Concept explainers
Interpretation:
For the given proton transfer reaction, which side of the reaction is favored, and by what numerical factor, is to be predicted.
Concept introduction:
A proton transfer reaction is the one in which a Bronsted Lowry base reacts with a Bronsted Lowry acid to form a conjugate base and a conjugate acid respectively.
A reaction’s tendency to form products is described by its equilibrium constant Keq. A very large Keq favors the products side, while a very small Keq value heavily favors the reactants.
A proton transfer reaction favors the side opposite the stronger acid (i.e., opposite to the lower pKa value). Each difference of one in pKa values between the two acids corresponds to a power of ten by which that side of the reaction is favored.
Want to see the full answer?
Check out a sample textbook solutionChapter 6 Solutions
EBK GET READY FOR ORGANIC CHEMISTRY
- Nonearrow_forward4. Draw and label all possible isomers for [M(py)3(DMSO)2(CI)] (py = pyridine, DMSO dimethylsulfoxide).arrow_forwardThe emission data in cps displayed in Table 1 is reported to two decimal places by the chemist. However, the instrument output is shown in Table 2. Table 2. Iron emission from ICP-AES Sample Blank Standard Emission, cps 579.503252562 9308340.13122 Unknown Sample 343.232365741 Did the chemist make the correct choice in how they choose to display the data up in Table 1? Choose the best explanation from the choices below. No. Since the instrument calculates 12 digits for all values, they should all be kept and not truncated. Doing so would eliminate significant information. No. Since the instrument calculates 5 decimal places for the standard, all of the values should be limited to the same number. The other decimal places are not significant for the blank and unknown sample. Yes. The way Saman made the standards was limited by the 250-mL volumetric flask. This glassware can report values to 2 decimal places, and this establishes our number of significant figures. Yes. Instrumental data…arrow_forward
- 7. Draw a curved arrow mechanism for the following reaction. HO cat. HCI OH in dioxane with 4A molecular sievesarrow_forwardTry: Convert the given 3D perspective structure to Newman projection about C2 - C3 bond (C2 carbon in the front). Also, show Newman projection of other possible staggered conformers and circle the most stable conformation. Use the template shown. F H3C Br Harrow_forwardNonearrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage LearningOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning