EBK CHEMICAL PRINCIPLES
8th Edition
ISBN: 9781305856745
Author: DECOSTE
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Textbook Question
Chapter 6, Problem 2DQ
The boxes shown below represent a set of initial conditionsfor the reaction:
Draw a quantitative molecular picture that shows whatthis system looks like after the reactants are mixed inone of the boxes and the system reaches equilibrium.Support your answer with calculations.
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
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11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
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Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
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+
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to oc
occur
WHY?
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H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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Parent name (noname)
4 Bromo
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b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 6 Solutions
EBK CHEMICAL PRINCIPLES
Ch. 6 - Prob. 1DQCh. 6 - The boxes shown below represent a set of initial...Ch. 6 - For the reaction H2(g)+I2(g)2HI(g) , considertwo...Ch. 6 - Given the reaction A(g)+B(g)C(g)+D(g) ,...Ch. 6 - Consider the reaction A(g)+2B(g)C(g)+D(g) ina...Ch. 6 - Consider the reaction A(g)+B(g)C(g)+D(g) . Afriend...Ch. 6 - Consider the following statements: “Consider the...Ch. 6 - Le Châtelier’s principle is stated (Section 6.8)...Ch. 6 - The value of the equilibrium constant K depends on...Ch. 6 - Prob. 10E
Ch. 6 - Consider the following reactions at some...Ch. 6 - Prob. 12ECh. 6 - Consider the same reaction as in Exercise 12. In a...Ch. 6 - Consider the following reaction at some...Ch. 6 - Prob. 15ECh. 6 - Prob. 16ECh. 6 - Prob. 17ECh. 6 - Prob. 18ECh. 6 - Explain the difference between K, Kp , and Q.Ch. 6 - Prob. 20ECh. 6 - Prob. 21ECh. 6 - For which reactions in Exercise 21 is Kp equal to...Ch. 6 - Prob. 23ECh. 6 - Prob. 24ECh. 6 - At 327°C, the equilibrium concentrations are...Ch. 6 - Prob. 26ECh. 6 - At a particular temperature, a 2.00-L flask at...Ch. 6 - Prob. 28ECh. 6 - Prob. 29ECh. 6 - Prob. 30ECh. 6 - Prob. 31ECh. 6 - Nitrogen gas (N2) reacts with hydrogen gas (H2) to...Ch. 6 - A sample of gaseous PCl5 was introduced into an...Ch. 6 - Prob. 34ECh. 6 - Prob. 35ECh. 6 - At a particular temperature, 8.0 moles of NO2 is...Ch. 6 - Prob. 37ECh. 6 - Prob. 38ECh. 6 - Prob. 39ECh. 6 - Prob. 40ECh. 6 - At a particular temperature, K=1.00102 for...Ch. 6 - Prob. 42ECh. 6 - Prob. 43ECh. 6 - For the reaction below at a certain temperature,...Ch. 6 - At 1100 K, Kp=0.25 for the following reaction:...Ch. 6 - At 2200°C, K=0.050 for the reaction...Ch. 6 - Prob. 47ECh. 6 - Prob. 48ECh. 6 - Prob. 49ECh. 6 - Prob. 50ECh. 6 - Prob. 51ECh. 6 - Prob. 52ECh. 6 - Prob. 53ECh. 6 - Prob. 54ECh. 6 - Which of the following statements is(are) true?...Ch. 6 - Prob. 56ECh. 6 - Prob. 57ECh. 6 - Prob. 58ECh. 6 - Chromium(VI) forms two different oxyanions, the...Ch. 6 - Solid NH4HS decomposes by the following...Ch. 6 - An important reaction in the commercial production...Ch. 6 - Prob. 62ECh. 6 - Prob. 63ECh. 6 - Prob. 64ECh. 6 - Prob. 65ECh. 6 - Prob. 66ECh. 6 - Prob. 67ECh. 6 - Prob. 68ECh. 6 - Prob. 69AECh. 6 - Prob. 70AECh. 6 - Prob. 71AECh. 6 - Prob. 72AECh. 6 - Prob. 73AECh. 6 - Prob. 74AECh. 6 - An initial mixture of nitrogen gas and hydrogen...Ch. 6 - Prob. 76AECh. 6 - Prob. 77AECh. 6 - Prob. 78AECh. 6 - Prob. 79AECh. 6 - Prob. 80AECh. 6 - Prob. 81AECh. 6 - For the reaction PCl5(g)PCl3(g)+Cl2(g) at 600. K,...Ch. 6 - Prob. 83AECh. 6 - The gas arsine (AsH3) decomposes as follows:...Ch. 6 - Prob. 85AECh. 6 - Prob. 86AECh. 6 - Consider the decomposition of the compound C5H6O3...Ch. 6 - Prob. 88AECh. 6 - Prob. 89AECh. 6 - Prob. 90AECh. 6 - Prob. 91AECh. 6 - Prob. 92AECh. 6 - Prob. 93AECh. 6 - Prob. 94AECh. 6 - Prob. 95AECh. 6 - Prob. 96CPCh. 6 - Nitric oxide and bromine at initial partial...Ch. 6 - Prob. 98CPCh. 6 - Prob. 99CPCh. 6 - Consider the reaction 3O2(g)2O3(g) At 175°C and a...Ch. 6 - A mixture of N2,H2andNH3 is at equilibrium...Ch. 6 - Prob. 103CPCh. 6 - Prob. 104CPCh. 6 - Prob. 105CPCh. 6 - A 1.604-g sample of methane (CH4) gas and 6.400 g...Ch. 6 - At 1000 K the N2(g)andO2(g) in air (78% N2, 21% O2...Ch. 6 - Prob. 108CPCh. 6 - Prob. 109CPCh. 6 - Prob. 110CPCh. 6 - Prob. 111CPCh. 6 - A sample of gaseous nitrosyl bromide (NOBr)...Ch. 6 - A gaseous material XY(g) dissociates to some...
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