The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers. Concept Introduction: Each electron in an atom is described by four different quantum numbers. The first three (n, l, m l ) specify the particular orbital of interest, and the fourth (m s ) specifies how many electrons can occupy that orbital. Principal Quantum Number (n) The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell ( level ). The total number of orbitals for a given n value is n 2 . As the value of ‘n’ increases, the energy of the electron also increases. Angular Momentum Quantum Number (l) The angular momentum quantum number (l) explains the shape of the atomic orbital . The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel) . The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f). Magnetic Quantum Number (m l ) The magnetic quantum number (m l ) explains the orientation of the orbital in space . The value of m l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m l which is explained as follows: m l = ‒ l, ..., 0, ..., +l If l = 0, there is only one possible value of m l : 0. If l = 1, then there are three values of m l : −1, 0, and +1. If l = 2, there are five values of m l , namely, −2, −1, 0, +1, and +2. If l = 3, there are seven values of m l , namely, −3, −2, −1, 0, +1, +2, and +3, and so on. The number of m l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m l value refers to a different orbital. Electron Spin Quantum Number (m s ) It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number. To find: Get the values of the quantum numbers (n, l, m l , m s ) associated with the given orbital (a) 3s Get the values of the quantum numbers ‘n’, ‘l’ in (a)

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Answer 1

Question

Chapter 7, Problem 7.56QP

(a)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (a) 3s

Get the values of the quantum numbers ‘n’, ‘l’ in (a)

(b)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (b) 4p

Get the values of the quantum numbers ‘n’, ‘l’ in (b)

(c)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (c) 3d

Get the values of the quantum numbers ‘n’, ‘l’ in (c)

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Consider the reaction: 2 A (aq) ⇌ B(aq) Given the following KC values and starting with the initial concentration of A = 4.00 M, complete ICE diagram(s)and find the equilibrium concentrations for A and B.A) KC = 4.00B) KC = 200C) KC = 8.00 x10-3

5) Consider the reaction: Cl2 (g) + F2 (g) ⟷ 2 ClF (g) KP=? The partial pressure of 203 kPa for Cl2 and a partial pressure of 405 kPa for F2. Upon reaching equilibrium, thepartial pressure of ClF is 180 kPa. Calculate the equilibrium concentrations and then find the value for KP.

Answer 2

Question

Chapter 7, Problem 7.56QP

(a)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (a) 3s

Get the values of the quantum numbers ‘n’, ‘l’ in (a)

(b)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (b) 4p

Get the values of the quantum numbers ‘n’, ‘l’ in (b)

(c)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (c) 3d

Get the values of the quantum numbers ‘n’, ‘l’ in (c)

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 7, Problem 7.56QP

(a)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (a) 3s

Get the values of the quantum numbers ‘n’, ‘l’ in (a)

(b)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (b) 4p

Get the values of the quantum numbers ‘n’, ‘l’ in (b)

(c)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (c) 3d

Get the values of the quantum numbers ‘n’, ‘l’ in (c)

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 7, Problem 7.56QP

(a)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (a) 3s

Get the values of the quantum numbers ‘n’, ‘l’ in (a)

(b)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (b) 4p

Get the values of the quantum numbers ‘n’, ‘l’ in (b)

(c)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (c) 3d

Get the values of the quantum numbers ‘n’, ‘l’ in (c)

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 7, Problem 7.56QP

(a)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (a) 3s

Get the values of the quantum numbers ‘n’, ‘l’ in (a)

(b)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (b) 4p

Get the values of the quantum numbers ‘n’, ‘l’ in (b)

(c)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (c) 3d

Get the values of the quantum numbers ‘n’, ‘l’ in (c)

Answer 6

Chapter 7, Problem 7.56QP

(a)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (a) 3s

Get the values of the quantum numbers ‘n’, ‘l’ in (a)

