Chemistry: An Atoms First Approach
2nd Edition
ISBN: 9781305079243
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Chapter 7, Problem 88E
Interpretation Introduction
Interpretation: Standard enthalpy of combustion of liquid methanol per gram has to calculate and compare this answer to ethanol.
Concept introduction
Standard enthalpy of combustion (
Standard conditions:
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Chapter 7 Solutions
Chemistry: An Atoms First Approach
Ch. 7 - Define the following terms: potential energy,...Ch. 7 - Consider the following potential energy diagrams...Ch. 7 - What is the first law of thermodynamics? How can a...Ch. 7 - When a gas expands, what is the sign of w? Why?...Ch. 7 - Prob. 5RQCh. 7 - High-quality audio amplifiers generate large...Ch. 7 - Explain how calorimetry works to calculate H or E...Ch. 7 - What is Hesss law? When a reaction is reversed,...Ch. 7 - Define the standard enthalpy of formation. What...Ch. 7 - Prob. 1ALQ
Ch. 7 - Prob. 2ALQCh. 7 - A fire is started in a fireplace by striking a...Ch. 7 - Liquid water turns to ice. Is this process...Ch. 7 - Prob. 5ALQCh. 7 - Prob. 6ALQCh. 7 - Consider 5.5 L of a gas at a pressure of 3.0 atm...Ch. 7 - Explain why oceanfront areas generally have...Ch. 7 - Hesss law is really just another statement of the...Ch. 7 - Prob. 10ALQCh. 7 - Prob. 11QCh. 7 - Prob. 12QCh. 7 - Assuming gasoline is pure C8H18(l), predict the...Ch. 7 - Prob. 14QCh. 7 - The enthalpy change for the reaction...Ch. 7 - For the reaction HgO(s)Hg(l)+12O2(g),H=+90.7KJ: a....Ch. 7 - Prob. 17QCh. 7 - The enthalpy change for a reaction is a state...Ch. 7 - Standard enthalpies of formation are relative...Ch. 7 - The combustion of methane can be represented as...Ch. 7 - Prob. 21QCh. 7 - Prob. 22QCh. 7 - Prob. 23QCh. 7 - Prob. 24QCh. 7 - Prob. 25ECh. 7 - Prob. 26ECh. 7 - Consider the following diagram when answering the...Ch. 7 - Consider the accompanying diagram. Ball A is...Ch. 7 - A gas absorbs 45 kJ of heat and does 29 kJ of...Ch. 7 - A system releases 125 kJ of heat while 104 kJ of...Ch. 7 - Calculate E for each of the following. a. q = 47...Ch. 7 - A system undergoes a process consisting of the...Ch. 7 - If the internal energy of a thermodynamic system...Ch. 7 - Calculate the internal energy change for each of...Ch. 7 - A sample of an ideal gas at 15.0 atm and 10.0 L is...Ch. 7 - Prob. 36ECh. 7 - Consider a mixture of air and gasoline vapor in a...Ch. 7 - As a system increases in volume, it absorbs 52.5 J...Ch. 7 - A balloon filled with 39.1 moles of helium has a...Ch. 7 - Prob. 40ECh. 7 - One of the components of polluted air is NO. It is...Ch. 7 - Prob. 42ECh. 7 - Are the following processes exothermic or...Ch. 7 - Are the following processes exothermic or...Ch. 7 - The overall reaction in a commercial heat pack can...Ch. 7 - Consider the following reaction:...Ch. 7 - Consider the combustion of propane:...Ch. 7 - Consider the following reaction:...Ch. 7 - Prob. 49ECh. 7 - The specific heat capacity of silver is 0.24 J/Cg....Ch. 7 - A 500-g sample of one of the substances listed in...Ch. 7 - Prob. 52ECh. 7 - A 30.0-g sample of water at 280. K is mixed with...Ch. 7 - A biology experiment requires the preparation of a...Ch. 7 - A 5.00-g sample of aluminum pellets (specific heat...Ch. 7 - Hydrogen gives off 120. J/g of energy when burned...Ch. 7 - Prob. 57ECh. 7 - A 110.