Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Chapter 7, Problem 35Q
Fuel cells were invented in 1839 but never developed into practical devices for producing electric energy until the U.S. space program in the 1960s. What advantages did fuel cells have over previous power sources?
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Given the cell: Pt l H2(g) l dis X:KCl (sat) l Hg2Cl2(s) l Hg l Pt. Calculate the emf of the cell as a function of pH.
The decimolar calomel electrode has a potential of 0.3335 V at 25°C compared to the standard hydrogen electrode. If the standard reduction potential of Hg22+ is 0.7973 V and the solubility product of Hg2Cl2 is 1.2x 10-18, find the activity of the chlorine ion at this electrode.Data: R = 8.314 J K-1 mol-1, F = 96485 C mol-1, T = 298.15 K.
2.
Add the following group of numbers using the correct number of significant figures for the
answer. Show work to earn full credit such as rounding off the answer to the correct number
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the calculated answers near the question marks.
10916.345
37.40832
5.4043
3.94
+
0.0426
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(7 significant figures)
Chapter 7 Solutions
Chemistry In Context
Ch. 7.1 - Prob. 7.2YTCh. 7.2 - Skill Building Coulombs The SI unit of electric...Ch. 7.2 - Prob. 7.4YTCh. 7.4 - Prob. 7.5YTCh. 7.4 - Scientific Practices The Shift from NiCd to NiMH...Ch. 7.5 - Scientific Practices The Battery in Your Car Lets...Ch. 7.7 - Prob. 7.9YTCh. 7.8 - Prob. 7.10YTCh. 7.9 - Prob. 7.11YTCh. 7.9 - Prob. 7.12YT
Ch. 7.10 - Prob. 7.13YTCh. 7.10 - Prob. 7.14YTCh. 7.11 - Skill Building Metal Refining (Smelting) The...Ch. 7.11 - You Decide Could Metals Become Extinct? In 2015,...Ch. 7.11 - Prob. 7.17YTCh. 7 - You Decide The Baghdad Battery Alessandro Volta is...Ch. 7 - Prob. 1QCh. 7 - Prob. 2QCh. 7 - Which chemical species gets oxidized and which...Ch. 7 - What is the difference between a galvanic cell and...Ch. 7 - Two common units associated with electricity are...Ch. 7 - Consider the galvanic cell pictured. A coating of...Ch. 7 - Prob. 7QCh. 7 - a. How does the voltage from a tiny AAA alkaline...Ch. 7 - Identify the type of galvanic cell commonly used...Ch. 7 - The mercury battery has been used extensively in...Ch. 7 - Prob. 12QCh. 7 - During the conversion of O2(g) to H2O(l) in a fuel...Ch. 7 - How does the reaction between hydrogen and oxygen...Ch. 7 - This diagram represents the hydrogen fuel cell...Ch. 7 - What is a PEM fuel cell? How does it differ from...Ch. 7 - How do PEM fuel cells allow H2 and O2 to combine...Ch. 7 - In addition to hydrogen, methane also has been...Ch. 7 - Prob. 19QCh. 7 - Potassium and lithium both are reactive Group 1...Ch. 7 - What challenges keep hydrogen fuel cells from...Ch. 7 - Explain the concept of energy density of a battery...Ch. 7 - Describe how a normal AA battery stores and...Ch. 7 - Prob. 24QCh. 7 - What is the difference between an electrolytic...Ch. 7 - Provide some differences between a leadacid...Ch. 7 - Describe the importance of a separator in primary...Ch. 7 - The company ZPower is promoting its silverzinc...Ch. 7 - Prob. 29QCh. 7 - Prob. 30QCh. 7 - Describe some advantages and disadvantages of...Ch. 7 - You never need to plug in Toyotas gasolinebattery...Ch. 7 - Prob. 33QCh. 7 - Hydrogen is considered an environmentally friendly...Ch. 7 - Fuel cells were invented in 1839 but never...Ch. 7 - Hydrogen and methane both can react with oxygen in...Ch. 7 - Engineers have developed a prototype fuel cell...Ch. 7 - Prob. 38QCh. 7 - Describe some similarities and differences between...Ch. 7 - Prob. 40QCh. 7 - Prob. 41QCh. 7 - Prob. 42QCh. 7 - Small quantities of hydrogen gas can be prepared...Ch. 7 - Prob. 44QCh. 7 - Although Alessandro Volta is credited with the...Ch. 7 - Prob. 46QCh. 7 - Prob. 47QCh. 7 - What is the tragedy of the commons? How does this...Ch. 7 - How can the principles of green chemistry be...Ch. 7 - If all of todays technology presently based on...Ch. 7 - Consider these three sources of light: a candle, a...Ch. 7 - Prob. 52Q
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- The emf at 25°C of the cell: Pt l H2(g) l dis X:KCl (sat) l Hg2Cl2(s) l Hg l Pt was 612 mV. When solution X was replaced by normal phosphate buffer solution with a pH of 6.86, the emf was 741 mV. Calculate the pH of solution X.arrow_forwardIndicate how to calculate the potential E of the reaction Hg2Cl2(s) + 2e ⇄ 2Hg + 2Cl- as a function of the concentration of Cl- ions. Data: the solubility product of Hg2Cl2.arrow_forwardHow can Beer’s Law be used to determine the concentration in a selected food sample. Provide an in-depth discussion and examples of this.arrow_forward
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