Answer 7

Chapter 7, Problem 7.56QP

(a)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (a) 3s

Get the values of the quantum numbers ‘n’, ‘l’ in (a)

Answer 8

(b)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (b) 4p

Get the values of the quantum numbers ‘n’, ‘l’ in (b)

Answer 9

(b)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (b) 4p

Get the values of the quantum numbers ‘n’, ‘l’ in (b)

Answer 10

(c)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (c) 3d

Get the values of the quantum numbers ‘n’, ‘l’ in (c)

Answer 11

(c)

Interpretation Introduction

Interpretation:

The values of the quantum numbers associated with the given orbitals should be identified using the concept of quantum numbers.

Concept Introduction:

Each electron in an atom is described by four different quantum numbers. The first three (n, l, m_l) specify the particular orbital of interest, and the fourth (m_s) specifies how many electrons can occupy that orbital.

Principal Quantum Number (n)

The principal quantum number (n) assigns the size of the orbital and specifies the energy of an electron. If the value of n is larger, then the average distance of an electron in the orbital from the nucleus will be greater. Therefore the size of the orbital is large. The principal quantum numbers have the integral values of 1, 2, 3 and so forth and it corresponds to the quantum number in Bohr’s model of the hydrogen atom. If all orbitals have the same value of ‘n’, they are said to be in the same shell (level). The total number of orbitals for a given n value is n². As the value of ‘n’ increases, the energy of the electron also increases.

Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) explains the shape of the atomic orbital. The values of l are integers which depend on the value of the principal quantum number, n. For a given value of n, the possible values of l range are from 0 to n − 1. If n = 1, there is only one possible value of l (l=0). If n = 2, there are two values of l: 0 and 1. If n = 3, there are three values of l: 0, 1, and 2. The value of l is selected by the letters s, p, d, and f. If l = 0, we have an s orbital; if l = 1, we have a p orbital; if l = 2, we have a d orbital and finally if l = 3, we have a f orbital. A collection of orbitals with the same value of n is called a shell. One or more orbitals with the same n and l values are referred to a subshell (sublevel). The value of l also has a slight effect on the energy of the subshell; the energy of the subshell increases with l (s < p < d < f).

Magnetic Quantum Number (m_l)

The magnetic quantum number (m_l) explains the orientation of the orbital in space. The value of m_l depends on the value of l in a subshell. This number divides the subshell into individual orbitals which hold the electrons. For a certain value of l, there are (2l + 1) integral values of m_l which is explained as follows:

m_l = ‒ l, ..., 0, ..., +l

If l = 0, there is only one possible value of m_l: 0.

If l = 1, then there are three values of m_l: −1, 0, and +1.

If l = 2, there are five values of m_l, namely, −2, −1, 0, +1, and +2.

If l = 3, there are seven values of m_l, namely, −3, −2, −1, 0, +1, +2, and +3, and so on.

The number of m_l values indicates the number of orbitals in a subshell with a particular l value. Therefore, each m_l value refers to a different orbital.

Electron Spin Quantum Number (m_s)

It specifies the orientation of the spin axis of an electron. An electron can spin in only one of two directions. There are two possible ways to represent m_s values. They are +½ and ‒½. One electron spins in the clockwise direction. Another electron spins in the anticlockwise direction. But, no two electrons should have the same spin quantum number.

To find: Get the values of the quantum numbers (n, l, m_l, m_s) associated with the given orbital (c) 3d

Get the values of the quantum numbers ‘n’, ‘l’ in (c)

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 7.1 - Review of Concepts What of the waves shown here...Ch. 7.1 - Prob. 1PE Ch. 7.1 - Prob. 2RC Ch. 7.2 - Prob. 1PE Ch. 7.2 - Prob. 2PE Ch. 7.2 - Prob. 1RC Ch. 7.3 - Prob. 1PE Ch. 7.3 - Prob. 1RC Ch. 7.4 - Prob. 1PE Ch. 7.4 - Prob. 1RC

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