Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
9th Edition
ISBN: 9781305968707
Author: Spencer L. Seager
Publisher: Brooks Cole
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Chapter 6, Problem 6.117E
Interpretation Introduction
Interpretation:
Number of liters occupied by the given sample at STP is to be identified.
Concept Introduction:
According to the
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
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Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
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solution.
acids:
П
bases:
Х
other: ☐
ப
acids:
0.51 mol of KOH is added to
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
N2O4 (g) 2NO2 (g)
AG⁰ = 5.4 kJ
Now suppose a reaction vessel is filled with 1.68 atm of dinitrogen tetroxide (N204) at 148. °C. Answer the following questions about this system:
rise
Under these conditions, will the pressure of N2O4 tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
yes
no
0.42 atm
☑
5
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Chapter 6 Solutions
Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
Ch. 6 - Calculate the volume of 125g of the following...Ch. 6 - Calculate the volume of 125g of the following...Ch. 6 - Copper metal has a density of 8.92g/cm3 at 20.0C...Ch. 6 - Liquid water has a density of 1.00g/mL at 10.0C...Ch. 6 - Gallium metal melts at 29.8C. At the melting...Ch. 6 - Prob. 6.6ECh. 6 - Describe the change in form of energy kinetic...Ch. 6 - Prob. 6.8ECh. 6 - Prob. 6.9ECh. 6 - At 25.0C, helium molecules (He) have an average...
Ch. 6 - Prob. 6.11ECh. 6 - Prob. 6.12ECh. 6 - Explain each of the following observations using...Ch. 6 - Prob. 6.14ECh. 6 - The following statements are best associated with...Ch. 6 - Prob. 6.16ECh. 6 - Prob. 6.17ECh. 6 - Prob. 6.18ECh. 6 - Prob. 6.19ECh. 6 - Prob. 6.20ECh. 6 - Prob. 6.21ECh. 6 - Convert each of the following temperatures from...Ch. 6 - Prob. 6.23ECh. 6 - Prob. 6.24ECh. 6 - A 200.mL sample of oxygen gas is collected at...Ch. 6 - A 200.mL sample of nitrogen gas is collected at...Ch. 6 - Prob. 6.27ECh. 6 - Prob. 6.28ECh. 6 - What volume in liters of air measured at 1.00atm...Ch. 6 - What volume in liters of air measured at 1.00atm...Ch. 6 - Prob. 6.31ECh. 6 - Prob. 6.32ECh. 6 - Prob. 6.33ECh. 6 - Prob. 6.34ECh. 6 - A sample of gas has a volume of 375mL at 27C. The...Ch. 6 - What volume of gas in liters at 120.C must be...Ch. 6 - Prob. 6.37ECh. 6 - Prob. 6.38ECh. 6 - Prob. 6.39ECh. 6 - A helium balloon was partially filled with...Ch. 6 - You have a 1.50-L balloon full of air at 30.C. To...Ch. 6 - Prob. 6.42ECh. 6 - What minimum pressure would a 250.-mL aerosol can...Ch. 6 - Prob. 6.44ECh. 6 - Prob. 6.45ECh. 6 - Prob. 6.46ECh. 6 - Prob. 6.47ECh. 6 - Prob. 6.48ECh. 6 - Prob. 6.49ECh. 6 - The pressure gauge of a steel cylinder of methane...Ch. 6 - Suppose 12.0g of dry ice (solidCO2) was placed in...Ch. 6 - Prob. 6.52ECh. 6 - Prob. 6.53ECh. 6 - A sample of gaseous methyl ether has a mass of...Ch. 6 - A sample of gaseous nitrogen oxide is found to...Ch. 6 - A sample of gas weighs 0.176g and has a volume of...Ch. 6 - Prob. 6.57ECh. 6 - Prob. 6.58ECh. 6 - Prob. 6.59ECh. 6 - Prob. 6.60ECh. 6 - Prob. 6.61ECh. 6 - Prob. 6.62ECh. 6 - Prob. 6.63ECh. 6 - Classify each of the following processes as...Ch. 6 - Classify each of the following processes as...Ch. 6 - Prob. 6.66ECh. 6 - Prob. 6.67ECh. 6 - Prob. 6.68ECh. 6 - Prob. 6.69ECh. 6 - Prob. 6.70ECh. 6 - Prob. 6.71ECh. 6 - Prob. 6.72ECh. 6 - Prob. 6.73ECh. 6 - Prob. 6.74ECh. 6 - Prob. 6.75ECh. 6 - Using the specific heat data of Table 6.8,...Ch. 6 - Using the specific heat data of Table 6.8,...Ch. 6 - Prob. 6.78ECh. 6 - Prob. 6.79ECh. 6 - Liquid Freon (CCl2F2) is used as a refrigerant. It...Ch. 6 - Prob. 6.81ECh. 6 - What is the density of argon gas in g/mL at STP?Ch. 6 - Prob. 6.83ECh. 6 - Prob. 6.84ECh. 6 - Prob. 6.85ECh. 6 - Prob. 6.86ECh. 6 - Prob. 6.87ECh. 6 - Prob. 6.88ECh. 6 - Prob. 6.89ECh. 6 - Prob. 6.90ECh. 6 - Prob. 6.91ECh. 6 - Prob. 6.92ECh. 6 - Refer to Figure 6.12 and answer the question....Ch. 6 - Prob. 6.94ECh. 6 - Prob. 6.95ECh. 6 - Definite shape and definite volume best describes...Ch. 6 - Prob. 6.97ECh. 6 - Prob. 6.98ECh. 6 - Prob. 6.99ECh. 6 - Which of the following indicates the relative...Ch. 6 - Prob. 6.101ECh. 6 - Prob. 6.102ECh. 6 - What are the differentiating factors between...Ch. 6 - Prob. 6.104ECh. 6 - Prob. 6.105ECh. 6 - When a vapor condenses into a liquid: a.it absorbs...Ch. 6 - Prob. 6.107ECh. 6 - Prob. 6.108ECh. 6 - Prob. 6.109ECh. 6 - Prob. 6.110ECh. 6 - Prob. 6.111ECh. 6 - Prob. 6.112ECh. 6 - How much heat is required to raise the temperature...Ch. 6 - Prob. 6.115ECh. 6 - Prob. 6.116ECh. 6 - Prob. 6.117ECh. 6 - Prob. 6.118ECh. 6 - Prob. 6.119ECh. 6 - Prob. 6.120ECh. 6 - Prob. 6.121ECh. 6 - Prob. 6.122ECh. 6 - Prob. 6.123ECh. 6 - Prob. 6.124ECh. 6 - Prob. 6.125E
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