Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card
5th Edition
ISBN: 9781260170405
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 6, Problem 6.11P
Given each of the following values, is the starting material or product lower in energy?
a.
b.
c.
d.
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a.Which value corresponds to a negative value of ΔGo: Keq = 10−2 or Keq = 102?
b.In a unimolecular reaction with five times as much starting material as product at equilibrium, what is the value of Keq? Is ΔGo positive or negative?
c.Which value corresponds to a larger Keq: ΔGo = −8 kJ/mol or ΔGo = 20 kJ/mol?
XY ↔ X + Y Kc = 1.1 x 10-1 at 125C ΔH = -24.5 kJ/mol rxn.
b. A catalyst is added to the reaction. a.How will the concentrations of the reactants and products at equilibrium change? Explain your reasoning.b. How will the addition of a catalyst affect the enthalpy of the reaction? Explain your reasoning. c.The temperature of the reaction is decreased from 125 oC to 25 oC. In the boxes like the ones shown here, draw a possible new molecular diagram to represent any changes that would occur in concentrations. d. Will the equilibrium constant value increase, decrease, or remain the same when the temperature is decreased? Explain your reasoning. e. How will lowering the temperature affect the enthalpy of the reaction? Explain your reasoning.
HO
AG° =
HOT
HO
OH
a form of glucose
OH
a form
ß form
H
-
Which of the two forms is most stable:
HO
HO
HO
OH
B form of glucose
H
COH
At equilibrium at 25 °C, the two forms are present in a ratio of approximately 64 : 36. Calculate the standard free energy (AG°)
difference that corresponds to this equilibrium ratio (i.e. more stable form : less stable form).
Kcal/mol
Chapter 6 Solutions
Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card
Ch. 6 - Problem 6.1 Classify each transformation as...Ch. 6 - Prob. 6.2PCh. 6 - Problem 6.3 By taking into account...Ch. 6 - Problem 6.4 Use curved arrows to show the movement...Ch. 6 - Problem 6.5 Follow the curved arrows and draw the...Ch. 6 - Prob. 6.6PCh. 6 - Problem 6.7 Use the values in Table 6.2 to...Ch. 6 - Prob. 6.8PCh. 6 - aWhich Keq corresponds to a negative value of G,...Ch. 6 - Given each of the following values, is the...
Ch. 6 - Given each of the following values, is the...Ch. 6 - The equilibrium constant for the conversion of the...Ch. 6 - Prob. 6.13PCh. 6 - For a reaction with H=40kJ/mol, decide which of...Ch. 6 - For a reaction with H=20kJ/mol, decide which of...Ch. 6 - Draw an energy diagram for a reaction in which the...Ch. 6 - Prob. 6.17PCh. 6 - Prob. 6.18PCh. 6 - Problem 6.19 Consider the following energy...Ch. 6 - Draw an energy diagram for a two-step reaction,...Ch. 6 - Which value if any corresponds to a faster...Ch. 6 - Prob. 6.22PCh. 6 - Problem 6.23 For each rate equation, what effect...Ch. 6 - Prob. 6.24PCh. 6 - Identify the catalyst in each equation. a....Ch. 6 - Draw the products of homolysis or heterolysis of...Ch. 6 - Explain why the bond dissociation energy for bond...Ch. 6 - Classify each transformation as substitution,...Ch. 6 - Prob. 6.29PCh. 6 - 6.30 Draw the products of each reaction by...Ch. 6 - 6.31 (a) Add curved arrows for each step to show...Ch. 6 - Prob. 6.32PCh. 6 - Prob. 6.33PCh. 6 - Prob. 6.34PCh. 6 - Calculate H for each reaction. a HO+CH4CH3+H2O b...Ch. 6 - Homolysis of the indicated CH bond in propene...Ch. 6 - Prob. 6.37PCh. 6 - Prob. 6.38PCh. 6 - 6.39. a. Which value corresponds to a negative...Ch. 6 - Prob. 6.40PCh. 6 - For which of the following reaction is S a...Ch. 6 - Prob. 6.42PCh. 6 - Prob. 6.43PCh. 6 - 6.44 Consider the following reaction: .
Use curved...Ch. 6 - Prob. 6.45PCh. 6 - Draw an energy diagram for the Bronsted-Lowry...Ch. 6 - Prob. 6.47PCh. 6 - Indicate which factors affect the rate of a...Ch. 6 - Prob. 6.49PCh. 6 - 6.50 The conversion of acetyl chloride to methyl...Ch. 6 - Prob. 6.51PCh. 6 - Prob. 6.52PCh. 6 - The conversion of (CH3)3Cl to (CH3)2C=CH2 can...Ch. 6 - 6.54 Explain why is more acidic than , even...Ch. 6 - Prob. 6.55PCh. 6 - Prob. 6.56PCh. 6 - Prob. 6.57PCh. 6 - Although Keq of equation 1 in problem 6.57 does...Ch. 6 - Prob. 6.59P
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