GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
4th Edition
ISBN: 9781265982959
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 7, Problem 84P
If it takes 37.0 cal of heat to raise the temperature of12.0gofasubstanceby
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 7 Solutions
GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
Ch. 7.1 - Prob. 7.1PCh. 7.2 - Convert each pressure unit to the indicated unit....Ch. 7.3 - Prob. 7.2PPCh. 7.3 - Prob. 7.2PCh. 7.3 - Prob. 7.3PPCh. 7.3 - Prob. 7.3PCh. 7.3 - Prob. 7.4PPCh. 7.3 - Prob. 7.4PCh. 7.3 - The pressure inside a 1.0-L balloon at 25C was 750...Ch. 7.4 - A sample of nitrogen gas contains 5.0 mol in a...
Ch. 7.4 - Prob. 7.7PPCh. 7.4 - Prob. 7.5PCh. 7.5 - Prob. 7.8PPCh. 7.5 - Prob. 7.6PCh. 7.6 - CO2 was added to a cylinder containing 2.5 atm of...Ch. 7.6 - Prob. 7.10PPCh. 7.6 - Prob. 7.7PCh. 7.7 - Prob. 7.8PCh. 7.7 - Prob. 7.9PCh. 7.7 - Prob. 7.11PPCh. 7.7 - Which species in each pair has stronger...Ch. 7.7 - Prob. 7.12PPCh. 7.7 - Prob. 7.11PCh. 7.8 - Prob. 7.13PPCh. 7.8 - Would you predict the surface tension of gasoline,...Ch. 7.9 - Prob. 7.13PCh. 7.10 - Prob. 7.14PPCh. 7.10 - The human body is composed of about 70% water. How...Ch. 7.10 - How much energy is required to heat 28.0 g of iron...Ch. 7.10 - Prob. 7.15PCh. 7.10 - Prob. 7.16PPCh. 7.10 - If the initial temperature of 120. g of ethanol is...Ch. 7.11 - Use the heat of fusion of water from Sample...Ch. 7.11 - Answer the following questions about water, which...Ch. 7.11 - Prob. 7.19PPCh. 7.12 - Answer the following questions about the graph...Ch. 7.12 - How much energy (in calories) is released when...Ch. 7.12 - How much energy (in calories) is required to melt...Ch. 7 - Prob. 19PCh. 7 - Prob. 20PCh. 7 - Prob. 21PCh. 7 - The compressed air tank of a scuba diver reads...Ch. 7 - Assume that each of the following samples is at...Ch. 7 - Use the diagrams in problem 7.23 to answer the...Ch. 7 - Prob. 25PCh. 7 - Prob. 26PCh. 7 - Prob. 27PCh. 7 - Prob. 28PCh. 7 - Prob. 29PCh. 7 - Prob. 30PCh. 7 - Prob. 31PCh. 7 - Prob. 32PCh. 7 - Prob. 33PCh. 7 - If you pack a bag of potato chips for a snack on a...Ch. 7 - Prob. 35PCh. 7 - Prob. 36PCh. 7 - Prob. 37PCh. 7 - Prob. 38PCh. 7 - Prob. 39PCh. 7 - Prob. 40PCh. 7 - Prob. 41PCh. 7 - Prob. 42PCh. 7 - Prob. 43PCh. 7 - Prob. 44PCh. 7 - Prob. 45PCh. 7 - Prob. 46PCh. 7 - Prob. 47PCh. 7 - Consider balloons A and B, which contain CH4 and...Ch. 7 - Prob. 49PCh. 7 - Prob. 50PCh. 7 - Prob. 51PCh. 7 - Prob. 52PCh. 7 - Prob. 53PCh. 7 - Prob. 54PCh. 7 - Prob. 55PCh. 7 - Prob. 56PCh. 7 - Prob. 57PCh. 7 - Prob. 58PCh. 7 - Prob. 59PCh. 7 - Prob. 60PCh. 7 - Prob. 61PCh. 7 - Prob. 62PCh. 7 - Prob. 63PCh. 7 - Prob. 64PCh. 7 - Which molecules are capable of intermolecular...Ch. 7 - Prob. 66PCh. 7 - Prob. 67PCh. 7 - Explain why the boiling point of A is higher than...Ch. 7 - Prob. 69PCh. 7 - Prob. 70PCh. 7 - Prob. 71PCh. 7 - Prob. 72PCh. 7 - Prob. 73PCh. 7 - Prob. 74PCh. 7 - Prob. 75PCh. 7 - Prob. 76PCh. 7 - Prob. 77PCh. 7 - Prob. 78PCh. 7 - Prob. 79PCh. 7 - Prob. 80PCh. 7 - Prob. 81PCh. 7 - How many calories of heat are needed to increase...Ch. 7 - Prob. 83PCh. 7 - If it takes 37.0 cal of heat to raise the...Ch. 7 - Prob. 85PCh. 7 - What phase change is shown in the accompanying...Ch. 7 - Prob. 87PCh. 7 - Which process requires more energy, melting 250 g...Ch. 7 - Consider the cooling curve drawn below a. Which...Ch. 7 - Prob. 90PCh. 7 - Draw the heating curve that is observed when...Ch. 7 - Prob. 92PCh. 7 - Use the following values to answer each part. The...Ch. 7 - Prob. 94PCh. 7 - Prob. 95PCh. 7 - Prob. 96PCh. 7 - Prob. 97PCh. 7 - Explain why you feel cool when you get out of a...Ch. 7 - Prob. 99CPCh. 7 - As we learned in Chapter 5, an automobile airbag...
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