A mechanism to explain each product of the given reaction is to be stated. Concept introduction: Substitution reaction involves the replacement of one functional group by another. In nucleophilic substitution reaction, the attack of nucleophile over positive charge or over the partially positively charged species occurs. This leads to the removal of weaker nucleophile.

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Answer 1

Question

Chapter 7, Problem 7.75SP

(a)

Interpretation Introduction

Interpretation:

A mechanism to explain each product of the given reaction is to be stated.

Concept introduction:

Substitution reaction involves the replacement of one functional group by another. In nucleophilic substitution reaction, the attack of nucleophile over positive charge or over the partially positively charged species occurs. This leads to the removal of weaker nucleophile.

(b)

Interpretation Introduction

Interpretation:

An explanation for the elimination rate is slower, but the substitution rate is unchanged is to be stated.

Concept introduction:

The rate of reaction depends upon the strength of chemical bond. The rate of reaction would be less if the chemical bond is strong.

(c)

Interpretation Introduction

Interpretation:

The mechanism for the formation of each product under given conditions is to be stated and the rate of formation of each product is to be predicted.

Concept introduction:

Substitution reaction involves the replacement of one functional group by another. In nucleophillic substitution reaction, the attack of nucleophille over positive charge or over the partially positively charged species occurs. This leads to the removal of weaker nucleophille.

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Experiment: Each team will be provided with 5g of a mixture of acetanilide and salicylic acid. You will divide it into three 1.5 g portions in separate 125 mL Erlenmeyer flasks savıng some for melting point analysis. Dissolve the mixture in each flask in ~60mL of DI water by heating to boiling on a hotplate. Take the flasks off the hotplate once you have a clear solution and let them stand on the bench top for 5 mins and then allow them to cool as described below. Sample A-Let the first sample cool slowly to room temperature by letting it stand on your lab bench, with occasional stirring to promote crystallization. Sample B-Cool the second sample 1n a tap-water bath to 10-15 °C Sample C-Cool the third sample in an ice-bath to 0-2 °C Results: weight after recrystalization and melting point temp. A=0.624g,102-115° B=0.765g, 80-105° C=1.135g, 77-108 What is the percent yield of A,B, and C.

Answer 2

Question

Chapter 7, Problem 7.75SP

(a)

Interpretation Introduction

Interpretation:

A mechanism to explain each product of the given reaction is to be stated.

Concept introduction:

Substitution reaction involves the replacement of one functional group by another. In nucleophilic substitution reaction, the attack of nucleophile over positive charge or over the partially positively charged species occurs. This leads to the removal of weaker nucleophile.

(b)

Interpretation Introduction

Interpretation:

An explanation for the elimination rate is slower, but the substitution rate is unchanged is to be stated.

Concept introduction:

The rate of reaction depends upon the strength of chemical bond. The rate of reaction would be less if the chemical bond is strong.

(c)

Interpretation Introduction

Interpretation:

The mechanism for the formation of each product under given conditions is to be stated and the rate of formation of each product is to be predicted.

Concept introduction:

Substitution reaction involves the replacement of one functional group by another. In nucleophillic substitution reaction, the attack of nucleophille over positive charge or over the partially positively charged species occurs. This leads to the removal of weaker nucleophille.

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Answer 3

Question

Chapter 7, Problem 7.75SP

(a)

Interpretation Introduction

Interpretation:

A mechanism to explain each product of the given reaction is to be stated.

Concept introduction:

Substitution reaction involves the replacement of one functional group by another. In nucleophilic substitution reaction, the attack of nucleophile over positive charge or over the partially positively charged species occurs. This leads to the removal of weaker nucleophile.

(b)

Interpretation Introduction

Interpretation:

An explanation for the elimination rate is slower, but the substitution rate is unchanged is to be stated.

Concept introduction:

The rate of reaction depends upon the strength of chemical bond. The rate of reaction would be less if the chemical bond is strong.

(c)

Interpretation Introduction

Interpretation:

The mechanism for the formation of each product under given conditions is to be stated and the rate of formation of each product is to be predicted.

Concept introduction:

Substitution reaction involves the replacement of one functional group by another. In nucleophillic substitution reaction, the attack of nucleophille over positive charge or over the partially positively charged species occurs. This leads to the removal of weaker nucleophille.

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Answer 4

Question

Chapter 7, Problem 7.75SP

(a)

Interpretation Introduction

Interpretation:

A mechanism to explain each product of the given reaction is to be stated.

Concept introduction:

Substitution reaction involves the replacement of one functional group by another. In nucleophilic substitution reaction, the attack of nucleophile over positive charge or over the partially positively charged species occurs. This leads to the removal of weaker nucleophile.

(b)

Interpretation Introduction

Interpretation:

An explanation for the elimination rate is slower, but the substitution rate is unchanged is to be stated.

Concept introduction:

The rate of reaction depends upon the strength of chemical bond. The rate of reaction would be less if the chemical bond is strong.

