GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
4th Edition
ISBN: 9781265982959
Author: SMITH
Publisher: MCG
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Chapter 6, Problem 67P
Interpretation Introduction
Interpretation:
Diagrams corresponding to each temperature should be determined.
Concept Introduction:
The net concentrations of the reactants and products do not change at equilibrium. They are used to define an expression and the equilibrium constant (K) which has a characteristic value.
For a reaction at a given temperature,
Le Chatelier's principle is a general rule used to explain the effect of a change in reaction conditions on equilibrium.
Le Chatelier's principle states:
If a chemical system at equilibrium is disturbed, equilibrium will shift in the direction to counteract the change.
Endothermic reaction absorbs energy to drive the forward reaction.
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5.
Use the MS data to answer the questions on the next page.
14.0
1.4
15.0
8.1
100-
MS-IW-5644
26.0
2.8
27.0
6.7
28.0
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29.0
80
4.4
38.0
1.0
39.0
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1.2
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100.0
44.0
4.3
79.0
1.9
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40
81.0
1.9
82.0
2.5
93.0
8.7
20-
95.0
8.2
121.0
2.0
123.0
2.0
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11.8
0
138.0
11.5
20
40
8.
60
a.
Br
- 0
80
100
120
140
160
180
200
220
m/z
Identify the m/z of the base peak and molecular ion.
2
b.
Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0,
95.0, 136.0, and 138.0 m/z.
C.
Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to
fragment 43.0 m/z. Be sure to include all electrons and formal charges.
6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium
ion (CsH6N) and show your work.
None
Stereochemistry: Three possible answers- diastereomers, enantiomers
OH
CH₂OH
I
-c=0
21108 1101
41745 HOR
CH₂OH
IL
Но
CH₂OH
TIL
a. Compounds I and III have this relationship with each other: enantiomers
b. Compounds II and IV have this relationship with each other:
c. Compounds I and II have this relationship with each other:
d. *Draw one structure that is a stereoisomer of II, but neither a
diastereomer nor an enantiomer. (more than one correct answer)
Chapter 6 Solutions
GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
Ch. 6.1 - Prob. 6.1PPCh. 6.1 - Prob. 6.1PCh. 6.1 - Prob. 6.2PPCh. 6.1 - Prob. 6.2PCh. 6.2 - Using the values in Table 6.2, give H for each...Ch. 6.2 - Prob. 6.4PPCh. 6.2 - Answer the following questions using the given...Ch. 6.2 - Given the H and balanced equation in Sample...Ch. 6.2 - Prob. 6.6PPCh. 6.3 - Prob. 6.7PP
Ch. 6.4 - Consider the reaction of ozone (O3) with nitrogen...Ch. 6.4 - Draw an energy diagram for an uncatalyzed...Ch. 6.5 - Identify the forward and reverse reactions in each...Ch. 6.5 - Write the expression for the equilibrium constant...Ch. 6.5 - Consider the reversible reaction AB, with K=1....Ch. 6.5 - Given each equilibrium constant, state whether the...Ch. 6.5 - Consider the following reaction:...Ch. 6.5 - Using the equilibrium mixture of reactants and...Ch. 6.5 - Calculate the equilibrium constant for each...Ch. 6.5 - Consider the representation depicted in the...Ch. 6.6 - Prob. 6.13PPCh. 6.6 - Prob. 6.14PPCh. 6.6 - wThe conversion of H2O to H2 and O2 is an...Ch. 6.6 - The reaction of O2 with NO to form NO2 and O2 is...Ch. 6.6 - wIn which direction is the equilibrium shifted in...Ch. 6.6 - Label each statement about the following...Ch. 6 - Prob. 11PCh. 6 - Prob. 12PCh. 6 - Prob. 13PCh. 6 - Prob. 14PCh. 6 - Prob. 15PCh. 6 - Prob. 16PCh. 6 - Prob. 17PCh. 6 - Prob. 18PCh. 6 - Prob. 19PCh. 6 - Prob. 20PCh. 6 - Prob. 21PCh. 6 - Prob. 22PCh. 6 - Prob. 23PCh. 6 - Prob. 24PCh. 6 - Prob. 25PCh. 6 - Prob. 26PCh. 6 - Prob. 27PCh. 6 - Ammonia ( NH3 ) decomposes to hydrogen and...Ch. 6 - Prob. 29PCh. 6 - Ethanol ( C2H6O ), a gasoline additive, is formed...Ch. 6 - Prob. 31PCh. 6 - Prob. 32PCh. 6 - Prob. 33PCh. 6 - Prob. 34PCh. 6 - Draw an energy diagram for the following reaction...Ch. 6 - Prob. 36PCh. 6 - State two reasons why increasing temperature...Ch. 6 - Why does decreasing concentration decrease the...Ch. 6 - Prob. 39PCh. 6 - Prob. 40PCh. 6 - Which of the following affect the rate of a...Ch. 6 - Prob. 42PCh. 6 - How does a catalyst affect each of the following:...Ch. 6 - What is the difference between a catalyst and an...Ch. 6 - Prob. 45PCh. 6 - Consider the representation depicted in the...Ch. 6 - For each value, are the reactants or products...Ch. 6 - Prob. 48PCh. 6 - Prob. 49PCh. 6 - Prob. 50PCh. 6 - Prob. 51PCh. 6 - Consider three different equilibrium mixtures...Ch. 6 - Write an expression for the equilibrium constant...Ch. 6 - Write an expression for the equilibrium constant...Ch. 6 - Prob. 55PCh. 6 - Use each expression for the equilibrium constant...Ch. 6 - Prob. 57PCh. 6 - Consider the following reaction:...Ch. 6 - Prob. 59PCh. 6 - Which of the following representations ([1][3]) of...Ch. 6 - Consider the following reaction....Ch. 6 - Consider the following reaction. H2(g)+I2(g)2HI(g)...Ch. 6 - Prob. 63PCh. 6 - Prob. 64PCh. 6 - Consider the reaction of N2(g)+O2(g)2NO(g). What...Ch. 6 - Consider the reaction of H2(g)+F2(g)2HF(g). What...Ch. 6 - Prob. 67PCh. 6 - Consider the reversible reaction ABA+B, shown at...Ch. 6 - Consider the endothermic conversion of oxygen to...Ch. 6 - Consider the exothermic reaction:...Ch. 6 - Consider the exothermic reaction:...Ch. 6 - Consider the endothermic reaction:...Ch. 6 - Consider the gas-phase reaction of ethylene...Ch. 6 - Methanol (CHO), which is used as a fuel in race...Ch. 6 - Prob. 75PCh. 6 - How does a catalytic converter clean up automobile...Ch. 6 - Prob. 77PCh. 6 - The reaction of salicylic acid with acetic acid...Ch. 6 - Prob. 79PCh. 6 - Prob. 80PCh. 6 - Prob. 81PCh. 6 - Prob. 82PCh. 6 - Prob. 83CPCh. 6 - Prob. 84CP
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