The alkyl halide which is used in the given E2 reaction has to be drawn. Concept Introduction: Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E 1 (the reaction depends only on the substrate involved in the reaction) or E 2 (the reaction depends on both of the substituents in the reaction) mechanism. In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β -proton and one α -halo group of the alkyl halide. The double bond is located between α , β -carbons. The product of the elimination reaction is depends upon the β -positions of alkyl halide. If the β-positions are identical and the products formed are also identical . If the β-positions are different and the products formed are also different . This means the double bond can form in two different regions, so it will give different alkene products.

Question

* Hint: Think back to Chem 1 solubility rules. Follow Up Questions for Part B 12. What impact do the following disturbances to a system at equilibrium have on k, the rate constant for the forward reaction? Explain. (4 pts) a) Changing the concentration of a reactant or product. (2 pts) b) Changing the temperature of an exothermic reaction. (2 pts) of

Answer 1

Question

Chapter 7, Problem 65PP

(a)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

(b)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

(c)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

(d)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

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Answer 2

Question

Chapter 7, Problem 65PP

(a)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

(b)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

(c)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

(d)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

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Answer 3

Question

Chapter 7, Problem 65PP

(a)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

(b)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

(c)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

(d)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

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Answer 4

Question

Chapter 7, Problem 65PP

(a)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

(b)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

(c)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

(d)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

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Answer 5

Chapter 7, Problem 65PP

(a)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

(b)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

(c)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

(d)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

Answer 6

Chapter 7, Problem 65PP

(a)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

Answer 7

Chapter 7, Problem 65PP

(a)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The alkyl halide which is used in the given E2 reaction has to be drawn.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

In an elimination reaction, alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α -halo group of the alkyl halide. The double bond is located between α,β-carbons.

The product of the elimination reaction is depends upon the β-positions of alkyl halide. If the β-positions are identical and the products formed are also identical. If the β-positions are different and the products formed are also different. This means the double bond can form in two different regions, so it will give different alkene products.

Answer 14

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Ch. 7.2 - Prob. 1CC Ch. 7.3 - Prob. 2CC Ch. 7.3 - Prob. 1LTS Ch. 7.3 - Prob. 3PTS Ch. 7.3 - Prob. 4ATS Ch. 7.3 - Prob. 2LTS Ch. 7.3 - Prob. 5PTS Ch. 7.3 - Prob. 6ATS Ch. 7.3 - Prob. 7CC Ch. 7.4 - Prob. 8CC

Chapter 7 Solutions