Concept explainers
Interpretation:
The reason should be determined for not forming an amide during the condensation of tertiary
Concept Introduction:
Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and
The compound containsat least one nitrogen atom (with one lone pair of electrons) which is linked with hydrogen atoms or alkyl or aryl groups are known as amine.It is a derivative of ammonia.
Amides: These are the derivatives of carboxylic acids in which the hydroxyl group is replaced by an ammonia or amine.
In carboxylic acid, carbonyl carbon is linked to carbon or hydrogen on one side and on other side linked to a heteroatom such as O, N, S. The general formula is RCOOH, where R is an alkyl group.
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Chapter 7 Solutions
PRINCIPLES OF MODERN CHEMISTRY-OWLV2
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- Write the systematic (IUPAC) names for the amines. The names should have the format alkanamine. H₂C-N-CH3 H3C-CH2-CH-CH3 systematic (IUPAC) name: HC-N-CH2-CH3 HC-CH2-CH2-CH₂ systematic (IUPAC) name: These compounds are amines.arrow_forwardH₂C Carboxylic Acid Acid anhydride CHÍNH, CH₂ H₂O H3C Amide CHÍNH, LIAIH, CHÍNH, Acid chloride Amine Esterarrow_forwardThree amide isomers, N,N-dimethylformamide, N-methylacetamide, and propanamide, have respective boiling points of 153 °C (426 K), 202 °C (475 K), and 213 °C (486 K). Explain these boiling points in light of their structural formulas.arrow_forward
- Write the systematic (IUPAC) names for the amines. The names should have the format alkanamine.arrow_forwardThe C-N distance in an amide bond is approximately 1.32 Å. A typical C-N single bond is 1.45Å, while a typical C=N double bond is 1.25 Å. Explain this observation and describe how thebonding in amides restricts the conformations amides can adopt.arrow_forwardWrite both condensed and line structures for (a) the ester formed when butyric acid reacts with cyclopentanol, (b) the amide formed when isopropyl amine is reacted with butyric acid, and (c) the amide formed when diethylamine is reacted with butyric acid.arrow_forward
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