Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
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Chapter 8, Problem 34P
8-46 If 25.0 mL of an aqueous solution of H2SO4 requires 19.7 mL of 0.72 M NaOH to reach the end point, what is the molarity of the HO2SO4 solution?
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Chapter 8 Solutions
Introduction to General, Organic and Biochemistry
Ch. 8.3 - Problem 8-1 Draw the acid and base reactions for...Ch. 8.4 - Prob. 8.2QCCh. 8.5 - Prob. 8.3QCCh. 8.5 - Problem 8-4 Which is the stronger acid? (a)...Ch. 8.6 - Problem 8-5 Write the balanced net ionic equation...Ch. 8.7 - Problem 8-6 The [OH-] of an aqueous solution is M....Ch. 8.8 - Problem 8-7 (a) The [H3O+] of an acidic solution...Ch. 8.8 - Problem 8-8 The [OH-] of a solution is M. What are...Ch. 8.9 - Problem 8-9 Calculate the concentration of an...Ch. 8.10 - Problem 8-10 What is the pH of a buffer solution...
Ch. 8.11 - Problem 8-11 What is the pH of a boric acid buffer...Ch. 8.12 - Prob. 8.12QCCh. 8 - 8-13 Define (a) an Arrhenius acid and (b) an...Ch. 8 - 8-14 Write an equation for the reaction that takes...Ch. 8 - 8-15 Write an equation for the reaction that takes...Ch. 8 - 8-16 For each of the following, tell whether the...Ch. 8 - 8-17 For each of the following, tell whether the...Ch. 8 - 8-18 Which of these acids are monoprotic, which...Ch. 8 - 8-19 Define (a) a Brønsted—Lowry acid and (b) a...Ch. 8 - 8-20 Write the formula for the conjugate base of...Ch. 8 - 8-21 Write the formula for the conjugate base of...Ch. 8 - Prob. 10PCh. 8 - Prob. 11PCh. 8 - Prob. 12PCh. 8 - 8-25 Draw the acid and base reactions for the...Ch. 8 - Prob. 14PCh. 8 - Prob. 15PCh. 8 - 8-28 Will carbon dioxide be evolved as a gas when...Ch. 8 - Prob. 17PCh. 8 - Prob. 18PCh. 8 - Prob. 19PCh. 8 - Prob. 20PCh. 8 - 8-33 Write an equation for the reaction of HCI...Ch. 8 - 8-34 When a solution of sodium hydroxide is added...Ch. 8 - 8-35 Given the following values of [H3O+),...Ch. 8 - 8-36 Given the following values of [OH-],...Ch. 8 - 8-37 What is the pH of each solution given the...Ch. 8 - 8-38 What is the pH and pOH of each solution given...Ch. 8 - 8-39 What is the pH of each solution given the...Ch. 8 - Prob. 28PCh. 8 - 8-41 What is the [OH-] and pOH of each solution?...Ch. 8 - Prob. 30PCh. 8 - 8-43 What is the molarity of a solution made by...Ch. 8 - 8-44 What is the molarity of a solution made by...Ch. 8 - 8-45 Describe how you would prepare each of the...Ch. 8 - 8-46 If 25.0 mL of an aqueous solution of H2SO4...Ch. 8 - 8-47 A sample of 27.0 mL of 0.310 M NaOH is...Ch. 8 - 8-48 A 0.300 M solution of H2SO4 was used to...Ch. 8 - 8-49 A solution of NaOH base was titrated with...Ch. 8 - 8-50 The usual concentration of HCO3- ions in...Ch. 8 - 8-51 What is the end point of a titration?Ch. 8 - Prob. 40PCh. 8 - 8-53 Write equations to show what happens when, to...Ch. 8 - 8-54 Write equations to show what happens when, to...Ch. 8 - 8-55 We commonly refer to a buffer as consisting...Ch. 8 - Prob. 44PCh. 8 - Prob. 45PCh. 8 - 8-58 What is the connection between buffer action...Ch. 8 - Prob. 47PCh. 8 - 8-60 How is the buffer capacity affected by the...Ch. 8 - 8-61 Can 100 of 0.1 M phosphate buffer at pH 7.2...Ch. 8 - 8-62 What is the pH of a buffer solution made by...Ch. 8 - 8-63 The pH of a solution made by dissolving 1.0...Ch. 8 - Prob. 52PCh. 8 - Prob. 53PCh. 8 - Prob. 54PCh. 8 - Prob. 55PCh. 8 - 8-66 Calculate the pH of an aqueous solution...Ch. 8 - Prob. 57PCh. 8 - 8-68 If you have 100 mL of a 0.1 M buffer made of...Ch. 8 - Prob. 59PCh. 8 - Prob. 60PCh. 8 - 8-71 Explain why you do not need to know the...Ch. 8 - Prob. 62PCh. 8 - Prob. 63PCh. 8 - Prob. 64PCh. 8 - Prob. 65PCh. 8 - 8-76 (Chemical Connections 8B) Name the most...Ch. 8 - Prob. 