(c)

Interpretation Introduction

Interpretation:

The mechanism for the formation of each product under given conditions is to be stated and the rate of formation of each product is to be predicted.

Concept introduction:

Substitution reaction involves the replacement of one functional group by another. In nucleophillic substitution reaction, the attack of nucleophille over positive charge or over the partially positively charged species occurs. This leads to the removal of weaker nucleophille.

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Answer 5

Chapter 7, Problem 7.75SP

(a)

Interpretation Introduction

Interpretation:

A mechanism to explain each product of the given reaction is to be stated.

Concept introduction:

Substitution reaction involves the replacement of one functional group by another. In nucleophilic substitution reaction, the attack of nucleophile over positive charge or over the partially positively charged species occurs. This leads to the removal of weaker nucleophile.

(b)

Interpretation Introduction

Interpretation:

An explanation for the elimination rate is slower, but the substitution rate is unchanged is to be stated.

Concept introduction:

The rate of reaction depends upon the strength of chemical bond. The rate of reaction would be less if the chemical bond is strong.

(c)

Interpretation Introduction

Interpretation:

The mechanism for the formation of each product under given conditions is to be stated and the rate of formation of each product is to be predicted.

Concept introduction:

Substitution reaction involves the replacement of one functional group by another. In nucleophillic substitution reaction, the attack of nucleophille over positive charge or over the partially positively charged species occurs. This leads to the removal of weaker nucleophille.

Answer 6

Chapter 7, Problem 7.75SP

(a)

Interpretation Introduction

Interpretation:

A mechanism to explain each product of the given reaction is to be stated.

Concept introduction:

Substitution reaction involves the replacement of one functional group by another. In nucleophilic substitution reaction, the attack of nucleophile over positive charge or over the partially positively charged species occurs. This leads to the removal of weaker nucleophile.

Answer 7

Chapter 7, Problem 7.75SP

(a)

Interpretation Introduction

Interpretation:

A mechanism to explain each product of the given reaction is to be stated.

Concept introduction:

Substitution reaction involves the replacement of one functional group by another. In nucleophilic substitution reaction, the attack of nucleophile over positive charge or over the partially positively charged species occurs. This leads to the removal of weaker nucleophile.

Answer 8

(b)

Interpretation Introduction

Interpretation:

An explanation for the elimination rate is slower, but the substitution rate is unchanged is to be stated.

Concept introduction:

The rate of reaction depends upon the strength of chemical bond. The rate of reaction would be less if the chemical bond is strong.

Answer 9

(b)

Interpretation Introduction

Interpretation:

An explanation for the elimination rate is slower, but the substitution rate is unchanged is to be stated.

Concept introduction:

The rate of reaction depends upon the strength of chemical bond. The rate of reaction would be less if the chemical bond is strong.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The mechanism for the formation of each product under given conditions is to be stated and the rate of formation of each product is to be predicted.

Concept introduction:

Substitution reaction involves the replacement of one functional group by another. In nucleophillic substitution reaction, the attack of nucleophille over positive charge or over the partially positively charged species occurs. This leads to the removal of weaker nucleophille.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The mechanism for the formation of each product under given conditions is to be stated and the rate of formation of each product is to be predicted.

Concept introduction:

Substitution reaction involves the replacement of one functional group by another. In nucleophillic substitution reaction, the attack of nucleophille over positive charge or over the partially positively charged species occurs. This leads to the removal of weaker nucleophille.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 7.3A - Prob. 7.1P Ch. 7.3A - Prob. 7.2P Ch. 7.3B - Draw five more compounds of formula C4H6NOC1.Ch. 7.3B - For each of the following molecular formulas,...Ch. 7.4 - Give the systematic (IUPAC) names of the following...Ch. 7.5B - The following names are all incorrect. Draw the...Ch. 7.5B - Prob. 7.8P Ch. 7.5B - a. How many stereogcmc double bonds are in...Ch. 7.6 - Teflon-coated frying pans routinely endure...Ch. 7.7B - Prob. 7.11P

Solution Summary: The author explains the mechanism for the formation of each product under given conditions and the rate of substitution reaction is unchanged.

Interpretation:

An explanation for the elimination rate is slower, but the substitution rate is unchanged is to be stated.

Concept introduction:

The rate of reaction depends upon the strength of chemical bond. The rate of reaction would be less if the chemical bond is strong.

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Chapter 7 Solutions

Solution Summary: The author explains the mechanism for the formation of each product under given conditions and the rate of substitution reaction is unchanged.

Interpretation: An explanation for the elimination rate is slower, but the substitution rate is unchanged is to be stated. Concept introduction: The rate of reaction depends upon the strength of chemical bond. The rate of reaction would be less if the chemical bond is strong.

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Chapter 7 Solutions

Interpretation:

An explanation for the elimination rate is slower, but the substitution rate is unchanged is to be stated.

Concept introduction:

The rate of reaction depends upon the strength of chemical bond. The rate of reaction would be less if the chemical bond is strong.