Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Chapter 6, Problem 6.24P
Interpretation Introduction

Interpretation:

The quality of steam in its initial state should be deduced based on the given initial and final conditions of steam.

Concept Introduction:

  • For a two-phase liquid-vapor equilibrium mixture the specific volume (V), enthalpy (H) and entropy (S) are given as:

V = Vf + x(Vg-Vf) -----(1)H = Hf + x(Hg-Hf)-----(2)S = Sf + x(Sg-Sf)--------(3)where, Vg and Vf are the specific volumes in the vapor and liquid phases respectively Hg and Hf are the specific enthalpies in the vapor and liquid phases respectivelySg and Sf are the specific entropies in the vapor and liquid phases respectivelyx = steam quality 

  • For a process that takes place at constant enthalpy, the change in enthalpy is zero. In other words, the enthalpy in the final state (H2) is equal to that in the initial state (H1). The change in enthalpy is given as:

ΔH = H2-H1 -----(4)When, ΔH = 0 H2 = H1 

Quality of steam in the initial state = 0.953

Given:

Initial pressure of wet steam, P1 = 1100 kPa

Final pressure P2 = 101.33 kPa

Final Temperature of steam = 105C0

Explanation:

Since this is a constant enthalpy process, H2 = H1

The final state enthalpy (H2) can be deduced by interpolation based on the steam table data for saturated steam and superheated steam at 101.33 kPa. Finally, the initial state steam quality (x) can be deduced based on equation (2) and known values of the initial state Hg and Hffrom the steam tables.

Calculation:

Step 1:

Calculate the final state enthalpy

Based on the steam tables at the final state pressure = 101.33 kPa we have:

For saturated steam:

Saturation temperature, T = 99.97C0

Specific enthalpy of vapor, Hg = 2675.6 kJ/kg

For superheated steam:

Saturation temperature, T = 150C0

Specific enthalpy of vapor, Hg = 2776.6 kJ/kg

Thus the enthalpy at final state T = 105C0 can be calculated by interpolation:

H2 = 2675.6 + 105-99.97150-99.97(2776.6-2675.6)= 2685.8 kJ/kg

Step 2:

Calculate the initial state steam quality

Since, H2 = H1 We have, H1 = 2685.8 kJ/kg

Based on the steam tables at the initial state P = 1100 kPa we have:

Specific enthalpy of vapor, Hg = 2780.7 kJ/kg

Specific enthalpy of liquid, Hf = 781.0 kJ/kg

Based on equation (2) we have for the initial state enthalpy:

H1 = Hf + x(Hg-Hf)x = H1-HfHg-Hf=2685.8781.02780.7781.0=0.953

The quality of steam in the initial state is, x = 0.953

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Chapter 6 Solutions

Introduction to Chemical Engineering Thermodynamics

Ch. 6 - Prob. 6.11PCh. 6 - Prob. 6.12PCh. 6 - Prob. 6.13PCh. 6 - Prob. 6.14PCh. 6 - Prob. 6.15PCh. 6 - Prob. 6.16PCh. 6 - Prob. 6.17PCh. 6 - Prob. 6.18PCh. 6 - Prob. 6.19PCh. 6 - Prob. 6.20PCh. 6 - Prob. 6.21PCh. 6 - Prob. 6.22PCh. 6 - Prob. 6.23PCh. 6 - Prob. 6.24PCh. 6 - Prob. 6.25PCh. 6 - Prob. 6.26PCh. 6 - Prob. 6.27PCh. 6 - What is the mole fraction of water vapor in air...Ch. 6 - Prob. 6.29PCh. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - Prob. 6.32PCh. 6 - Prob. 6.33PCh. 6 - Prob. 6.34PCh. 6 - Prob. 6.35PCh. 6 - Prob. 6.36PCh. 6 - Prob. 6.37PCh. 6 - Prob. 6.38PCh. 6 - Prob. 6.39PCh. 6 - Prob. 6.40PCh. 6 - Prob. 6.41PCh. 6 - Prob. 6.42PCh. 6 - Prob. 6.43PCh. 6 - Prob. 6.44PCh. 6 - Prob. 6.45PCh. 6 - Prob. 6.46PCh. 6 - Prob. 6.47PCh. 6 - Prob. 6.48PCh. 6 - Prob. 6.49PCh. 6 - Prob. 6.50PCh. 6 - Prob. 6.51PCh. 6 - Prob. 6.52PCh. 6 - Prob. 6.53PCh. 6 - Prob. 6.54PCh. 6 - Prob. 6.55PCh. 6 - Prob. 6.56PCh. 6 - Prob. 6.57PCh. 6 - Prob. 6.58PCh. 6 - Prob. 6.59PCh. 6 - Prob. 6.60PCh. 6 - Prob. 6.61PCh. 6 - Prob. 6.62PCh. 6 - Prob. 6.63PCh. 6 - Prob. 6.64PCh. 6 - Prob. 6.65PCh. 6 - Prob. 6.66PCh. 6 - Prob. 6.67PCh. 6 - Prob. 6.68PCh. 6 - Prob. 6.69PCh. 6 - Prob. 6.71PCh. 6 - Prob. 6.72PCh. 6 - Prob. 6.73PCh. 6 - Prob. 6.74PCh. 6 - Prob. 6.75PCh. 6 - Prob. 6.76PCh. 6 - Prob. 6.77PCh. 6 - Prob. 6.78PCh. 6 - Prob. 6.79PCh. 6 - Prob. 6.80PCh. 6 - Prob. 6.81PCh. 6 - The temperature dependence of the second virial...Ch. 6 - Prob. 6.83PCh. 6 - Prob. 6.84PCh. 6 - Prob. 6.85PCh. 6 - Prob. 6.86PCh. 6 - Prob. 6.87PCh. 6 - Prob. 6.88PCh. 6 - Prob. 6.89PCh. 6 - Prob. 6.90PCh. 6 - Prob. 6.91PCh. 6 - Prob. 6.92PCh. 6 - Prob. 6.93PCh. 6 - Prob. 6.94PCh. 6 - Prob. 6.95PCh. 6 - Prob. 6.96PCh. 6 - Prob. 6.97PCh. 6 - Prob. 6.98PCh. 6 - Prob. 6.99PCh. 6 - Prob. 6.100P
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