Concept explainers
The sun supplies energy at a rate of about 1.0 kilowatt per square meter of surface area (1 watt = 1 J/s). The plants in an agricultural field produce the equivalent of 20. kg sucrose (C12H22O1l) per hour per hectare (1 ha = 10.000 m2). Assuming that sucrose is produced by the reaction
calculate the percentage of sunlight used to produce the sucrose—that is, determine the efficiency of photosynthesis.
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Chapter 7 Solutions
Chemistry: An Atoms First Approach
- A rebreathing gas mask contains potassium superoxide, KO2, which reacts with moisture in the breath to give oxygen. 4KO2(s)+2H2O(l)4KOH(s)+3O2(g) Estimate the grams of potassium superoxide required to supply a persons oxygen needs for one hour. Assume a person requires 1.00 102 kcal of energy for this time period. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 1.00 102 kcal of heat, calculate the amount of oxygen consumed and hence the amount of KO2 required. The ff0 for glucose(s) is 1273 kJ/mol.arrow_forwardThe equation for the fermentation of glucose to alcohol and carbon dioxide is: C6H12O6(aq) 2C2H5OH(aq) + 2CO2(g) The enthalpy change for the reaction is 67 kJ. Is this reaction exothermic or endothermic? Is energy, in the form of heat, absorbed or evolved as the reaction occurs?arrow_forwardThe carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.arrow_forward
- 4.60 Why are fuel additives used?arrow_forwardEthanol, C2H5OH, is a gasoline additive that can be produced by fermentation of glucose. C6H12O62C2H5OH+2CO2 (a) Calculate the mass (g) of ethanol produced by the fermentation of 1.000 lb glucose. (b) Gasohol is a mixture of 10.00 mL ethanol per 90.00 mL gasoline. Calculate the mass (in g) of glucose required to produce the ethanol in 1.00 gal gasohol. Density of ethanol = 0.785 g/mL. (c) By 2022, the U. S. Energy Independence and Security Act calls for annual production of 3.6 1010 gal of ethanol, no more than 40% of it produced by fermentation of corn. Fermentation of 1 ton (2.2 103 lb) of corn yields approximately 106 gal of ethanol. The average corn yield in the United States is about 2.1 105 lb per 1.0 105 m2. Calculate the acreage (in m2) required to raise corn solely for ethanol production in 2022 in the United States.arrow_forwardConsider the two space shuttle fuel reactions in Exercises 81 and 82. Which reaction produces more energy per kilogram of reactant mixture (stoichiometric amounts)? 81. The reusable booster rockets of the space shuttle use a mixture of aluminum and ammonium perchlorate as fuel. A possible reaction is 3Al(s)+3NH4ClO4(s)Al2O3(s)+AlCl3(s)+3NO(g)+6H2O(g) Calculate H for this reaction 82. The space shuttle Orbiter utilizes the oxidation of methylhydrazine by dinitrogen tetroxide for propulsion: 4N2H3CH3(l)+5N2O4(l)12H2O(g)+9N2(g)+4CO2(g) Calculate H for this reactionarrow_forward
- The enthalpy change for the reaction of hydrogen gas with fluorine gas (o produce hydrogen fluoride is 542 U for the equation as written: mg src=Images/HTML_99425-10-41QAP_image001.jpg alt="" align="top"/> l type='a'> What is the enthalpy change per mole of hydrogen fluoride produced? Is the reaction exothermic or endothermic as written? What would be the enthalpy change for the reverse of the given equation (that 1%, for the decomposition of HF into its constituent elements)?arrow_forwardThe reusable booster rockets of the space shuttle use a mixture of aluminum and ammonium perchlorate as fuel. A possible reaction is 3Al(s)+3NH4ClO4(s)Al2O3(s)+AlCl3(s)+3NO(g)+6H2O(g) Calculate H for this reactionarrow_forward4.61 What is actually measured by the octane ratings of different grades of gasoline?arrow_forward
- Consider the accompanying diagram. Ball A is allowed to fall and strike ball B. Assume that all of ball As energy is transferred to ball B at point I, and that there is no loss of energy to other sources. What is the kinetic energy and the potential energy of ball B at point II? The potential energy is given by PE = mgz, where m is the mass in kilograms, g is the gravitational constant (9.81 m/s2), and z is the distance in meters.arrow_forwardThe best solar panels currently available are about 15% efficient in converting sunlight to electricity. A typical home will use about 40. kWh of electricity per day (1 kWh = 1 kilowatt hour; 1kW = 1000 J/s). Assuming 8.0 hours of useful sunlight per day, calculate the minimum solar panel surface area necessary to provide all of a typical homes electricity. (See Exercise 124 for the energy rate supplied by the sun.)arrow_forwardWe burn 3.47 g lithium in excess oxygen at constant atmospheric pressure to form Li2O. Then, we bring the reaction mixture back to 25 C. In this process 146 kJ of heat is given off. Calculate the standard formation enthalpy of Li2O.arrow_forward
- General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
- Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning