Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Question
Chapter 7.7, Problem 8P
Interpretation Introduction
Interpretation:
The name and stability (most stable to least stable) of given
Concept Introduction:
Delocalized electrons: Electrons that are not localized in one particular atom or bond and shared by three or more atoms are called delocalized electrons.
Compounds with two double bonds are known as dienes.
Stability of diene: The number of alkyl group increases with increasing the stability of the dienes.
Conjugated diene: Dienes are hydrocarbons with two double bonds; where the conjugated double bonds are separated by one single bond.
Resonance contributor: In some chemical compounds like benzene pi electrons are delocalized in it and difficult to locate it. Resonance contributor gives an idea of whereabouts of pi electrons. The exact structure with localized electrons are called resonance contributor.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Draw the alkene that would react with the reagent given to account for the product formed.
OH
H₂SO4
CH3CH2CCH2CH3
?
+
H₂O
CH2CH3
. You do not have to consider stereochemistry.
• You do not have to explicitly draw H atoms.
• In cases where there is more than one answer, just draw one.
Shown below are four isomeric alkenes. Put them in order based on their stability.
(1)
Most stable:
(2)
V
(3)
(4)
:least stable
44a) Draw the bond-line structure of 1,4-dimethyl-cyclohexa-1,3-diene here:
STRUCTURE:
b) Circle all the sp²-hybridized carbons in your drawing of the structure.
c) In the spaces below, draw two potential products from a chlorination
reaction (addition of Cl2) with your first structure
Product 1:
Product 2:
Chapter 7 Solutions
Essential Organic Chemistry, Global Edition
Ch. 7.4 - Prob. 1PCh. 7.5 - Prob. 3PCh. 7.6 - a. Predict the relative bond lengths of the three...Ch. 7.6 - Prob. 5PCh. 7.6 - Prob. 6PCh. 7.7 - Prob. 7PCh. 7.7 - Prob. 8PCh. 7.7 - Prob. 9PCh. 7.7 - Prob. 10PCh. 7.8 - Which member of each pair is the stronger acid? a....
Ch. 7.8 - Which member of each pair is the stronger base? a....Ch. 7.9 - Prob. 13PCh. 7.9 - Which species in each of the following pairs is...Ch. 7.9 - Prob. 16PCh. 7.11 - Prob. 18PCh. 7.11 - Prob. 19PCh. 7.11 - Prob. 20PCh. 7.11 - Prob. 21PCh. 7.11 - Prob. 22PCh. 7.12 - Prob. 23PCh. 7.12 - Prob. 24PCh. 7.15 - Prob. 25PCh. 7.15 - Which of the following are aromatic? A...Ch. 7.17 - Prob. 29PCh. 7.17 - Prob. 30PCh. 7 - Prob. 31PCh. 7 - Prob. 32PCh. 7 - Prob. 33PCh. 7 - Prob. 34PCh. 7 - Prob. 35PCh. 7 - Prob. 36PCh. 7 - Which of the compounds in each of the following...Ch. 7 - Prob. 39PCh. 7 - Prob. 40PCh. 7 - Prob. 41PCh. 7 - Prob. 42PCh. 7 - Prob. 43PCh. 7 - Prob. 44PCh. 7 - Prob. 45PCh. 7 - Which species in each of the pairs in Problem 45...Ch. 7 - Rank the following anions in order from most basic...Ch. 7 - a. Which oxygen atom has the greater electron...Ch. 7 - Prob. 49PCh. 7 - Which compound is the strongest base?Ch. 7 - Prob. 51PCh. 7 - Prob. 52PCh. 7 - Prob. 53PCh. 7 - Prob. 54PCh. 7 - Prob. 55PCh. 7 - a. Which dienophile in each pair is more reactive...Ch. 7 - Prob. 57PCh. 7 - Draw the product of each of the following...Ch. 7 - Prob. 59PCh. 7 - Prob. 60PCh. 7 - Prob. 61PCh. 7 - a. In what direction is the dipole moment in...Ch. 7 - Propose a mechanism for each of the following...Ch. 7 - Prob. 1PCh. 7 - Prob. 2PCh. 7 - Prob. 3PCh. 7 - Prob. 4PCh. 7 - Prob. 5PCh. 7 - Prob. 6PCh. 7 - Prob. 7PCh. 7 - Prob. 8PCh. 7 - Prob. 9PCh. 7 - Prob. 10PCh. 7 - Prob. 11PCh. 7 - Prob. 12P