67PCh. 8 - Prob. 68PCh. 8 - 8-79 (Chemical Connections 8D) Another form of the...Ch. 8 - Prob. 70PCh. 8 - Prob. 71PCh. 8 - 8-82 Assume that you have a dilute solution of HCI...Ch. 8 - Prob. 73PCh. 8 - Prob. 74PCh. 8 - Prob. 75PCh. 8 - 8-86 Following are three organic acids and the...Ch. 8 - 8-87 The pKavalue of barbituric acid is 5.0. If...Ch. 8 - Prob. 78PCh. 8 - Prob. 79PCh. 8 - Prob. 80PCh. 8 - Prob. 81PCh. 8 - Prob. 82PCh. 8 - 8-93 Do a 1.0 M CH3COOH solution and a 1.0 M HCI...Ch. 8 - 8-94 Suppose you wish to make a buffer whose pH is...Ch. 8 - Prob. 85PCh. 8 - 8-96 Suppose you want to make a CH3COOH/CH3COO-...Ch. 8 - Prob. 87PCh. 8 - 8-98 When a solution prepared by dissolving 4.00 g...Ch. 8 - Prob. 89PCh. 8 - Prob. 90PCh. 8 - 8-101 Suppose you have an aqueous solution...Ch. 8 - Prob. 92PCh. 8 - 8-103 Suppose you have a phosphate buffer...Ch. 8 - Prob. 94PCh. 8 - Prob. 95PCh. 8 - Prob. 96PCh. 8 - 8-107 Following are pH ranges for several human...Ch. 8 - Prob. 98PCh. 8 - Prob. 99PCh. 8 - 8-108 What is the ratio of HPO42-/H2PO4- in a...Ch. 8 - Prob. 101PCh. 8 - 8-110 A concentrated hydrochloric acid solution...Ch. 8 - 8-111 The volume of an adult's stomach ranges from...Ch. 8 - 8-112 Consider an initial 0.040 M hypobromous acid...Ch. 8 - Prob. 105PCh. 8 - Prob. 106PCh. 8 - 8-115 When a solution prepared by dissolving 0.125...Ch. 8 - 8-116 A railroad tank car derails and spills 26...Ch. 8 - Prob. 109PCh. 8 - Prob. 110PCh. 8 - Prob. 111P
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- 6-71 A 4 M acetic acid (CH3COOH) solution lowers the freezing point by-8°C; a 4 M KF solution yields a-15°C freezing-point depression. What can account for this difference?arrow_forward8-47 A sample of 27.0 mL of 0.310 M NaOH is titrated with 0.740 M H2SO4. How many milliliters of the H2SO4 solution are required to reach the end point?arrow_forward8-43 What is the molarity of a solution made by dissolving 12.7 g of HCI in enough water to make 1.00 L of solution?arrow_forward
- 8-98 When a solution prepared by dissolving 4.00 g of an unknown monoprotic acid in 1.00 L of water is titrated with 0.600 M NaOH, 38.7 ml, of the NaOH solution is needed to neutralize the acid. Determine the molarity of the acid solution. What is the molar mass of the unknown acid?arrow_forward8-115 When a solution prepared by dissolving 0.125 g of an unknown diprotic acid in 25.0 mL of water is titrated with 0.200 M NaOH, 30.0 ml, of the NaOH solution is needed to neutralize the acid. Determine the molarity of the acid solution. What is the molar mass of the unknown diprotic acid?arrow_forward8-50 The usual concentration of HCO3- ions in blood plasma is approximately 24 millimoles per liter (mmol/L). How would you make up 1.00 L of a solution containing this concentration of HCO3- ions?arrow_forward
- 8-14 Write an equation for the reaction that takes place when each acid is added to water. (a) HNO3 (b) HBr (c) HCO3- (d) NH4+arrow_forward8-48 A 0.300 M solution of H2SO4 was used to titrate 10.00 mL of NaOH; 15.00 mL of acid was required to neutralize the basic solution. What was the molarity of the base?arrow_forward6-82 (Chemical Connections 6C) A solution contains 54 mEq/L ofCI- and 12 mEq/L of HCO3-. If Na+ is the only cation present in the solution, what is the Na+ concentration in milliequivalents per liter?arrow_forward
- 8-51 What is the end point of a titration?arrow_forward43.27 mL of 0.5033 M NaOH are required to neutralize 29.16 mL of a H2SO4 solution.What is the molarity of the H2SO4 solution? H2SO4 + 2 NaOH ® Na2SO4 + 2 H2Oarrow_forwardHow many milliliters (mL) of 0.5 M NaOH will be used to completely neutralize 3.0 g of acetic acid, HC2H3O2 in a commercial sample of vinegar?arrow_forward
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