Elementary Principles Of Chemical Processes

4th Edition

ISBN: 9781119254003

Author: Richard M. Felder And Ronald W. Rousseau

Publisher: WILEY

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Principal Quantities and EOS

A physical quantity represents the physical state of a system. It is expressed as the product of a number and unit. The basic quantities used in science are length, mass, and time. The principal quantities are the quantities that are independent of other…

Textbook Question

Chapter 6, Problem 6.2P

A quantity of methyl acetate is placed in an open, transparent, three-liter flask and boiled long enough to purge all air from the vapor space. The flask is then sealed and allowed to equilibrate at 30°C, at which temperature methyl acetate has a vapor pressure of 269 mm Hg. Visual inspection shows 10 mL of liquid methyl acetate present.

(a) What is the pressure in the flask at equilibrium? Explain your reasoning.

(b) What is the total mass (grams) of methyl acetate in the flask? What fraction is in the vapor phase at equilibrium?

(c) The above answers would be different if the species in the vessel were ethyl acetate because methyl acetate and ethyl acetate have different vapor pressures. Give a rationale for that difference.

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Chapter 6, Problem 6.1P

Chapter 6, Problem 6.3P

Chapter 6 Solutions

Elementary Principles Of Chemical Processes

Ch. 6 - Ten mL of pure liquid water in a cylinder with a...Ch. 6 - A quantity of methyl acetate is placed in an open,...Ch. 6 - Ethyl alcohol has a vapor pressure of 20.0 mm Hg...Ch. 6 - Prob. 6.4P Ch. 6 - Prob. 6.5P Ch. 6 - Prob. 6.6P Ch. 6 - Prob. 6.7P Ch. 6 - Prob. 6.8P Ch. 6 - Prob. 6.9P Ch. 6 - Prob. 6.10P

Ch. 6 - Prob. 6.11P Ch. 6 - Prob. 6.12P Ch. 6 - Prob. 6.13P Ch. 6 - Air at 50% relative humidity is cooled...Ch. 6 - Prob. 6.15P Ch. 6 - Prob. 6.16P Ch. 6 - Air at 90°C and 1.00 atm (absolute) contains 10.0...Ch. 6 - When fermentation units are operated with high...Ch. 6 - When you step out of a shower, the temperature in...Ch. 6 - A fuel cell is an electrochemical device in which...Ch. 6 - Prob. 6.21P Ch. 6 - Prob. 6.22P Ch. 6 - Prob. 6.23P Ch. 6 - Prob. 6.24P Ch. 6 - Prob. 6.25P Ch. 6 - Prob. 6.26P Ch. 6 - Prob. 6.27P Ch. 6 - Prob. 6.28P Ch. 6 - An air conditioner is designed to bring 10.000...Ch. 6 - Prob. 6.30P Ch. 6 - Prob. 6.31P Ch. 6 - Prob. 6.32P Ch. 6 - A gas stream containing 40.0 mole% hydrogen, 35.0%...Ch. 6 - Prob. 6.34P Ch. 6 - In the manufacture of an active pharmaceutical...Ch. 6 - Prob. 6.36P Ch. 6 - In the ?nal stage of the manufacturing process...Ch. 6 - Prob. 6.38P Ch. 6 - A fuel gas containing methane and ethane is burned...Ch. 6 - A mixture of propane and butane is burned with...Ch. 6 - An important parameter in the design of gas...Ch. 6 - A liquid stream consisting of 12.5 mole% n-butane...Ch. 6 - Nitric acid is a chemical intermediate primarily...Ch. 6 - Prob. 6.44P Ch. 6 - Sulfur trioxide (SO3) dissolves in and reacts with...Ch. 6 - State whether you would use Raoult’s law or Henrys...Ch. 6 - A gas containing nitrogen, benzene, and toluene is...Ch. 6 - Prob. 6.48P Ch. 6 - Prob. 6.49P Ch. 6 - A conelation for methane solubility in...Ch. 6 - Prob. 6.51P Ch. 6 - The constituent partial pressures of a gas in...Ch. 6 - Prob. 6.53P Ch. 6 - Prob. 6.54P Ch. 6 - Prob. 6.55P Ch. 6 - Prob. 6.56P Ch. 6 - Prob. 6.57P Ch. 6 - Prob. 6.58P Ch. 6 - Nitrogen is bubbled through a liquid mixture that...Ch. 6 - Prob. 6.60P Ch. 6 - Prob. 6.61P Ch. 6 - Prob. 6.62P Ch. 6 - The feed to a distillation column (sketched below)...Ch. 6 - Prob. 6.64P Ch. 6 - Prob. 6.65P Ch. 6 - Prob. 6.66P Ch. 6 - Prob. 6.67P Ch. 6 - Prob. 6.68P Ch. 6 - Prob. 6.69P Ch. 6 - Prob. 6.70P Ch. 6 - A methanol-water feed stream is introduced to a...Ch. 6 - Prob. 6.72P Ch. 6 - In this problem you will use a spreadsheet to...Ch. 6 - Prob. 6.74P Ch. 6 - Prob. 6.75P Ch. 6 - Prob. 6.76P Ch. 6 - Acetaldehyde is synthesized by the catalytic...Ch. 6 - Dehydration of natural gas is necessary to prevent...Ch. 6 - A two-unit process is used to separate H2S from a...Ch. 6 - Prob. 6.80P Ch. 6 - Prob. 6.81P Ch. 6 - Prob. 6.82P Ch. 6 - Prob. 6.83P Ch. 6 - A solution containing 100 lbm KNO3/100 Ibm H2O at...Ch. 6 - A 10.0 wt% aqueous solution of sodium chloride is...Ch. 6 - Potassium dichromate (K2Cr2O7) is to be recovered...Ch. 6 - Prob. 6.87P Ch. 6 - Prob. 6.88P Ch. 6 - Sodium bicarbonate is synthesized by reacting...Ch. 6 - An ore containing 90 wt% MgSO4(H2O and the balance...Ch. 6 - An aqueous waste stream leaving a process contains...Ch. 6 - A solution of diphenyl (MW = 154.2) in benzene is...Ch. 6 - An aqueous solution of urea (MW = 60.06) freezes...Ch. 6 - Prob. 6.94P Ch. 6 - Derive Equation 6.54 for the boiling-point...Ch. 6 - Prob. 6.96P Ch. 6 - A stream of 5.00 wt% oleic acid in cottonseed oil...Ch. 6 - Benzene and hexane are being considered as...Ch. 6 - Acetone is lo be extracted with n-hexane from a...Ch. 6 - Prob. 6.100P Ch. 6 - Prob. 6.101P Ch. 6 - Five kilograms of a 30 wt% acetone70% water...Ch. 6 - An aqueous acetone solution is fed at a rate of...Ch. 6 - Prob. 6.104P Ch. 6 - Prob. 6.105P Ch. 6 - Air at 25°C and 1 atm with a relative humidity of...Ch. 6 - Prob. 6.107P Ch. 6 - Prob. 6.108P Ch. 6 - Various amounts of activated carbon were added to...

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