Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 6, Problem 21CTQ
Interpretation Introduction

Interpretation: The conformer of given structures needs to be drawn.

  Organic Chemistry: A Guided Inquiry, Chapter 6, Problem 21CTQ

Concept introduction:

Conformational isomer are those stereoisomers which can be interconverted by rotation about the single bonds without breaking bonds.

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4. For the following structures, draw both possible chair conformations, using a ring flip to go from one to the other, and circle the one that is most stable/lowest energy. (Hint: Use Table 4.8 in Klein.) Show all groups, including hydrogen atoms, attached to the cyclohexane ring. А. Me Me Et В. Et t-Bu Et
. Consider the hash/wedge structure below. a. Draw the Newman projection of the bond indicated, keeping the conformation the same. НО b. Draw the Newman projection for the most stable conformation CI c. In the Newman projection for part b, label all gauche interactions.
\Br A. Redraw the bond-line structure of the molecule above on a separate sheet of paper. B. Draw a chair conformation for the molecule. C. Draw the new chair conformation after ring inversion (ring flip). D. Circle the most stable (lowest energy) chair conformation.

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Organic Chemistry: A Guided Inquiry

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Organic Chemistry: A Guided Inquiry
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ISBN:9780618974122
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Publisher:Cengage Learning