Interpretation:
The
Concept introduction:
Wavelength is the separation between two progressive crests or troughs.
The energy of a photon can be expressed as
Here,
The emission energy of photon (E) when it moves from the first excited state to ground state can be calculated as
The relationship between meter and nanometer can be expressed as:
To convert meter to nanometer, conversion factor is
The relationship between number of moles and number of atoms can be expressed as
To convert number of atoms to number of moles, conversion factor is
The relationship between kilojoules and joules can be expressed as
To convert kilojoules to joules, conversion factor is
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Chemistry
- It requires 799 kJ of energy to break one mole of carbon-oxygen double bonds in carbon dioxide. What wavelength of light does this correspond to per bond? Is there any transition in the hydrogen atom that has at least this quantity of energy to one photon?arrow_forward6.96 When a helium atom absorbs light at 58.44 nm, an electron is promoted from the 1s orbital to a 2p orbital. Given that the ionization energy of (ground state) helium is 2372 kJ/ mol, find the longest wavelength of light that could eject an electron from the excited state helium atom.arrow_forwardHow many electrons in an atom can have the following quantum designation? (a) 1s (b) 4d, m l =0(c) n=5,l=2arrow_forward
- Investigating Energy Levels Consider the hypothetical atom X that has one electron like the H atom but has different energy levels. The energies of an electron in an X atom are described by the equation E=RHn3 where RH is the same as for hydrogen (2.179 1018 J). Answer the following questions, without calculating energy values. a How would the ground-state energy levels of X and H compare? b Would the energy of an electron in the n = 2 level of H be higher or lower than that of an electron in the n = 2 level of X? Explain your answer. c How do the spacings of the energy levels of X and H compare? d Which would involve the emission of a higher frequency of light, the transition of an electron in an H atom from the n = 5 to the n = 3 level or a similar transition in an X atom? e Which atom, X or H, would require more energy to completely remove its electron? f A photon corresponding to a particular frequency of blue light produces a transition from the n = 2 to the n = 5 level of a hydrogen atom. Could this photon produce the same transition (n = 12 to n = 5) in an atom of X? Explain.arrow_forwardAccording to a relationship developed by Niels Bohr, for an atom or ion that has a single electron, the total energy, En, of an electron in a stable orbit of quantum number n is En = [Z2/n2] (2.179 1018 J) where Z is the atomic number. Calculate the ionization energy for the electron in a ground-state He+ ion.arrow_forwardOne bit of evidence that the quantum mechanical model is correct lies in the magnetic properties of matter. Atoms with unpaired electrons are attracted by magnetic fields and thus are said to exhibit pararamagnetism. The degree to which this effect is observed is directly related to the number of unpaired electrons present in the atom. Consider the ground-state electron configurations for Li, N, Ni, Te, Ba, and Hg. Which of these atoms would be expected to be paramagnetic, and how many unpaired electrons are present in each paramagnetic atom?arrow_forward
- What is the maximum number of electrons that can occupy a f subshell (l = 3)?arrow_forwardLight with a wavelength of 425 nm fell on a potassium surface, and electrons were ejected at a speed of 4.88 105 m/s. What energy was expended in removing an electron from the metal? Express the answer in joules (per electron) and in kilojoules per mole (of electrons).arrow_forwardA metallic element reacts vigorously with water, evolving hydrogen gas. An excited atom of this element has its outer electron in the 3p orbital. When this electron drops to its ground state in the 3s orbital, light is emitted of wavelength 589 nm What is the identity of the element? Explain how you arrived at your answer. What is the color of the emitted light?arrow_forward
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