Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 6, Problem 110CP
Interpretation Introduction
Interpretation:Value of
Concept introduction:Chemical equilibrium is taken into consideration if rate of forward and backward reactions become equal. At this stage, both reactants and products have constant concentration. It can be studied in terms of pressure also.
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Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
2600
2400
2200
2000
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1400
1200
1000
800
Potential Energy (kJ)
600
400
200
0
-200-
-400
-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would
you be able to make the reaction reverse itself (i.e. have…
draw the enolate anion and the carbonyl that would be needed to make this product through an aldol addition reaction.
Chapter 6 Solutions
Chemical Principles
Ch. 6 - Prob. 1DQCh. 6 - The boxes shown below represent a set of initial...Ch. 6 - For the reaction H2(g)+I2(g)2HI(g) , considertwo...Ch. 6 - Given the reaction A(g)+B(g)C(g)+D(g) ,...Ch. 6 - Consider the reaction A(g)+2B(g)C(g)+D(g) ina...Ch. 6 - Consider the reaction A(g)+B(g)C(g)+D(g) . Afriend...Ch. 6 - Consider the following statements: “Consider the...Ch. 6 - Le Châtelier’s principle is stated (Section 6.8)...Ch. 6 - The value of the equilibrium constant K depends on...Ch. 6 - Prob. 10E
Ch. 6 - Consider the following reactions at some...Ch. 6 - Prob. 12ECh. 6 - Consider the same reaction as in Exercise 12. In a...Ch. 6 - Consider the following reaction at some...Ch. 6 - Prob. 15ECh. 6 - Prob. 16ECh. 6 - Prob. 17ECh. 6 - Prob. 18ECh. 6 - Explain the difference between K, Kp , and Q.Ch. 6 - Prob. 20ECh. 6 - Prob. 21ECh. 6 - For which reactions in Exercise 21 is Kp equal to...Ch. 6 - Prob. 23ECh. 6 - Prob. 24ECh. 6 - At 327°C, the equilibrium concentrations are...Ch. 6 - Prob. 26ECh. 6 - At a particular temperature, a 2.00-L flask at...Ch. 6 - Prob. 28ECh. 6 - Prob. 29ECh. 6 - Prob. 30ECh. 6 - Prob. 31ECh. 6 - Nitrogen gas (N2) reacts with hydrogen gas (H2) to...Ch. 6 - A sample of gaseous PCl5 was introduced into an...Ch. 6 - Prob. 34ECh. 6 - Prob. 35ECh. 6 - At a particular temperature, 8.0 moles of NO2 is...Ch. 6 - Prob. 37ECh. 6 - Prob. 38ECh. 6 - Prob. 39ECh. 6 - Prob. 40ECh. 6 - At a particular temperature, K=1.00102 for...Ch. 6 - Prob. 42ECh. 6 - Prob. 43ECh. 6 - For the reaction below at a certain temperature,...Ch. 6 - At 1100 K, Kp=0.25 for the following reaction:...Ch. 6 - At 2200°C, K=0.050 for the reaction...Ch. 6 - Prob. 47ECh. 6 - Prob. 48ECh. 6 - Prob. 49ECh. 6 - Prob. 50ECh. 6 - Prob. 51ECh. 6 - Prob. 52ECh. 6 - Prob. 53ECh. 6 - Prob. 54ECh. 6 - Which of the following statements is(are) true?...Ch. 6 - Prob. 56ECh. 6 - Prob. 57ECh. 6 - Prob. 58ECh. 6 - Chromium(VI) forms two different oxyanions, the...Ch. 6 - Solid NH4HS decomposes by the following...Ch. 6 - An important reaction in the commercial production...Ch. 6 - Prob. 62ECh. 6 - Prob. 63ECh. 6 - Prob. 64ECh. 6 - Prob. 65ECh. 6 - Prob. 66ECh. 6 - Prob. 67ECh. 6 - Prob. 68ECh. 6 - Prob. 69AECh. 6 - Prob. 70AECh. 6 - Prob. 71AECh. 6 - Prob. 72AECh. 6 - Prob. 73AECh. 6 - Prob. 74AECh. 6 - An initial mixture of nitrogen gas and hydrogen...Ch. 6 - Prob. 76AECh. 6 - Prob. 77AECh. 6 - Prob. 78AECh. 6 - Prob. 79AECh. 6 - Prob. 80AECh. 6 - Prob. 81AECh. 6 - For the reaction PCl5(g)PCl3(g)+Cl2(g) at 600. K,...Ch. 6 - Prob. 83AECh. 6 - The gas arsine (AsH3) decomposes as follows:...Ch. 6 - Prob. 85AECh. 6 - Prob. 86AECh. 6 - Consider the decomposition of the compound C5H6O3...Ch. 6 - Prob. 88AECh. 6 - Prob. 89AECh. 6 - Prob. 90AECh. 6 - Prob. 91AECh. 6 - Prob. 92AECh. 6 - Prob. 93AECh. 6 - Prob. 94AECh. 6 - Prob. 95AECh. 6 - Prob. 96CPCh. 6 - Nitric oxide and bromine at initial partial...Ch. 6 - Prob. 98CPCh. 6 - Prob. 99CPCh. 6 - Consider the reaction 3O2(g)2O3(g) At 175°C and a...Ch. 6 - A mixture of N2,H2andNH3 is at equilibrium...Ch. 6 - Prob. 103CPCh. 6 - Prob. 104CPCh. 6 - Prob. 105CPCh. 6 - A 1.604-g sample of methane (CH4) gas and 6.400 g...Ch. 6 - At 1000 K the N2(g)andO2(g) in air (78% N2, 21% O2...Ch. 6 - Prob. 108CPCh. 6 - Prob. 109CPCh. 6 - Prob. 110CPCh. 6 - Prob. 111CPCh. 6 - A sample of gaseous nitrosyl bromide (NOBr)...Ch. 6 - A gaseous material XY(g) dissociates to some...
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