Knowledge Booster
Similar questions
- [References] The two alkenes below react with HI at different rates. CH3 CH3CH=CHCH3 and CH;ċ=CHCH3 Draw the structural formula of the MAJOR product formed by the alkene having the HIGHER reaction rate. You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. In cases where there is more than one answer, just draw one. C P opy aste Previous Next ChemDoodle®arrow_forward6) Rank the stability of the following carbocations (1 = most stable) Toarrow_forwardThe compound below is treated with chlorine in the presence of lightarrow_forward
- 4. For the following reactions, develop a transition-state structure using molecular models which would account for the observed stereoselectivity. Also, describe the type of pericyclic reactions using the proper terminology. (each Br heat A & Br b) F 0°C F heat heat d) product? =& & MeO₂C OCH3 H HO 1. CO₂Me مر CO₂Me LOCH3 heat heat MeO₂C HOarrow_forward6. The addition reaction of unsymmetrical molecules, e.g. HCI, H20, to unsymmetrical alkene molecules, e.g. propene, produces two products: a main product and a byproduct. The main product is the one obtained according to Markovnikov's rule and the by-product is the one obtained not according to Markovnikov's rule. Complete the given equations of chemical reactions by writing the semi-structural formulas of the missing substrates and products. Circle the main products. A. 2CH, = CH- CH, – CH, + 2HCĮ- В. В. 2 +2H,0- + CH, — сH, — сн, - онarrow_forwardDraw a structural formula for cis-1-bromo-4-chlorocyclohexane. Show stereochemistry only if given in the name. • In cases where there is more than one answer, just draw one. **** Sn [F ChemDoodleⓇarrow_forward
- Rank the following cyclohexane isomers in order of stability (where the Most Stable Isomer = 1). If you believe multiple isomers have the same approximate overall energies indicate this by ranking them with the same number. Me. Me Me.* Me Me Me Me Me Ме,. Me Me* Me Ме, Me Me Mearrow_forwardAlkyl halides undergo elimination reactions to produce alkenes by the reacting with strong bases as shown in the following reaction (see image). In general, compounds where the halogen is axial (axial position) are much more reactive than those in which they are in the equatorial position. Taking the above into account: a. Which of the following compounds would give a faster elimination reaction: cis-1-bromo-2-tert-butylcyclohexane or trans-1-bromo-2-tert-butylcyclohexane? Draw the corresponding structures and clearly explain the choice.arrow_forward8. +) Draw the structure of (2S,3S)-2-chloro-3-methylhexane. Use wedges and dashes (where applicable) to indicate stereochemistry. CI (2S,3S)-2-chloro-3-methylhexanearrow_forward
- The two alkenes below react with HI at different rates. CH3CH=CHCH3 and CH₂=CH₂ Draw the structural formula of the MAJOR product formed by the alkene having the HIGHER reaction rate. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. TAYY [ ] در ChemDoodle Ⓡarrow_forwardDraw the structure for an alkene that gives the following reaction product. 7 CH2l2, Zn/Cu Ignore alkene stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. / [F ?arrow_forward5. Provide an example of/structure for: [a] the endo cycloadduct derived from the Diels-Alder reaction of CpH and methyl vinyl ketone [b] a fused bicyclic structure [c] bicyclo[3.2.0]hep-2-enearrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning