Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Chapter 7, Problem 19Q
Interpretation Introduction
Interpretation:
The two advantage offered by hydrogen FCVs have to be listed.
Concept Introduction:
An
Fuel cell vehicles (FCVs) have the potential to significantly reduce our dependence on engine oil and lower harmful emission that cause climate change. FCVs run on hydrogen gas rather than gasoline and emit no harmful emission.
Fuel cell is an electrochemical cell which converts chemical energy contained in readily available fuel oxidant system into electrical energy.
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Draw the anti-Markovnikov product of the hydration of this alkene.
this problem.
Note for advanced students: draw only one product, and don't worry about showing any stereochemistry. Drawing dash and wedge bonds has been disabled for
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Explanation
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 7 Solutions
Chemistry In Context
Ch. 7.1 - Prob. 7.2YTCh. 7.2 - Skill Building Coulombs The SI unit of electric...Ch. 7.2 - Prob. 7.4YTCh. 7.4 - Prob. 7.5YTCh. 7.4 - Scientific Practices The Shift from NiCd to NiMH...Ch. 7.5 - Scientific Practices The Battery in Your Car Lets...Ch. 7.7 - Prob. 7.9YTCh. 7.8 - Prob. 7.10YTCh. 7.9 - Prob. 7.11YTCh. 7.9 - Prob. 7.12YT
Ch. 7.10 - Prob. 7.13YTCh. 7.10 - Prob. 7.14YTCh. 7.11 - Skill Building Metal Refining (Smelting) The...Ch. 7.11 - You Decide Could Metals Become Extinct? In 2015,...Ch. 7.11 - Prob. 7.17YTCh. 7 - You Decide The Baghdad Battery Alessandro Volta is...Ch. 7 - Prob. 1QCh. 7 - Prob. 2QCh. 7 - Which chemical species gets oxidized and which...Ch. 7 - What is the difference between a galvanic cell and...Ch. 7 - Two common units associated with electricity are...Ch. 7 - Consider the galvanic cell pictured. A coating of...Ch. 7 - Prob. 7QCh. 7 - a. How does the voltage from a tiny AAA alkaline...Ch. 7 - Identify the type of galvanic cell commonly used...Ch. 7 - The mercury battery has been used extensively in...Ch. 7 - Prob. 12QCh. 7 - During the conversion of O2(g) to H2O(l) in a fuel...Ch. 7 - How does the reaction between hydrogen and oxygen...Ch. 7 - This diagram represents the hydrogen fuel cell...Ch. 7 - What is a PEM fuel cell? How does it differ from...Ch. 7 - How do PEM fuel cells allow H2 and O2 to combine...Ch. 7 - In addition to hydrogen, methane also has been...Ch. 7 - Prob. 19QCh. 7 - Potassium and lithium both are reactive Group 1...Ch. 7 - What challenges keep hydrogen fuel cells from...Ch. 7 - Explain the concept of energy density of a battery...Ch. 7 - Describe how a normal AA battery stores and...Ch. 7 - Prob. 24QCh. 7 - What is the difference between an electrolytic...Ch. 7 - Provide some differences between a leadacid...Ch. 7 - Describe the importance of a separator in primary...Ch. 7 - The company ZPower is promoting its silverzinc...Ch. 7 - Prob. 29QCh. 7 - Prob. 30QCh. 7 - Describe some advantages and disadvantages of...Ch. 7 - You never need to plug in Toyotas gasolinebattery...Ch. 7 - Prob. 33QCh. 7 - Hydrogen is considered an environmentally friendly...Ch. 7 - Fuel cells were invented in 1839 but never...Ch. 7 - Hydrogen and methane both can react with oxygen in...Ch. 7 - Engineers have developed a prototype fuel cell...Ch. 7 - Prob. 38QCh. 7 - Describe some similarities and differences between...Ch. 7 - Prob. 40QCh. 7 - Prob. 41QCh. 7 - Prob. 42QCh. 7 - Small quantities of hydrogen gas can be prepared...Ch. 7 - Prob. 44QCh. 7 - Although Alessandro Volta is credited with the...Ch. 7 - Prob. 46QCh. 7 - Prob. 47QCh. 7 - What is the tragedy of the commons? How does this...Ch. 7 - How can the principles of green chemistry be...Ch. 7 - If all of todays technology presently based on...Ch. 7 - Consider these three sources of light: a candle, a...Ch. 7 - Prob. 52Q
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