Bundle: Principles of Modern Chemistry, Loose-leaf Version, 8th + LMS Integrated for OWLv2 with MindTap Reader, 4 terms (24 months) Printed Access Card
Bundle: Principles of Modern Chemistry, Loose-leaf Version, 8th + LMS Integrated for OWLv2 with MindTap Reader, 4 terms (24 months) Printed Access Card
8th Edition
ISBN: 9781305786950
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Chapter 7, Problem 19P

(a)

Interpretation Introduction

Interpretation:

The balanced chemical equation should be written for the production of butyl acetate from butanol and acetic acid.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

The balanced chemical equation is defined as the equation in which number of different atoms of elements on reactant side is similar to that of product side.

The formulas which contains different symbols for different atoms and connected by a line that denotes chemical bond is known as structural formulas. One line represents single bond, two lines represent double bond and three lines represent triple bond.

(b)

Interpretation Introduction

Interpretation:

The balanced chemical equation should be written for the conversion of ammonium acetate to acetamide and water.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

The balanced chemical equation is defined as the equation in which number of different atoms of elements on reactant side is similar to that of product side.

The formulas which contains different symbols for different atoms and connected by a line that denotes chemical bond is known as structural formulas. One line represents single bond, two lines represent double bond and three lines represent triple bond.

(c)

Interpretation Introduction

Interpretation:

The balanced chemical equation should be written for the dehydrogenation of 1-propanol.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

The balanced chemical equation is defined as the equation in which number of different atoms of elements on reactant side is similar to that of product side.

The formulas which contains different symbols for different atoms and connected by a line that denotes chemical bond is known as structural formulas. One line represents single bond, two lines represent double bond and three lines represent triple bond.

(d)

Interpretation Introduction

Interpretation:

The balanced chemical equation should be written for the complete combustion of heptane.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

The balanced chemical equation is defined as the equation in which number of different atoms of elements on reactant side is similar to that of product side.

The formulas which contains different symbols for different atoms and connected by a line that denotes chemical bond is known as structural formulas. One line represents single bond, two lines represent double bond and three lines represent triple bond.

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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution.  How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. cleavage Bond A •CH3 + 26.← Cleavage 2°C. + Bond C +3°C• CH3 2C Cleavage E 2°C. 26. weakest bond Intact molecule Strongest 3°C 20. Gund Largest argest a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. C Weakest bond A Produces Most Bond Strongest Bond Strongest Gund produces least stable radicals Weakest Stable radical b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 13°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. • CH3 methyl radical Formed in Gund A Cleavage c.…

Chapter 7 Solutions

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