(a) Interpretation: A structural formula for anisole should be drawn showing positions of multiple bonds and lone pairs. Concept introduction: The strategy for identifying multiple bonds and lone pairs in an organic molecule is to look at each atom of the structure, what is needed to complete their octet and a bond or a lone pair, (except hydrogen) should be determined. Elements in the different groups of the periodic table can form a different number of bonds.
(a) Interpretation: A structural formula for anisole should be drawn showing positions of multiple bonds and lone pairs. Concept introduction: The strategy for identifying multiple bonds and lone pairs in an organic molecule is to look at each atom of the structure, what is needed to complete their octet and a bond or a lone pair, (except hydrogen) should be determined. Elements in the different groups of the periodic table can form a different number of bonds.
Solution Summary: The author explains that a structural formula for anisole should be drawn showing positions of multiple bonds and lone pairs in an organic molecule.
A structural formula for anisole should be drawn showing positions of multiple bonds and lone pairs.
Concept introduction:
The strategy for identifying multiple bonds and lone pairs in an organic molecule is to look at each atom of the structure, what is needed to complete their octet and a bond or a lone pair, (except hydrogen) should be determined. Elements in the different groups of the periodic table can form a different number of bonds.
Interpretation Introduction
(b)
Interpretation:
Using curved arrows, the method of converting between the original structure and two additional resonance structures should be shown.
Concept introduction:
Resonance structures are two or more electron-dot structures that describe the electronic bonding of a particular molecule. Resonance structures can be used to indicate the delocalized electrons which cannot be shown by a single electron-dot structure. The average of all resonance structures is called resonance hybrid.
What spectral features allow you to differentiate the product from the starting material?
Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR.
2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too.
3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.
Question 6
What is the major product of the following Diels-Alder reaction?
?
Aldy by day of
A.
H
о
B.
C.
D.
E.
OB
OD
Oc
OE
OA
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