:...Ch. 8 - Prob. 133QPCh. 8 - Prob. 134QPCh. 8 - Prob. 135QPCh. 8 - 8.136 Using this and data from Appendix 2,...Ch. 8 - Prob. 137QPCh. 8 - Prob. 138APCh. 8 - Prob. 139APCh. 8 - Prob. 140APCh. 8 - Prob. 141APCh. 8 - Prob. 142APCh. 8 - Prob. 143APCh. 8 - Although nitrogen dioxide ( NO 2 ) is a stable...Ch. 8 - 8.145 The chlorine nitrate molecule is believed...Ch. 8 - The hydroxyl radical ( OH ) plays an important...Ch. 8 - Prob. 147APCh. 8 - Prob. 148APCh. 8 - Prob. 1SEPPCh. 8 - 2. Use formal charges to choose the best of the...Ch. 8 - Prob. 3SEPPCh. 8 - Prob. 4SEPP
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- Bond Enthalpy When atoms of the hypothetical element X are placed together, they rapidly undergo reaction to form the X2 molecule: X(g)+X(g)X2(g) a Would you predict that this reaction is exothermic or endothermic? Explain. b Is the bond enthalpy of X2 a positive or a negative quantity? Why? c Suppose H for the reaction is 500 kJ/mol. Estimate the bond enthalpy of the X2 molecule. d Another hypothetical molecular compound, Y2(g), has a bond enthalpy of 750 kJ/mol, and the molecular compound XY(g) has a bond enthalpy of 1500 kJ/mol. Using bond enthalpy information, calculate H for the following reaction. X2(g)+Y2(g)2XY(g) e Given the following information, as well as the information previously presented, predict whether or not the hypothetical ionic compound AX is likely to form. In this compound, A forms the A+ cation, and X forms the X anion. Be sure to justify your answer. Reaction: A(g)+12X2(g)AX(s)The first ionization energy of A(g) is 400 kJ/mol. The electron affinity of X(g) is 525 kJ/mol. The lattice energy of AX(s) is 100 kJ/mol. f If you predicted that no ionic compound would form from the reaction in Part e, what minimum amount of AX(s) lattice energy might lead to compound formation?arrow_forwardWrite the Lewis structure for nitrosyl fluoride, FNO. Using only a periodic table, identify (a) which is the longer bond. (b) which is the stronger bond. (c) which is the more polar bond.arrow_forwardConsider the pyrosulfate ion, S2O72-. It has no sulfur–sulfur nor oxygen–oxygen bonds. (a) Write a Lewis structure for the pyrosulfate ion using only single bonds. (b) What is the formal charge on the sulfur atoms for the Lewis structure you drew in part (a)? (c) Write another Lewis structure using six bonds and two O—S bonds. (d) What is the formal charge on each atom for the structure you drew in part (c)?arrow_forward
- Write all resonance structures of chlorobenzene, C6H5Cl, a molecule with the same cyclic structure as benzene. In all structures, keep the CCl bond as a single bond. Which resonance structures are the most important?arrow_forwardDraw Lewis structures for the following species. (The skeleton is indicated by the way the molecule is written.) (a) Cl2CO (b) H3C—CN (c) H2C—CH2arrow_forwardNitrosyl azide, N4O, is a pale yellow solid first synthesized in 1993. Write the Lewis structure for nitrosyl azide.arrow_forward
- In which of the following molecules does the sulfur have an expanded octet? For those that do, write the Lewis structure. (a) SO2 (b) SF4 (c) SO2Cl2 (d) SF6arrow_forwardExperimental evidence indicates the existence of HC3N molecules in interstellar clouds. Write a plausible Lewis structure for this molecule.arrow_forwardDraw Lewis structures for the following species. (The skeleton is indicated by the way the molecule is written.) (a) Cl2CO (b) H3CCNarrow_forward
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