The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the aldohexose has to be identified. Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group. Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Question

4. Provide a clear arrow-pushing mechanism for each of the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. 2. 1. LDA 3. H3O+ HO

Answer 1

Question

Chapter 7, Problem 7.68EP

(a)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the aldohexose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(b)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the aldopentose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(c)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the ketohexose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(d)

Interpretation Introduction

Interpretation: The ketopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

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4. Provide a clear arrow-pushing mechanism for each of the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. 2. 1. LDA 3. H3O+ HO

b. H3C CH3 H3O+ ✓ H OH

2. Provide reagents/conditions to accomplish the following syntheses. More than one step is required in some cases. a. CH3

Answer 2

Question

Chapter 7, Problem 7.68EP

(a)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the aldohexose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(b)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the aldopentose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(c)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the ketohexose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(d)

Interpretation Introduction

Interpretation: The ketopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

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Answer 3

Question

Chapter 7, Problem 7.68EP

(a)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the aldohexose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(b)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the aldopentose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(c)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the ketohexose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(d)

Interpretation Introduction

Interpretation: The ketopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

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Answer 4

Question

Chapter 7, Problem 7.68EP

(a)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the aldohexose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(b)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the aldopentose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(c)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the ketohexose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(d)

Interpretation Introduction

Interpretation: The ketopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

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Answer 5

Chapter 7, Problem 7.68EP

(a)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the aldohexose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(b)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the aldopentose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(c)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the ketohexose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(d)

Interpretation Introduction

Interpretation: The ketopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 6

Chapter 7, Problem 7.68EP

(a)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the aldohexose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 7

Chapter 7, Problem 7.68EP

(a)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the aldohexose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 8

(b)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the aldopentose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 9

(b)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the aldopentose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 10

(c)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the ketohexose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 11

(c)

Interpretation Introduction

Interpretation: The two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the ketohexose has to be identified.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 12

(d)

Interpretation Introduction

Interpretation: The ketopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 13

(d)

Interpretation Introduction

Interpretation: The ketopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 14

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Answer 25

Ch. 7.1 - In terms of mass percent, which of the following...Ch. 7.1 - Which of the following is the most abundant type...Ch. 7.2 - Which of the following statements concerning the...Ch. 7.2 - Prob. 2QQ Ch. 7.3 - Prob. 1QQ Ch. 7.3 - Prob. 2QQ Ch. 7.3 - Which of the following is not a possible value for...Ch. 7.3 - The complete hydrolysis of a polysaccharide...Ch. 7.4 - Prob. 1QQ Ch. 7.4 - Prob. 2QQ

Solution Summary: The author explains the two carbon atoms that bear the functional groups which interacts during intramolecular cyclization of the aldohexose.

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