-g sample of copper (specific heat capacity...Ch. 7 - In a coffee-cup calorimeter, 50.0 mL of 0.100 M...Ch. 7 - In a coffee-cup calorimeter, 100.0 mL of 1.0 M...Ch. 7 - A coffee-cup calorimeter initially contains 125 g...Ch. 7 - In a coffee-cup calorimeter, 1.60 g NH4NO3 is...Ch. 7 - Consider the dissolution of CaCl2:...Ch. 7 - Consider the reaction...Ch. 7 - The heat capacity of a bomb calorimeter was...Ch. 7 - The combustion of 0.1584 g benzoic acid increases...Ch. 7 - The enthalpy of combustion of solid carbon to form...Ch. 7 - Combustion reactions involve reacting a substance...Ch. 7 - Given the following data calculate H for the...Ch. 7 - Given the following data...Ch. 7 - Prob. 71ECh. 7 - Calculate H for the reaction...Ch. 7 - Given the following data...Ch. 7 - Given the following data...Ch. 7 - Give the definition of the standard enthalpy of...Ch. 7 - Write reactions for which the enthalpy change will...Ch. 7 - Prob. 77ECh. 7 - Use the values of Hf in Appendix 4 to calculate H...Ch. 7 - The Ostwald process for the commercial production...Ch. 7 - Calculate H for each of the following reactions...Ch. 7 - The reusable booster rockets of the space shuttle...Ch. 7 - The space shuttle Orbiter utilizes the oxidation...Ch. 7 - Consider the reaction...Ch. 7 - The standard enthalpy of combustion of ethene gas,...Ch. 7 - Water gas is produced from the reaction of steam...Ch. 7 - Prob. 86ECh. 7 - Prob. 87ECh. 7 - Prob. 88ECh. 7 - Some automobiles and buses have been equipped to...Ch. 7 - The complete combustion of acetylene, C2H2(g),...Ch. 7 - Prob. 91AECh. 7 - One way to lose weight is to exercise! Walking...Ch. 7 - Three gas-phase reactions were run in a...Ch. 7 - Nitrogen gas reacts with hydrogen gas to form...Ch. 7 - Combustion of table sugar produces CO2(g) and H2O(...Ch. 7 - Prob. 96AECh. 7 - Consider the following cyclic process carried out...Ch. 7 - Calculate H for the reaction...Ch. 7 - The enthalpy of neutralization for the reaction of...Ch. 7 - Prob. 100AECh. 7 - If a student performs an endothermic reaction in a...Ch. 7 - In a bomb calorimeter, the reaction vessel is...Ch. 7 - The bomb calorimeter in Exercise 102 is filled...Ch. 7 - Prob. 104AECh. 7 - Consider the following equations:...Ch. 7 - Prob. 106AECh. 7 - At 298 K, the standard enthalpies of formation for...Ch. 7 - Prob. 108AECh. 7 - A sample of nickel is heated to 99.8C and placed...Ch. 7 - Quinone is an important type of molecule that is...Ch. 7 - Calculate H for each of the following reactions,...Ch. 7 - Compare your answers from parts a and b of...Ch. 7 - Compare your answer from Exercise 72 of Chapter 3...Ch. 7 - Consider a balloon filled with helium at the...Ch. 7 - Prob. 115CWPCh. 7 - Prob. 116CWPCh. 7 - Prob. 117CWPCh. 7 - A swimming pool, 10.0 m by 4.0 m, is filled with...Ch. 7 - Prob. 119CWPCh. 7 - Calculate H for the reaction...Ch. 7 - Which of the following substances have an enthalpy...Ch. 7 - Consider 2.00 moles of an ideal gas that are taken...Ch. 7 - For the process H2O(l)H2O(g) at 298 K and 1.0 atm,...Ch. 7 - The sun supplies energy at a rate of about 1.0...Ch. 7 - Prob. 125CPCh. 7 - The standard enthalpies of formation for S(g),...Ch. 7 - Use the following standard enthalpies of formation...Ch. 7 - The standard enthalpy of formation for N2H4(g) is...Ch. 7 - The standard enthalpy of formation for NO(g) is...Ch. 7 - A piece of chocolate cake contains about 400...Ch. 7 - You have a l.00-mole sample of water at 30.C and...Ch. 7 - A 500.0-g sample of an element at 195C is dropped...Ch. 7 - A cubic piece of uranium metal (specific heat...Ch. 7 - On Easter Sunday, April 3, 1983, nitric acid...Ch. 7 - Using data from Chapter 2, calculate the change in...Ch. 7 - In Exercise 89 in Chapter 3, the Lewis structures...Ch. 7 - A gaseous hydrocarbon reacts completely with...
