Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198727873
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 6, Problem 6C.4ST
Interpretation Introduction

Interpretation:

The half-life time when the concentration is lowered to 0.50mmoldm3 has to be calculated.

Concept Introduction:

Integrated rate law for second order reactions:

Taking in the example of following reaction,

    aAproducts

And the reaction follows second order rate law,

Then the relationship between the concentration of A and time can be mathematically expressed as,

    1[A]t=kt+1[A]0

The above expression is called as integrated rate for second order reactions.

Half-life period:

Half-life is defined as the time taken for amount of the sample to reduce to half of its starting value.  The symbol is t12.

t12=ln(2)k

Half-life for a first order reaction is, t12=0.693k

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Chapter 6 Solutions

Elements Of Physical Chemistry

Ch. 6 - Prob. 6C.4STCh. 6 - Prob. 6D.1STCh. 6 - Prob. 6D.2STCh. 6 - Prob. 6D.3STCh. 6 - Prob. 6E.1STCh. 6 - Prob. 6E.2STCh. 6 - Prob. 6F.1STCh. 6 - Prob. 6F.2STCh. 6 - Prob. 6G.1STCh. 6 - Prob. 6G.2STCh. 6 - Prob. 6G.3STCh. 6 - Prob. 6H.1STCh. 6 - Prob. 6I.1STCh. 6 - Prob. 6I.2STCh. 6 - Prob. 6A.1ECh. 6 - Prob. 6A.2ECh. 6 - Prob. 6A.3ECh. 6 - Prob. 6B.1ECh. 6 - Prob. 6B.2ECh. 6 - Prob. 6B.3ECh. 6 - Prob. 6B.4ECh. 6 - Prob. 6B.5ECh. 6 - Prob. 6C.1ECh. 6 - Prob. 6C.2ECh. 6 - Prob. 6C.3ECh. 6 - Prob. 6C.4ECh. 6 - Prob. 6C.5ECh. 6 - Prob. 6C.6ECh. 6 - Prob. 6C.7ECh. 6 - Prob. 6C.8ECh. 6 - Prob. 6C.9ECh. 6 - Prob. 6C.10ECh. 6 - Prob. 6C.11ECh. 6 - Prob. 6C.12ECh. 6 - Prob. 6D.1ECh. 6 - Prob. 6D.2ECh. 6 - Prob. 6D.3ECh. 6 - Prob. 6D.4ECh. 6 - Prob. 6D.5ECh. 6 - Prob. 6D.6ECh. 6 - Prob. 6D.7ECh. 6 - Prob. 6D.8ECh. 6 - Prob. 6D.9ECh. 6 - Prob. 6D.10ECh. 6 - Prob. 6D.11ECh. 6 - Prob. 6E.1ECh. 6 - Prob. 6E.2ECh. 6 - Prob. 6E.3ECh. 6 - Prob. 6F.1ECh. 6 - Prob. 6F.2ECh. 6 - Prob. 6F.3ECh. 6 - Prob. 6G.1ECh. 6 - Prob. 6G.2ECh. 6 - Prob. 6G.3ECh. 6 - Prob. 6G.5ECh. 6 - Prob. 6H.1ECh. 6 - Prob. 6H.2ECh. 6 - Prob. 6H.3ECh. 6 - Prob. 6H.4ECh. 6 - Prob. 6I.1ECh. 6 - Prob. 6I.2ECh. 6 - Prob. 6I.3ECh. 6 - Prob. 6.1DQCh. 6 - Prob. 6.2DQCh. 6 - Prob. 6.3DQCh. 6 - Prob. 6.4DQCh. 6 - Prob. 6.5DQCh. 6 - Prob. 6.6DQCh. 6 - Prob. 6.7DQCh. 6 - Prob. 6.8DQCh. 6 - Prob. 6.9DQCh. 6 - Prob. 6.10DQCh. 6 - Prob. 6.11DQCh. 6 - Prob. 6.12DQCh. 6 - Prob. 6.13DQCh. 6 - Prob. 6.14DQCh. 6 - Prob. 6.1PCh. 6 - Prob. 6.2PCh. 6 - Prob. 6.3PCh. 6 - Prob. 6.4PCh. 6 - Prob. 6.5PCh. 6 - Prob. 6.6PCh. 6 - Prob. 6.9PCh. 6 - Prob. 6.10PCh. 6 - Prob. 6.11PCh. 6 - Prob. 6.12PCh. 6 - Prob. 6.13PCh. 6 - Prob. 6.15PCh. 6 - Prob. 6.16PCh. 6 - Prob. 6.17PCh. 6 - Prob. 6.19PCh. 6 - Prob. 6.20PCh. 6 - Prob. 6.21PCh. 6 - Prob. 6.22PCh. 6 - Prob. 6.24PCh. 6 - Prob. 6.25PCh. 6 - Prob. 6.26PCh. 6 - Prob. 6.27PCh. 6 - Prob. 6.28PCh. 6 - Prob. 6.29PCh. 6 - Prob. 6.30P
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