Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 7, Problem 46PP
Interpretation Introduction
Interpretation: The transition state for the given reaction should be drawn.
Concept Introduction:
Transition State: The state which defines the highest potential energy with respect to reaction co-ordinate between reactant and product. It is usually denoted by using the symbol ‘≠’.
Leaving group: it is the fragment that leaves the substrate in a
Nucleophile: donates pair of electrons to positively charged substrate resulting in the formation of
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Students have asked these similar questions
What are the IUPAC Names of all the compounds in the picture?
1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following
compounds. Please show your work. (8) SF2, CH,OH, C₂H₂
b) Based on your answers given above, list the compounds in order of their Boiling Point
from low to high. (8)
19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Chapter 7 Solutions
Organic Chemistry
Ch. 7.2 - Prob. 1CCCh. 7.3 - Prob. 1LTSCh. 7.3 - Prob. 2PTSCh. 7.3 - Prob. 3PTSCh. 7.3 - Prob. 4ATSCh. 7.3 - Prob. 5ATSCh. 7.4 - Prob. 6CCCh. 7.4 - Prob. 2LTSCh. 7.4 - Prob. 7PTSCh. 7.4 - Prob. 8ATS
Ch. 7.4 - Prob. 3LTSCh. 7.4 - Prob. 9PTSCh. 7.4 - Prob. 10ATSCh. 7.4 - Prob. 11ATSCh. 7.4 - Prob. 12CCCh. 7.5 - Prob. 13CCCh. 7.5 - Prob. 4LTSCh. 7.5 - Prob. 14PTSCh. 7.5 - Prob. 15ATSCh. 7.5 - Prob. 5LTSCh. 7.5 - Prob. 16PTSCh. 7.5 - Prob. 17ATSCh. 7.6 - Prob. 18CCCh. 7.6 - Prob. 19CCCh. 7.6 - Prob. 20CCCh. 7.6 - Prob. 6LTSCh. 7.6 - Prob. 21PTSCh. 7.6 - Prob. 22ATSCh. 7.6 - Prob. 23ATSCh. 7.7 - Prob. 7LTSCh. 7.7 - Prob. 24PTSCh. 7.7 - Prob. 25ATSCh. 7.8 - Prob. 26CCCh. 7.8 - Prob. 27CCCh. 7.8 - Prob. 28CCCh. 7.8 - Prob. 29CCCh. 7.8 - Prob. 30CCCh. 7.8 - Prob. 8LTSCh. 7.8 - Prob. 31PTSCh. 7.8 - Prob. 32ATSCh. 7.9 - Prob. 9LTSCh. 7.9 - Prob. 33PTSCh. 7.9 - Prob. 34ATSCh. 7.9 - Prob. 35CCCh. 7 - Prob. 36PPCh. 7 - Prob. 37PPCh. 7 - Prob. 38PPCh. 7 - Prob. 39PPCh. 7 - Prob. 40PPCh. 7 - Prob. 41PPCh. 7 - Prob. 42PPCh. 7 - Prob. 43PPCh. 7 - Prob. 44PPCh. 7 - Prob. 45PPCh. 7 - Prob. 46PPCh. 7 - Prob. 47PPCh. 7 - Prob. 48PPCh. 7 - Prob. 49PPCh. 7 - Prob. 50PPCh. 7 - Prob. 51PPCh. 7 - Prob. 52PPCh. 7 - Prob. 53PPCh. 7 - Prob. 54PPCh. 7 - Prob. 55PPCh. 7 - Prob. 56PPCh. 7 - Prob. 57PPCh. 7 - Prob. 58PPCh. 7 - Prob. 59PPCh. 7 - Prob. 60PPCh. 7 - Prob. 61PPCh. 7 - Prob. 62PPCh. 7 - Prob. 63PPCh. 7 - Prob. 64IPCh. 7 - Prob. 65IPCh. 7 - Prob. 66IPCh. 7 - Prob. 67IPCh. 7 - Prob. 68IPCh. 7 - Prob. 69IPCh. 7 - Prob. 70IPCh. 7 - Prob. 71IPCh. 7 - Prob. 72IPCh. 7 - Prob. 73IPCh. 7 - Prob. 74IPCh. 7 - Prob. 75IPCh. 7 - Prob. 76IP
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