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- What mass of acetylene, C2H2(g), must be burned to produce 3420 kJ of heat, given that its enthalpy of combustion is 1301 kJ/mol? Compare this with the answer to Exercise 5.91 and determine which substance produces more heat per gram.arrow_forwardAlthough the gas used in an oxyacetylene torch (Figure 5.7) is essentially pure acetylene, the heat produced by combustion of one mole of acetylene in such a torch is likely not equal to the enthalpy of combustion of acetylene listed in Table 5.2. Considering the conditions for which the tabulated data are reported, suggest an explanation.arrow_forwardThe first step in the preparation of lead from its ore (galena, PbS) consists of roasting the ore. PbS(s)+32O2(g)SO2(g)+PbO(s) Calculate the standard enthalpy change for this reaction, using enthalpies of formation (see Appendix C).arrow_forward
- Gasohol, a mixture of gasoline and ethanol, C2H5OH, is used as automobile fuel. The alcohol releases energy in a combustion reaction with O2. C2H5OH(l)+3O2(g)2CO2(g)+3H2O(l) If 0.115 g ethanol evolves 3.62 kJ when burned at constant pressure, calculate the combustion enthalpy for ethanol.arrow_forwardThe enthalpy change for the following reaction is 393.5 kJ. C(s,graphite)+O2(g)CO2(g) (a) Is energy released from or absorbed by the system in this reaction? (b) What quantities of reactants and products are assumed? (c) Predict the enthalpy change observed when 3.00 g carbon burns in an excess of oxygen.arrow_forwardExplain why absolute enthalpies and energies cannot be measured, and only changes can be determined.arrow_forward
- When 2.50 g of methane burns in oxygen, 125 kJ of heat is produced. What is the enthalpy of combustion per mole of methane under these conditions?arrow_forwardUsing the data in Appendix G, calculate the standard enthalpy change for each of the following reactions: (a) Si(s)+2F2(g)SiF4(g) (b) 2C(s)+2H2(g)+O2(g)CH3CO2H(l) (c) CH4(g)+N2(g)HCN(g)+NH3(g) ; (d) CS2(g)+3Cl2(g)CCl4(g)+S2Cl2(g)arrow_forward9.41 Under what conditions does the enthalpy change equal the heat of a process?arrow_forward
- A 0.470-g sample of magnesium reacts with 200 g dilute HCl in a coffee-cup calorimeter to form MgCl2(aq) and H2(g). The temperature increases by 10.9 C as the magnesium reacts. Assume that the mixture has the same specific heat as water and a mass of 200 g. (a) Calculate the enthalpy change for the reaction. Is the process exothermic or endothermic? (b) Write the chemical equation and evaluate H.arrow_forwardCalculate the standard enthalpy of combustion for benzene, C6H6. C6H6() + 15/2 O2(g) 6 CO2(g) + 3 H2O() rH = ? The enthalpy of formation of benzene is known [rH[C6H6()] = +49.0 kJ/mol], and other values needed can be found in Appendix L.arrow_forwardIn the process of isolating iron from its ores, carbon monoxide reacts with iron(III) oxide, as described by the following equation: Fe2O3(s)+3CO(g)2Fe(s)+3CO2(g)H=24.8kJ The enthalpy change for the combustion of carbon monoxide is 2CO(g)+O2(g)2CO2(g)H=566kJ Use this information to calculate the enthalpy change for the equation 4Fe(s)+3O2(g)2Fe2O3(s)H=?arrow_forward
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