
Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
9th Edition
ISBN: 9781305968707
Author: Spencer L. Seager
Publisher: Brooks Cole
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Question
Chapter 6, Problem 6.37E
Interpretation Introduction
Interpretation:
The Celsius temperature of the gas in the
Concept introduction:
The ideal gas equation is used to represent the relation between the volume, pressure, temperature and number of moles of an ideal gas. The ideal gas equation is given as,
Where,
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 6 Solutions
Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
Ch. 6 - Calculate the volume of 125g of the following...Ch. 6 - Calculate the volume of 125g of the following...Ch. 6 - Copper metal has a density of 8.92g/cm3 at 20.0C...Ch. 6 - Liquid water has a density of 1.00g/mL at 10.0C...Ch. 6 - Gallium metal melts at 29.8C. At the melting...Ch. 6 - Prob. 6.6ECh. 6 - Describe the change in form of energy kinetic...Ch. 6 - Prob. 6.8ECh. 6 - Prob. 6.9ECh. 6 - At 25.0C, helium molecules (He) have an average...
Ch. 6 - Prob. 6.11ECh. 6 - Prob. 6.12ECh. 6 - Explain each of the following observations using...Ch. 6 - Prob. 6.14ECh. 6 - The following statements are best associated with...Ch. 6 - Prob. 6.16ECh. 6 - Prob. 6.17ECh. 6 - Prob. 6.18ECh. 6 - Prob. 6.19ECh. 6 - Prob. 6.20ECh. 6 - Prob. 6.21ECh. 6 - Convert each of the following temperatures from...Ch. 6 - Prob. 6.23ECh. 6 - Prob. 6.24ECh. 6 - A 200.mL sample of oxygen gas is collected at...Ch. 6 - A 200.mL sample of nitrogen gas is collected at...Ch. 6 - Prob. 6.27ECh. 6 - Prob. 6.28ECh. 6 - What volume in liters of air measured at 1.00atm...Ch. 6 - What volume in liters of air measured at 1.00atm...Ch. 6 - Prob. 6.31ECh. 6 - Prob. 6.32ECh. 6 - Prob. 6.33ECh. 6 - Prob. 6.34ECh. 6 - A sample of gas has a volume of 375mL at 27C. The...Ch. 6 - What volume of gas in liters at 120.C must be...Ch. 6 - Prob. 6.37ECh. 6 - Prob. 6.38ECh. 6 - Prob. 6.39ECh. 6 - A helium balloon was partially filled with...Ch. 6 - You have a 1.50-L balloon full of air at 30.C. To...Ch. 6 - Prob. 6.42ECh. 6 - What minimum pressure would a 250.-mL aerosol can...Ch. 6 - Prob. 6.44ECh. 6 - Prob. 6.45ECh. 6 - Prob. 6.46ECh. 6 - Prob. 6.47ECh. 6 - Prob. 6.48ECh. 6 - Prob. 6.49ECh. 6 - The pressure gauge of a steel cylinder of methane...Ch. 6 - Suppose 12.0g of dry ice (solidCO2) was placed in...Ch. 6 - Prob. 6.52ECh. 6 - Prob. 6.53ECh. 6 - A sample of gaseous methyl ether has a mass of...Ch. 6 - A sample of gaseous nitrogen oxide is found to...Ch. 6 - A sample of gas weighs 0.176g and has a volume of...Ch. 6 - Prob. 6.57ECh. 6 - Prob. 6.58ECh. 6 - Prob. 6.59ECh. 6 - Prob. 6.60ECh. 6 - Prob. 6.61ECh. 6 - Prob. 6.62ECh. 6 - Prob. 6.63ECh. 6 - Classify each of the following processes as...Ch. 6 - Classify each of the following processes as...Ch. 6 - Prob. 6.66ECh. 6 - Prob. 6.67ECh. 6 - Prob. 6.68ECh. 6 - Prob. 6.69ECh. 6 - Prob. 6.70ECh. 6 - Prob. 6.71ECh. 6 - Prob. 6.72ECh. 6 - Prob. 6.73ECh. 6 - Prob. 6.74ECh. 6 - Prob. 6.75ECh. 6 - Using the specific heat data of Table 6.8,...Ch. 6 - Using the specific heat data of Table 6.8,...Ch. 6 - Prob. 6.78ECh. 6 - Prob. 6.79ECh. 6 - Liquid Freon (CCl2F2) is used as a refrigerant. It...Ch. 6 - Prob. 6.81ECh. 6 - What is the density of argon gas in g/mL at STP?Ch. 6 - Prob. 6.83ECh. 6 - Prob. 6.84ECh. 6 - Prob. 6.85ECh. 6 - Prob. 6.86ECh. 6 - Prob. 6.87ECh. 6 - Prob. 6.88ECh. 6 - Prob. 6.89ECh. 6 - Prob. 6.90ECh. 6 - Prob. 6.91ECh. 6 - Prob. 6.92ECh. 6 - Refer to Figure 6.12 and answer the question....Ch. 6 - Prob. 6.94ECh. 6 - Prob. 6.95ECh. 6 - Definite shape and definite volume best describes...Ch. 6 - Prob. 6.97ECh. 6 - Prob. 6.98ECh. 6 - Prob. 6.99ECh. 6 - Which of the following indicates the relative...Ch. 6 - Prob. 6.101ECh. 6 - Prob. 6.102ECh. 6 - What are the differentiating factors between...Ch. 6 - Prob. 6.104ECh. 6 - Prob. 6.105ECh. 6 - When a vapor condenses into a liquid: a.it absorbs...Ch. 6 - Prob. 6.107ECh. 6 - Prob. 6.108ECh. 6 - Prob. 6.109ECh. 6 - Prob. 6.110ECh. 6 - Prob. 6.111ECh. 6 - Prob. 6.112ECh. 6 - How much heat is required to raise the temperature...Ch. 6 - Prob. 6.115ECh. 6 - Prob. 6.116ECh. 6 - Prob. 6.117ECh. 6 - Prob. 6.118ECh. 6 - Prob. 6.119ECh. 6 - Prob. 6.120ECh. 6 - Prob. 6.121ECh. 6 - Prob. 6.122ECh. 6 - Prob. 6.123ECh. 6 - Prob. 6.124ECh. 6 - Prob. 6.125E
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