
Chemistry
3rd Edition
ISBN: 9780073402734
Author: Julia Burdge
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Question
Chapter 6, Problem 65QP
Interpretation Introduction
Interpretation:
The quantum numbers associated with the orbitals
Concept introduction:
The four quantum numbers are principle quantum number (n), angular quantum number (l), magnetic spin quantum number
Principle quantum number designates the orbital size.
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Using the bond energy values, calculate the energy that must be supplied or is released upon the polymerization of 755 monomers. If energy must be supplied, provide a positive number; if energy is released, provide a negative number. Hint: Avogadro’s number is 6.02 × 1023.
-AG|F=2E|V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
Acidic solution
-0.93
+0.38
-0.51 -0.06
H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3
-0.28
-0.50
→
-0.50
Basic solution
3-1.12
-1.57
-2.05 -0.89
PO HPO →→H2PO2 P PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5 PH,
0.0
-0.5-
2 3 9 3
-1.5
-2.0
Pa
H,PO
H,PO
H,PO
-3
-1 0
2
4
Oxidation state, N
2
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…
These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?
Chapter 6 Solutions
Chemistry
Ch. 6.1 - Practice ProblemATTEMPT What is the frequency (in...Ch. 6.1 - Prob. 1PPBCh. 6.1 - Practice Problem CONCEPTUALIZE
Which of the...Ch. 6.1 - Prob. 1CPCh. 6.1 - Calculate the frequency of light with wavelength...Ch. 6.1 - Prob. 3CPCh. 6.1 - Prob. 4CPCh. 6.2 - Practice Problem ATTEMPT
Calculate the difference...Ch. 6.2 - Prob. 1PPBCh. 6.2 - Prob. 1PPC
Ch. 6.2 - Prob. 1CPCh. 6.2 - Prob. 2CPCh. 6.2 - Prob. 3CPCh. 6.2 - Prob. 4CPCh. 6.3 - Prob. 1PPACh. 6.3 - Practice Problem BUILD
(a) Calculate the...Ch. 6.3 - Prob. 1PPCCh. 6.3 - Prob. 1CPCh. 6.3 - Prob. 2CPCh. 6.3 - Prob. 3CPCh. 6.3 - Prob. 4CPCh. 6.4 - Prob. 1PPACh. 6.4 - Prob. 1PPBCh. 6.4 - Prob. 1PPCCh. 6.4 - Prob. 1CPCh. 6.4 - Prob. 2CPCh. 6.5 - Practice ProblemATTEMPT Calculate the de Broglie...Ch. 6.5 - Prob. 1PPBCh. 6.5 - Prob. 1PPCCh. 6.5 - What is the minimum uncertainty in the position of...Ch. 6.5 - Prob. 2CPCh. 6.6 - Prob. 1PPACh. 6.6 - Prob. 1PPBCh. 6.6 - Prob. 1PPCCh. 6.6 - Prob. 1CPCh. 6.6 - Prob. 2CPCh. 6.6 - Prob. 3CPCh. 6.6 - Prob. 4CPCh. 6.7 - Practice Problem ATTEMPT
(a) What are the possible...Ch. 6.7 - Practice ProblemBUILD (a) What is the lowest...Ch. 6.7 - Practice Problem CONCEPTUALIZE
Imagine a cobbler's...Ch. 6.7 - Prob. 1CPCh. 6.7 - Prob. 2CPCh. 6.7 - Prob. 3CPCh. 6.7 - Prob. 4CPCh. 6.8 - Prob. 1PPACh. 6.8 - Prob. 1PPBCh. 6.8 - Prob. 1PPCCh. 6.8 - Prob. 1CPCh. 6.8 - What element is represented by the following...Ch. 6.8 - Which orbital diagram is correct for the...Ch. 6.9 - Practice Problem ATTEMPT
Write the electron...Ch. 6.9 - Prob. 1PPBCh. 6.9 - Prob. 1PPCCh. 6.9 - Prob. 1CPCh. 6.9 - Prob. 2CPCh. 6.9 - 6.9.3 Which of the following is a d-block element?...Ch. 6.9 - Prob. 4CPCh. 6.10 - Practice ProblemATTEMPT Without referring to...Ch. 6.10 - Practice ProblemBUILD Without referring to Figure...Ch. 6.10 - Practice ProblemCONCEPTUALIZE Consider again the...Ch. 6 - Key Skills Problems What is the noble gas core for...Ch. 6 - Which of the following electron configurations...Ch. 6 - What element is represented by the electron...Ch. 6 - What is the electron configuration of the Lu atom?...Ch. 6 - What is a wave? Using a diagram, define the...Ch. 6 - 6.2 What are the units for wavelength and...Ch. 6 - List the types of electromagnetic radiation having...Ch. 6 - 6.4 Give the high and low wavelength values that...Ch. 6 - (a) What is the wavelength (in nm) of light having...Ch. 6 - 6.6 (a) What is the frequency of light having a...Ch. 6 - 6.7 The SI unit of time is the second, which is...Ch. 6 - 6.8 How many minutes would it take a radio wave to...Ch. 6 - The average distance between Mars and Earth is...Ch. 6 - 6.10 Four waves represent light in four different...Ch. 6 - Briefly explain Planck’s quantum theory and...Ch. 6 - Prob. 12QPCh. 6 - 6.13 Explain what is meant by the photoelectric...Ch. 6 - 6.14 What are photons? What role did Einstein’s...Ch. 6 - A photon has a wavelength of 705 nm. Calculate the...Ch. 6 - The blue color of the sky results from the...Ch. 6 - 6.17 A photon has a frequency of . (a) Convert...Ch. 6 - What is the wavelength (in nm) of radiation that...Ch. 6 - When copper is bombarded with high energy...Ch. 6 - 6.20 A particular form of electromagnetic...Ch. 6 - The retina of a human eye can detect light when...Ch. 6 - The radioactive 60 Co isotope is used in nuclear...Ch. 6 - Photosynthesis makes use of visible light or bring...Ch. 6 - A red light was shined onto a metal sample and the...Ch. 6 - A photoelectric experiment was performed by...Ch. 6 - What are emission spectra? How do line spectra...Ch. 6 - What is an energy level? 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Quantum...Ch. 6 - When an electron makes a transition between energy...Ch. 6 - Prob. 114APCh. 6 - Prob. 115APCh. 6 - Prob. 116APCh. 6 - 6.11 The wave function for the is orbital in the...Ch. 6 - Prob. 118APCh. 6 - Prob. 119APCh. 6 - Prob. 120APCh. 6 - 6.121 Calculate the wavelength and frequency of an...Ch. 6 - Prob. 122APCh. 6 - 6.123 In a photoelectric experiment a student uses...Ch. 6 - Prob. 124APCh. 6 - Prob. 125APCh. 6 - Prob. 126APCh. 6 - Prob. 127APCh. 6 - Prob. 128APCh. 6 - Prob. 129APCh. 6 - Prob. 130APCh. 6 - Prob. 131APCh. 6 - Prob. 132APCh. 6 - 6.133 Blackbody radiation is the term used to...Ch. 6 - Prob. 134APCh. 6 - Prob. 135APCh. 6 - How many photons at 586 nm must be absorbed to...Ch. 6 - Prob. 137APCh. 6 - Prob. 1SEPPCh. 6 - Prob. 2SEPPCh. 6 - What is the energy of a photon with wavelength λ...Ch. 6 - The visible region of the electromagnetic spectrum...
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