GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
4th Edition
ISBN: 9781265982959
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 6.2, Problem 6.5PP
Given the
More Practice: Try Problems 6.27, 6.28.
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1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
None
Part II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization
of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm").
Determine the following:
(a) molecular Formula and Degree of unsaturation of compound Brian
(b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts
(ii) integration, ciii) multiplicity and (iv) interferences made for each signal
(c) Draw the structure of compound Brian.
)
ΕΙ
43
41
27
71
114 (M+)
Hmmm
20
30
40
50 60
70
80
90 100 110 120
1H NMR spectrum
300 MHz in CDCl3
2.0
alle
1.0
Chapter 6 Solutions
GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
Ch. 6.1 - Prob. 6.1PPCh. 6.1 - Prob. 6.1PCh. 6.1 - Prob. 6.2PPCh. 6.1 - Prob. 6.2PCh. 6.2 - Using the values in Table 6.2, give H for each...Ch. 6.2 - Prob. 6.4PPCh. 6.2 - Answer the following questions using the given...Ch. 6.2 - Given the H and balanced equation in Sample...Ch. 6.2 - Prob. 6.6PPCh. 6.3 - Prob. 6.7PP
Ch. 6.4 - Consider the reaction of ozone (O3) with nitrogen...Ch. 6.4 - Draw an energy diagram for an uncatalyzed...Ch. 6.5 - Identify the forward and reverse reactions in each...Ch. 6.5 - Write the expression for the equilibrium constant...Ch. 6.5 - Consider the reversible reaction AB, with K=1....Ch. 6.5 - Given each equilibrium constant, state whether the...Ch. 6.5 - Consider the following reaction:...Ch. 6.5 - Using the equilibrium mixture of reactants and...Ch. 6.5 - Calculate the equilibrium constant for each...Ch. 6.5 - Consider the representation depicted in the...Ch. 6.6 - Prob. 6.13PPCh. 6.6 - Prob. 6.14PPCh. 6.6 - wThe conversion of H2O to H2 and O2 is an...Ch. 6.6 - The reaction of O2 with NO to form NO2 and O2 is...Ch. 6.6 - wIn which direction is the equilibrium shifted in...Ch. 6.6 - Label each statement about the following...Ch. 6 - Prob. 11PCh. 6 - Prob. 12PCh. 6 - Prob. 13PCh. 6 - Prob. 14PCh. 6 - Prob. 15PCh. 6 - Prob. 16PCh. 6 - Prob. 17PCh. 6 - Prob. 18PCh. 6 - Prob. 19PCh. 6 - Prob. 20PCh. 6 - Prob. 21PCh. 6 - Prob. 22PCh. 6 - Prob. 23PCh. 6 - Prob. 24PCh. 6 - Prob. 25PCh. 6 - Prob. 26PCh. 6 - Prob. 27PCh. 6 - Ammonia ( NH3 ) decomposes to hydrogen and...Ch. 6 - Prob. 29PCh. 6 - Ethanol ( C2H6O ), a gasoline additive, is formed...Ch. 6 - Prob. 31PCh. 6 - Prob. 32PCh. 6 - Prob. 33PCh. 6 - Prob. 34PCh. 6 - Draw an energy diagram for the following reaction...Ch. 6 - Prob. 36PCh. 6 - State two reasons why increasing temperature...Ch. 6 - Why does decreasing concentration decrease the...Ch. 6 - Prob. 39PCh. 6 - Prob. 40PCh. 6 - Which of the following affect the rate of a...Ch. 6 - Prob. 42PCh. 6 - How does a catalyst affect each of the following:...Ch. 6 - What is the difference between a catalyst and an...Ch. 6 - Prob. 45PCh. 6 - Consider the representation depicted in the...Ch. 6 - For each value, are the reactants or products...Ch. 6 - Prob. 48PCh. 6 - Prob. 49PCh. 6 - Prob. 50PCh. 6 - Prob. 51PCh. 6 - Consider three different equilibrium mixtures...Ch. 6 - Write an expression for the equilibrium constant...Ch. 6 - Write an expression for the equilibrium constant...Ch. 6 - Prob. 55PCh. 6 - Use each expression for the equilibrium constant...Ch. 6 - Prob. 57PCh. 6 - Consider the following reaction:...Ch. 6 - Prob. 59PCh. 6 - Which of the following representations ([1][3]) of...Ch. 6 - Consider the following reaction....Ch. 6 - Consider the following reaction. H2(g)+I2(g)2HI(g)...Ch. 6 - Prob. 63PCh. 6 - Prob. 64PCh. 6 - Consider the reaction of N2(g)+O2(g)2NO(g). What...Ch. 6 - Consider the reaction of H2(g)+F2(g)2HF(g). What...Ch. 6 - Prob. 67PCh. 6 - Consider the reversible reaction ABA+B, shown at...Ch. 6 - Consider the endothermic conversion of oxygen to...Ch. 6 - Consider the exothermic reaction:...Ch. 6 - Consider the exothermic reaction:...Ch. 6 - Consider the endothermic reaction:...Ch. 6 - Consider the gas-phase reaction of ethylene...Ch. 6 - Methanol (CHO), which is used as a fuel in race...Ch. 6 - Prob. 75PCh. 6 - How does a catalytic converter clean up automobile...Ch. 6 - Prob. 77PCh. 6 - The reaction of salicylic acid with acetic acid...Ch. 6 - Prob. 79PCh. 6 - Prob. 80PCh. 6 - Prob. 81PCh. 6 - Prob. 82PCh. 6 - Prob. 83CPCh. 6 - Prob. 84CP
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- The iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forwardPart V. Choose which isomer would give the 1H-NMR spectrum below. Justify your reasoning by assigning important signals to the Corresponding protons of the correct molecule. A D on of of of H H 88 2 90 7.8 7.6 7.4 80 5 6 [ppm] 7.2 6.8 6.6 6.4 ō [ppm]arrow_forwardShow work with explanation. don't give Ai generated solutionarrow_forward
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