Bundle: Principles of Modern Chemistry, Loose-leaf Version, 8th + LMS Integrated for OWLv2 with MindTap Reader, 4 terms (24 months) Printed Access Card
Bundle: Principles of Modern Chemistry, Loose-leaf Version, 8th + LMS Integrated for OWLv2 with MindTap Reader, 4 terms (24 months) Printed Access Card
8th Edition
ISBN: 9781305786950
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Chapter 7, Problem 22P

(a)

Interpretation Introduction

Interpretation:

The chemical equation should be written for the synthesis of vinyl acetate from easily available inorganic and petrochemicals starting materials.

Concept Introduction:

The chemicals which are derived from the natural gas and crude oil are known as petrochemicals and inorganic materials don’t contain carbon and hydrogen atoms.

The balanced chemical equation is defined as the equation in which number of different atoms of elements on reactant side is similar to that of product side.

(b)

Interpretation Introduction

Interpretation:

The chemical equation should be written for the synthesis of Formamide from easily available inorganic and petrochemicals starting materials.

Concept Introduction:

The chemicals which are derived from the natural gas and crude oil are known as petrochemicals and inorganic materials don’t contain carbon and hydrogen atoms.

The balanced chemical equation is defined as the equation in which number of different atoms of elements on reactant side is similar to that of product side.

(c)

Interpretation Introduction

Interpretation:

The chemical equation should be written for the synthesis of 1,2-difluoroethane from easily available inorganic and petrochemicals starting materials

Concept Introduction:

The chemicals which are derived from the natural gas and crude oil are known as petrochemicals and inorganic materials don’t contain carbon and hydrogen atoms.

The balanced chemical equation is defined as the equation in which number of different atoms of elements on reactant side is similar to that of product side.

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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution.  How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. cleavage Bond A •CH3 + 26.← Cleavage 2°C. + Bond C +3°C• CH3 2C Cleavage E 2°C. 26. weakest bond Intact molecule Strongest 3°C 20. Gund Largest argest a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. C Weakest bond A Produces Most Bond Strongest Bond Strongest Gund produces least stable radicals Weakest Stable radical b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 13°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. • CH3 methyl radical Formed in Gund A Cleavage c.…

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