Shift in equilibrium position on addition of water should be determined. Concept introduction: Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K . Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

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Answer 1

Question

Chapter 6, Problem 58E

a)

Interpretation Introduction

Interpretation:Shift in equilibrium position on addition of water should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

b)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of AgNO3 should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

c)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of NaOH should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

d)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of Fe(NO3)3 should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

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4. C6H100 5 I peak 3 2 PPM Integration values: 1.79ppm (2), 4.43ppm (1.33) Ipeak

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3. Consider the compounds below and determine if they are aromatic, antiaromatic, or non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly drawn and you should be able to tell that the bonding electrons and lone pair electrons should reside in which hybridized atomic orbital 2. You should consider ring strain- flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti- aromaticity) H H N N: NH2 N Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic TT electrons Me H Me Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic πT electrons H HH…

Answer 2

Question

Chapter 6, Problem 58E

a)

Interpretation Introduction

Interpretation:Shift in equilibrium position on addition of water should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

b)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of AgNO3 should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

c)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of NaOH should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

d)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of Fe(NO3)3 should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

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Answer 3

Question

Chapter 6, Problem 58E

a)

Interpretation Introduction

Interpretation:Shift in equilibrium position on addition of water should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

b)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of AgNO3 should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

c)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of NaOH should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

d)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of Fe(NO3)3 should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

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Answer 4

Question

Chapter 6, Problem 58E

a)

Interpretation Introduction

Interpretation:Shift in equilibrium position on addition of water should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

b)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of AgNO3 should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

c)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of NaOH should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

d)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of Fe(NO3)3 should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

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Answer 5

Chapter 6, Problem 58E

a)

Interpretation Introduction

Interpretation:Shift in equilibrium position on addition of water should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

b)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of AgNO3 should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

c)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of NaOH should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

d)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of Fe(NO3)3 should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

Answer 6

Chapter 6, Problem 58E

a)

Interpretation Introduction

Interpretation:Shift in equilibrium position on addition of water should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

Answer 7

Chapter 6, Problem 58E

a)

Interpretation Introduction

Interpretation:Shift in equilibrium position on addition of water should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

Answer 8

b)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of AgNO3 should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

Answer 9

b)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of AgNO3 should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

Answer 10

c)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of NaOH should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

Answer 11

c)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of NaOH should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

Answer 12

d)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of Fe(NO3)3 should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

Answer 13

d)

Interpretation Introduction

Interpretation: Shift in equilibrium position on addition of Fe(NO3)3 should be determined.

Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, reactants and products have constant concentration. Equilibrium constant is denoted by K .

Le Chatelier’s principle states that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction in such way that tends to reduce effect of that change. These changes can be made in concentration, pressure, and temperature.

Answer 14

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Answer 16

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Answer 17

Ch. 6 - Prob. 1DQ Ch. 6 - The boxes shown below represent a set of initial...Ch. 6 - For the reaction H2(g)+I2(g)2HI(g) , considertwo...Ch. 6 - Given the reaction A(g)+B(g)C(g)+D(g) ,...Ch. 6 - Consider the reaction A(g)+2B(g)C(g)+D(g) ina...Ch. 6 - Consider the reaction A(g)+B(g)C(g)+D(g) . Afriend...Ch. 6 - Consider the following statements: “Consider the...Ch. 6 - Le Châtelier’s principle is stated (Section 6.8)...Ch. 6 - The value of the equilibrium constant K depends on...Ch. 6 - Prob. 10E

Solution Summary: The author explains Le Chatelier's principle that if any change in conditions is done on system at equilibrium, it will result in shift of equilibrium direction.

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