(a) Interpretation: A structural formula for anisole should be drawn showing positions of multiple bonds and lone pairs. Concept introduction: The strategy for identifying multiple bonds and lone pairs in an organic molecule is to look at each atom of the structure, what is needed to complete their octet and a bond or a lone pair, (except hydrogen) should be determined. Elements in the different groups of the periodic table can form a different number of bonds.
(a) Interpretation: A structural formula for anisole should be drawn showing positions of multiple bonds and lone pairs. Concept introduction: The strategy for identifying multiple bonds and lone pairs in an organic molecule is to look at each atom of the structure, what is needed to complete their octet and a bond or a lone pair, (except hydrogen) should be determined. Elements in the different groups of the periodic table can form a different number of bonds.
Solution Summary: The author explains that a structural formula for anisole should be drawn showing positions of multiple bonds and lone pairs in an organic molecule.
A structural formula for anisole should be drawn showing positions of multiple bonds and lone pairs.
Concept introduction:
The strategy for identifying multiple bonds and lone pairs in an organic molecule is to look at each atom of the structure, what is needed to complete their octet and a bond or a lone pair, (except hydrogen) should be determined. Elements in the different groups of the periodic table can form a different number of bonds.
Interpretation Introduction
(b)
Interpretation:
Using curved arrows, the method of converting between the original structure and two additional resonance structures should be shown.
Concept introduction:
Resonance structures are two or more electron-dot structures that describe the electronic bonding of a particular molecule. Resonance structures can be used to indicate the delocalized electrons which cannot be shown by a single electron-dot structure. The average of all resonance structures is called resonance hybrid.
21.38 Arrange the molecules in each set in order of increasing acidity (from least acidic to
most acidic).
OH
OH
SH
NH2
8
NH3
OH
(b)
OH
OH
OH
(c)
& & &
CH3
NO2
21.39 Explain the trends in the acidity of phenol and the monofluoro derivatives of phenol.
OH
OH
OH
OH
PK 10.0
PK 8.81
PK 9.28
PK 9.81
identify which spectrum is for acetaminophen and which is for phenacetin
The Concept of Aromaticity
21.15 State the number of 2p orbital electrons in each molecule or ion.
(a)
(b)
(e)
(f)
(c)
(d)
(h)
(i)
DA
(k)
21.16 Which of the molecules and ions given in Problem 21.15 are aromatic according to the
Hückel criteria? Which, if planar, would be antiaromatic?
21.17 Which of the following structures are considered aromatic according to the Hückel
criteria?
---0-0
(a)
(b)
(c)
(d)
(e)
(h)
H
-H
.8.0-
21.18 Which of the molecules and ions from Problem 21.17 have electrons donated by a
heteroatom?
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