EBK CHEMISTRY: AN ATOMS FIRST APPROACH
2nd Edition
ISBN: 8220100552236
Author: ZUMDAHL
Publisher: CENGAGE L
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Chapter 8, Problem 39E
A sealed-tube manometer (as shown below) can be used to measure pressures below atmospheric pressure. The tube above the mercury is evacuated. When there is a vacuum in the flask, the mercury levels in both arms of the U-tube are equal. If a gaseous sample is introduced into the flask, the mercury levels are different. The difference h is a measure of the pressure of the gas inside the flask. If h is equal to 6.5 cm, calcúlate the pressure in the flask in torr, pascals, and atmospheres.
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each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that:
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
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HỌC—C—0—CH, CH,
2
A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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OA
B
OC
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 8 Solutions
EBK CHEMISTRY: AN ATOMS FIRST APPROACH
Ch. 8 - Prob. 1RQCh. 8 - Prob. 2RQCh. 8 - Prob. 3RQCh. 8 - Prob. 4RQCh. 8 - Prob. 5RQCh. 8 - Prob. 6RQCh. 8 - Prob. 7RQCh. 8 - Prob. 8RQCh. 8 - Prob. 9RQCh. 8 - Why do real gases not always behave ideally? Under...
Ch. 8 - Prob. 3ALQCh. 8 - Prob. 4ALQCh. 8 - Prob. 6ALQCh. 8 - Prob. 8ALQCh. 8 - Prob. 11ALQCh. 8 - Prob. 12ALQCh. 8 - Prob. 15ALQCh. 8 - Prob. 16ALQCh. 8 - Draw molecular-level views that show the...Ch. 8 - Prob. 20QCh. 8 - Prob. 21QCh. 8 - Prob. 22QCh. 8 - Prob. 23QCh. 8 - Prob. 24QCh. 8 - Prob. 25QCh. 8 - Consider two different containers, each filled...Ch. 8 - Prob. 27QCh. 8 - Prob. 28QCh. 8 - Prob. 29QCh. 8 - Prob. 30QCh. 8 - Prob. 31QCh. 8 - Prob. 32QCh. 8 - Prob. 33QCh. 8 - Prob. 34QCh. 8 - Prob. 35QCh. 8 - Prob. 36QCh. 8 - Prob. 37ECh. 8 - Prob. 38ECh. 8 - A sealed-tube manometer (as shown below) can be...Ch. 8 - Prob. 40ECh. 8 - A diagram for an open-tube manometer is shown...Ch. 8 - Prob. 42ECh. 8 - Prob. 43ECh. 8 - Prob. 44ECh. 8 - Prob. 45ECh. 8 - Prob. 46ECh. 8 - Prob. 47ECh. 8 - Prob. 48ECh. 8 - Prob. 49ECh. 8 - Prob. 50ECh. 8 - The Steel reaction vessel of a bomb calorimeter,...Ch. 8 - A 5.0-L flask contains 0.60 g O2 at a temperature...Ch. 8 - Prob. 53ECh. 8 - A person accidentally swallows a drop of liquid...Ch. 8 - A gas sample containing 1.50 moles at 25C exerts a...Ch. 8 - Prob. 56ECh. 8 - Prob. 57ECh. 8 - What will be the effect on the volume of an ideal...Ch. 8 - Prob. 59ECh. 8 - Prob. 60ECh. 8 - An ideal gas is contained in a cylinder with a...Ch. 8 - Prob. 62ECh. 8 - A sealed balloon is filled with 1.00 L helium at...Ch. 8 - Prob. 64ECh. 8 - Consider the following reaction:...Ch. 8 - A student adds 4.00 g of dry ice (solid CO2) to an...Ch. 8 - Air bags are activated when a severe impact causes...Ch. 8 - Concentrated hydrogen peroxide solutions are...Ch. 8 - In 1897 the Swedish explorer Andre tried to reach...Ch. 8 - Sulfur trioxide, SO3, is produced in enormous...Ch. 8 - A 15.0-L rigid container was charged with 0.500...Ch. 8 - An important process for the production of...Ch. 8 - Consider the reaction between 50.0 mL liquid...Ch. 8 - Urea (H2NCONH2) is used extensively as a nitrogen...Ch. 8 - Prob. 75ECh. 8 - Prob. 76ECh. 8 - Prob. 77ECh. 8 - A compound has the empirical formula CHCl. A...Ch. 8 - Prob. 79ECh. 8 - Given that a sample of air is made up of nitrogen,...Ch. 8 - Prob. 81ECh. 8 - Prob. 82ECh. 8 - Prob. 83ECh. 8 - Prob. 84ECh. 8 - Consider the flasks in the following diagram. What...Ch. 8 - Consider the flask apparatus in Exercise 85, which...Ch. 8 - Prob. 87ECh. 8 - At 0C a 1.0-L flask contains 5.0 102 mole of N2,...Ch. 8 - Prob. 89ECh. 8 - A tank contains a mixture of 52.5 g oxygen gas and...Ch. 8 - Prob. 91ECh. 8 - Helium is collected over water at 25C and 1.00 atm...Ch. 8 - At elevated temperatures, sodium chlorate...Ch. 8 - Xenon and fluorine will react to form binary...Ch. 8 - Methanol (CH3OH) can be produced by the following...Ch. 8 - In the Mthode Champenoise, grape juice is...Ch. 8 - Hydrogen azide, HN3, decomposes on heating by the...Ch. 8 - Prob. 98ECh. 8 - Some very effective rocket fuels are composed of...Ch. 8 - The oxides of Group 2A metals (symbolized by M...Ch. 8 - Prob. 101ECh. 8 - Prob. 102ECh. 8 - Prob. 103ECh. 8 - Prob. 104ECh. 8 - Prob. 105ECh. 8 - Prob. 106ECh. 8 - Prob. 107ECh. 8 - Prob. 108ECh. 8 - Prob. 109ECh. 8 - Prob. 110ECh. 8 - Prob. 111ECh. 8 - Prob. 112ECh. 8 - Prob. 113ECh. 8 - Prob. 114ECh. 8 - Prob. 115ECh. 8 - Prob. 116ECh. 8 - Prob. 117ECh. 8 - Prob. 118ECh. 8 - Prob. 119ECh. 8 - Prob. 120ECh. 8 - Prob. 121ECh. 8 - Prob. 122ECh. 8 - Prob. 123AECh. 8 - At STP, 1.0 L Br2 reacts completely with 3.0 L F2,...Ch. 8 - Prob. 125AECh. 8 - A 2.747g sample of manganese metal is reacted with...Ch. 8 - Prob. 127AECh. 8 - Cyclopropane, a gas that when mixed with oxygen is...Ch. 8 - The nitrogen content of organic compounds can be...Ch. 8 - Prob. 130AECh. 8 - A 15.0L tank is filled with H2 to a pressure of...Ch. 8 - A spherical glass container of unknown volume...Ch. 8 - Prob. 133AECh. 8 - A 20.0L stainless steel container at 25C was...Ch. 8 - Metallic molybdenum can be produced from the...Ch. 8 - Prob. 136AECh. 8 - Prob. 137AECh. 8 - One of the chemical controversies of the...Ch. 8 - An organic compound contains C, H, N, and O....Ch. 8 - Prob. 140AECh. 8 - The total volume of hydrogen gas needed to fill...Ch. 8 - Prob. 142AECh. 8 - Prob. 143CWPCh. 8 - Prob. 144CWPCh. 8 - A certain flexible weather balloon contains helium...Ch. 8 - Prob. 146CWPCh. 8 - A 20.0L nickel container was charged with 0.859...Ch. 8 - Consider the unbalanced chemical equation below:...Ch. 8 - Prob. 149CWPCh. 8 - Which of the following statements is(are) true? a....Ch. 8 - A chemist weighed out 5.14 g of a mixture...Ch. 8 - A mixture of chromium and zinc weighing 0.362 g...Ch. 8 - Prob. 153CPCh. 8 - You have an equimolar mixture of the gases SO2 and...Ch. 8 - Methane (CH4) gas flows into a combustion chamber...Ch. 8 - Prob. 156CPCh. 8 - Prob. 157CPCh. 8 - Prob. 158CPCh. 8 - You have a helium balloon at 1.00 atm and 25C. You...Ch. 8 - Prob. 160CPCh. 8 - You are given an unknown gaseous binary compound...Ch. 8 - Prob. 162CPCh. 8 - Calculate w and E when 1 mole of a liquid is...Ch. 8 - The preparation of NO2(g) from N2(g) and O2(g) is...Ch. 8 - In the presence of nitric acid, UO2+ undergoes a...Ch. 8 - Silane, SiH4, is the silicon analogue of methane,...Ch. 8 - Prob. 167IPCh. 8 - Prob. 168IPCh. 8 - Prob. 169MP
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