ELEM.PRIN.OF CHEMICAL...ABRIDGED (LL)
4th Edition
ISBN: 9781119540632
Author: FELDER
Publisher: WILEY
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Chapter 6, Problem 6.94P
Interpretation Introduction
Interpretation:
The molecular weight of the second solute and the heat of fusion (kJ/mol) of the solvent should be calculated.
Concept introduction:
The addition of solutes into the organic solvent changes the freezing (melting) point away from the standard value. The pure organic solvent freezes at
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A reactor in a pesticide plant contains 8000 lbm of a liquid mixture of 50% by weightmethyl isocyanate (MIC). The liquid is near its boiling point. A study of various releasescenarios indicates that a rupture of the reactor will spill the liquid to a boiling pool onthe ground. The boiling rate of the MIC has been estimated to be 50 lb m/min. Evacuationof the population must occur in areas where the vapor concentration exceeds ERPG-3levels. If the wind speed is 10 mph on a clear winter night, estimate the distancedownwind that must be evacuated.
A burning dump emits an estimated 1.5 kg/min of nitrogen dioxide (NO2 ). On a partlycloudy morning with a 2.5 m/s wind and temperature of 18°C, what is the concentrationof NO2 at a distance of 3.0 km directly downwind of the dump? Does this exceed theshort-term exposure limit for NO2 ? State your assumptions.
For each set of measurements below, calculate the Grubbs statistic, G, look up the appropriate
critical value of G from Table 4.6, and determine whether the Grubbs test supports discarding the
first value in the list at the 95% level of confidence.
a) 106.0, 165.0, 167.5, 170.5, 163.5, 170.7
(Geale -2.028; Gerit 1.822; yes, the Grubbs test supports discarding 106.0)
b) 214.8, 263.0, 229.9, 236.9, 221.8, 230.8, 241.1
c) 357.0, 309.3, 304.9, 314.8, 305.8, 295.3, 284.7, 299.5
TABLE 4-6
Critical values of G
for rejection of outlier
Number of
observations
otsulsve os
Tenos
nagsibarito G to buboxy
(95% confidence)
456
1.463
1.672
1.822
7
1.938
8 upa
2.032
9
2.110
10
2.176
- 1 12 15 20
11
2.234
2.285
2.409
2.557
Chapter 6 Solutions
ELEM.PRIN.OF CHEMICAL...ABRIDGED (LL)
Ch. 6 - Ten mL of pure liquid water in a cylinder with a...Ch. 6 - A quantity of methyl acetate is placed in an open,...Ch. 6 - Ethyl alcohol has a vapor pressure of 20.0 mm Hg...Ch. 6 - Prob. 6.4PCh. 6 - Prob. 6.5PCh. 6 - Prob. 6.6PCh. 6 - Prob. 6.7PCh. 6 - Prob. 6.8PCh. 6 - Prob. 6.9PCh. 6 - Prob. 6.10P
Ch. 6 - Prob. 6.11PCh. 6 - Prob. 6.12PCh. 6 - Prob. 6.13PCh. 6 - Air at 50% relative humidity is cooled...Ch. 6 - Prob. 6.15PCh. 6 - Prob. 6.16PCh. 6 - Air at 90°C and 1.00 atm (absolute) contains 10.0...Ch. 6 - When fermentation units are operated with high...Ch. 6 - When you step out of a shower, the temperature in...Ch. 6 - A fuel cell is an electrochemical device in which...Ch. 6 - Prob. 6.21PCh. 6 - Prob. 6.22PCh. 6 - Prob. 6.23PCh. 6 - Prob. 6.24PCh. 6 - Prob. 6.25PCh. 6 - Prob. 6.26PCh. 6 - Prob. 6.27PCh. 6 - Prob. 6.28PCh. 6 - An air conditioner is designed to bring 10.000...Ch. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - Prob. 6.32PCh. 6 - A gas stream containing 40.0 mole% hydrogen, 35.0%...Ch. 6 - Prob. 6.34PCh. 6 - In the manufacture of an active pharmaceutical...Ch. 6 - Prob. 6.36PCh. 6 - In the ?nal stage of the manufacturing process...Ch. 6 - Prob. 6.38PCh. 6 - A fuel gas containing methane and ethane is burned...Ch. 6 - A mixture of propane and butane is burned with...Ch. 6 - An important parameter in the design of gas...Ch. 6 - A liquid stream consisting of 12.5 mole% n-butane...Ch. 6 - Nitric acid is a chemical intermediate primarily...Ch. 6 - Prob. 6.44PCh. 6 - Sulfur trioxide (SO3) dissolves in and reacts with...Ch. 6 - State whether you would use Raoult’s law or Henrys...Ch. 6 - A gas containing nitrogen, benzene, and toluene is...Ch. 6 - Prob. 6.48PCh. 6 - Prob. 6.49PCh. 6 - A conelation for methane solubility in...Ch. 6 - Prob. 6.51PCh. 6 - The constituent partial pressures of a gas in...Ch. 6 - Prob. 6.53PCh. 6 - Prob. 6.54PCh. 6 - Prob. 6.55PCh. 6 - Prob. 6.56PCh. 6 - Prob. 6.57PCh. 6 - Prob. 6.58PCh. 6 - Nitrogen is bubbled through a liquid mixture that...Ch. 6 - Prob. 6.60PCh. 6 - Prob. 6.61PCh. 6 - Prob. 6.62PCh. 6 - The feed to a distillation column (sketched below)...Ch. 6 - Prob. 6.64PCh. 6 - Prob. 6.65PCh. 6 - Prob. 6.66PCh. 6 - Prob. 6.67PCh. 6 - Prob. 6.68PCh. 6 - Prob. 6.69PCh. 6 - Prob. 6.70PCh. 6 - A methanol-water feed stream is introduced to a...Ch. 6 - Prob. 6.72PCh. 6 - In this problem you will use a spreadsheet to...Ch. 6 - Prob. 6.74PCh. 6 - Prob. 6.75PCh. 6 - Prob. 6.76PCh. 6 - Acetaldehyde is synthesized by the catalytic...Ch. 6 - Dehydration of natural gas is necessary to prevent...Ch. 6 - A two-unit process is used to separate H2S from a...Ch. 6 - Prob. 6.80PCh. 6 - Prob. 6.81PCh. 6 - Prob. 6.82PCh. 6 - Prob. 6.83PCh. 6 - A solution containing 100 lbm KNO3/100 Ibm H2O at...Ch. 6 - A 10.0 wt% aqueous solution of sodium chloride is...Ch. 6 - Potassium dichromate (K2Cr2O7) is to be recovered...Ch. 6 - Prob. 6.87PCh. 6 - Prob. 6.88PCh. 6 - Sodium bicarbonate is synthesized by reacting...Ch. 6 - An ore containing 90 wt% MgSO4(H2O and the balance...Ch. 6 - An aqueous waste stream leaving a process contains...Ch. 6 - A solution of diphenyl (MW = 154.2) in benzene is...Ch. 6 - An aqueous solution of urea (MW = 60.06) freezes...Ch. 6 - Prob. 6.94PCh. 6 - Derive Equation 6.54 for the boiling-point...Ch. 6 - Prob. 6.96PCh. 6 - A stream of 5.00 wt% oleic acid in cottonseed oil...Ch. 6 - Benzene and hexane are being considered as...Ch. 6 - Acetone is lo be extracted with n-hexane from a...Ch. 6 - Prob. 6.100PCh. 6 - Prob. 6.101PCh. 6 - Five kilograms of a 30 wt% acetone70% water...Ch. 6 - An aqueous acetone solution is fed at a rate of...Ch. 6 - Prob. 6.104PCh. 6 - Prob. 6.105PCh. 6 - Air at 25°C and 1 atm with a relative humidity of...Ch. 6 - Prob. 6.107PCh. 6 - Prob. 6.108PCh. 6 - Various amounts of activated carbon were added to...
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