GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
4th Edition
ISBN: 9781265982959
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 7.12, Problem 7.17P
Answer the following questions about the graph
- Does the graph illustrate a heating curve or a cooling curve?
- What is the melting point of the substance?
- What is the boiling point of the substance?
- What phase(s) are present at plateau
- What phase(s) are present along the diagonal
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Students have asked these similar questions
Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
Chapter 7 Solutions
GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
Ch. 7.1 - Prob. 7.1PCh. 7.2 - Convert each pressure unit to the indicated unit....Ch. 7.3 - Prob. 7.2PPCh. 7.3 - Prob. 7.2PCh. 7.3 - Prob. 7.3PPCh. 7.3 - Prob. 7.3PCh. 7.3 - Prob. 7.4PPCh. 7.3 - Prob. 7.4PCh. 7.3 - The pressure inside a 1.0-L balloon at 25C was 750...Ch. 7.4 - A sample of nitrogen gas contains 5.0 mol in a...
Ch. 7.4 - Prob. 7.7PPCh. 7.4 - Prob. 7.5PCh. 7.5 - Prob. 7.8PPCh. 7.5 - Prob. 7.6PCh. 7.6 - CO2 was added to a cylinder containing 2.5 atm of...Ch. 7.6 - Prob. 7.10PPCh. 7.6 - Prob. 7.7PCh. 7.7 - Prob. 7.8PCh. 7.7 - Prob. 7.9PCh. 7.7 - Prob. 7.11PPCh. 7.7 - Which species in each pair has stronger...Ch. 7.7 - Prob. 7.12PPCh. 7.7 - Prob. 7.11PCh. 7.8 - Prob. 7.13PPCh. 7.8 - Would you predict the surface tension of gasoline,...Ch. 7.9 - Prob. 7.13PCh. 7.10 - Prob. 7.14PPCh. 7.10 - The human body is composed of about 70% water. How...Ch. 7.10 - How much energy is required to heat 28.0 g of iron...Ch. 7.10 - Prob. 7.15PCh. 7.10 - Prob. 7.16PPCh. 7.10 - If the initial temperature of 120. g of ethanol is...Ch. 7.11 - Use the heat of fusion of water from Sample...Ch. 7.11 - Answer the following questions about water, which...Ch. 7.11 - Prob. 7.19PPCh. 7.12 - Answer the following questions about the graph...Ch. 7.12 - How much energy (in calories) is released when...Ch. 7.12 - How much energy (in calories) is required to melt...Ch. 7 - Prob. 19PCh. 7 - Prob. 20PCh. 7 - Prob. 21PCh. 7 - The compressed air tank of a scuba diver reads...Ch. 7 - Assume that each of the following samples is at...Ch. 7 - Use the diagrams in problem 7.23 to answer the...Ch. 7 - Prob. 25PCh. 7 - Prob. 26PCh. 7 - Prob. 27PCh. 7 - Prob. 28PCh. 7 - Prob. 29PCh. 7 - Prob. 30PCh. 7 - Prob. 31PCh. 7 - Prob. 32PCh. 7 - Prob. 33PCh. 7 - If you pack a bag of potato chips for a snack on a...Ch. 7 - Prob. 35PCh. 7 - Prob. 36PCh. 7 - Prob. 37PCh. 7 - Prob. 38PCh. 7 - Prob. 39PCh. 7 - Prob. 40PCh. 7 - Prob. 41PCh. 7 - Prob. 42PCh. 7 - Prob. 43PCh. 7 - Prob. 44PCh. 7 - Prob. 45PCh. 7 - Prob. 46PCh. 7 - Prob. 47PCh. 7 - Consider balloons A and B, which contain CH4 and...Ch. 7 - Prob. 49PCh. 7 - Prob. 50PCh. 7 - Prob. 51PCh. 7 - Prob. 52PCh. 7 - Prob. 53PCh. 7 - Prob. 54PCh. 7 - Prob. 55PCh. 7 - Prob. 56PCh. 7 - Prob. 57PCh. 7 - Prob. 58PCh. 7 - Prob. 59PCh. 7 - Prob. 60PCh. 7 - Prob. 61PCh. 7 - Prob. 62PCh. 7 - Prob. 63PCh. 7 - Prob. 64PCh. 7 - Which molecules are capable of intermolecular...Ch. 7 - Prob. 66PCh. 7 - Prob. 67PCh. 7 - Explain why the boiling point of A is higher than...Ch. 7 - Prob. 69PCh. 7 - Prob. 70PCh. 7 - Prob. 71PCh. 7 - Prob. 72PCh. 7 - Prob. 73PCh. 7 - Prob. 74PCh. 7 - Prob. 75PCh. 7 - Prob. 76PCh. 7 - Prob. 77PCh. 7 - Prob. 78PCh. 7 - Prob. 79PCh. 7 - Prob. 80PCh. 7 - Prob. 81PCh. 7 - How many calories of heat are needed to increase...Ch. 7 - Prob. 83PCh. 7 - If it takes 37.0 cal of heat to raise the...Ch. 7 - Prob. 85PCh. 7 - What phase change is shown in the accompanying...Ch. 7 - Prob. 87PCh. 7 - Which process requires more energy, melting 250 g...Ch. 7 - Consider the cooling curve drawn below a. Which...Ch. 7 - Prob. 90PCh. 7 - Draw the heating curve that is observed when...Ch. 7 - Prob. 92PCh. 7 - Use the following values to answer each part. The...Ch. 7 - Prob. 94PCh. 7 - Prob. 95PCh. 7 - Prob. 96PCh. 7 - Prob. 97PCh. 7 - Explain why you feel cool when you get out of a...Ch. 7 - Prob. 99CPCh. 7 - As we learned in Chapter 5, an automobile airbag...
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