Which of the following structures are identical? (Green = Cl.)

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Answer 1

Textbook Question

Chapter 5.SE, Problem 26VC

Which of the following structures are identical? (Green = Cl.)

Chapter 5.SE, Problem 26VC, Which of the following structures are identical? (Green = Cl.)

Expert Solution & Answer

Interpretation Introduction

Interpretation:

Among the four structures given which are identical is to be stated.

Concept introduction:

All the four structures given have chiral carbons. By assigning the configuration as R or S the identical structures can be identified.

To state:

Which among the four structures given are identical.

Answer to Problem 26VC

Structures a, b, and d are identical. Structure c is different.

Explanation of Solution

The chiral carbon in all the four structures given is attached to the same four groups, H, Cl, CH₃ and COOH but differently oriented. When the sequence rules are applied to these four groups, the order of priority obtained is Cl, COOH, CH₃ and H. Using this priorities the configuration of the four structures can be obtained. It is clear that a, b and d have R configuration and d has S configuration. Hence a, b and d represent identical structures and c represents a different configuration.

Conclusion

Structure a, b, and d are identical. Structure c is different.

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Answer 2

Textbook Question

Chapter 5.SE, Problem 26VC

Which of the following structures are identical? (Green = Cl.)

Chapter 5.SE, Problem 26VC, Which of the following structures are identical? (Green = Cl.)

Expert Solution & Answer

Interpretation Introduction

Interpretation:

Among the four structures given which are identical is to be stated.

Concept introduction:

All the four structures given have chiral carbons. By assigning the configuration as R or S the identical structures can be identified.

To state:

Which among the four structures given are identical.

Answer to Problem 26VC

Structures a, b, and d are identical. Structure c is different.

Explanation of Solution

The chiral carbon in all the four structures given is attached to the same four groups, H, Cl, CH₃ and COOH but differently oriented. When the sequence rules are applied to these four groups, the order of priority obtained is Cl, COOH, CH₃ and H. Using this priorities the configuration of the four structures can be obtained. It is clear that a, b and d have R configuration and d has S configuration. Hence a, b and d represent identical structures and c represents a different configuration.

Conclusion

Structure a, b, and d are identical. Structure c is different.

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Answer 3

Textbook Question

Chapter 5.SE, Problem 26VC

Which of the following structures are identical? (Green = Cl.)

Chapter 5.SE, Problem 26VC, Which of the following structures are identical? (Green = Cl.)

Expert Solution & Answer

Interpretation Introduction

Interpretation:

Among the four structures given which are identical is to be stated.

Concept introduction:

All the four structures given have chiral carbons. By assigning the configuration as R or S the identical structures can be identified.

To state:

Which among the four structures given are identical.

Answer to Problem 26VC

Structures a, b, and d are identical. Structure c is different.

Explanation of Solution

The chiral carbon in all the four structures given is attached to the same four groups, H, Cl, CH₃ and COOH but differently oriented. When the sequence rules are applied to these four groups, the order of priority obtained is Cl, COOH, CH₃ and H. Using this priorities the configuration of the four structures can be obtained. It is clear that a, b and d have R configuration and d has S configuration. Hence a, b and d represent identical structures and c represents a different configuration.

Conclusion

Structure a, b, and d are identical. Structure c is different.

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Answer 4

Textbook Question

Chapter 5.SE, Problem 26VC

Which of the following structures are identical? (Green = Cl.)

Chapter 5.SE, Problem 26VC, Which of the following structures are identical? (Green = Cl.)

Expert Solution & Answer

Interpretation Introduction

Interpretation:

Among the four structures given which are identical is to be stated.

Concept introduction:

All the four structures given have chiral carbons. By assigning the configuration as R or S the identical structures can be identified.

To state:

Which among the four structures given are identical.

Answer to Problem 26VC

Structures a, b, and d are identical. Structure c is different.

Explanation of Solution

The chiral carbon in all the four structures given is attached to the same four groups, H, Cl, CH₃ and COOH but differently oriented. When the sequence rules are applied to these four groups, the order of priority obtained is Cl, COOH, CH₃ and H. Using this priorities the configuration of the four structures can be obtained. It is clear that a, b and d have R configuration and d has S configuration. Hence a, b and d represent identical structures and c represents a different configuration.

Conclusion

Structure a, b, and d are identical. Structure c is different.

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Answer 5

Textbook Question

Answer 6

Textbook Question

Answer 7

Expert Solution & Answer

Interpretation Introduction

Interpretation:

Among the four structures given which are identical is to be stated.

Concept introduction:

All the four structures given have chiral carbons. By assigning the configuration as R or S the identical structures can be identified.

To state:

Which among the four structures given are identical.

Answer to Problem 26VC

Structures a, b, and d are identical. Structure c is different.

Explanation of Solution

The chiral carbon in all the four structures given is attached to the same four groups, H, Cl, CH₃ and COOH but differently oriented. When the sequence rules are applied to these four groups, the order of priority obtained is Cl, COOH, CH₃ and H. Using this priorities the configuration of the four structures can be obtained. It is clear that a, b and d have R configuration and d has S configuration. Hence a, b and d represent identical structures and c represents a different configuration.

Conclusion

Structure a, b, and d are identical. Structure c is different.

Answer 8

Expert Solution & Answer

Interpretation Introduction

Interpretation:

Among the four structures given which are identical is to be stated.

Concept introduction:

All the four structures given have chiral carbons. By assigning the configuration as R or S the identical structures can be identified.

To state:

Which among the four structures given are identical.

Answer to Problem 26VC

Structures a, b, and d are identical. Structure c is different.

Explanation of Solution

The chiral carbon in all the four structures given is attached to the same four groups, H, Cl, CH₃ and COOH but differently oriented. When the sequence rules are applied to these four groups, the order of priority obtained is Cl, COOH, CH₃ and H. Using this priorities the configuration of the four structures can be obtained. It is clear that a, b and d have R configuration and d has S configuration. Hence a, b and d represent identical structures and c represents a different configuration.

Conclusion

Structure a, b, and d are identical. Structure c is different.

Answer 9

Expert Solution & Answer

Answer 10

Expert Solution & Answer

Answer 11

Interpretation Introduction

Interpretation:

Among the four structures given which are identical is to be stated.

Concept introduction:

All the four structures given have chiral carbons. By assigning the configuration as R or S the identical structures can be identified.

To state:

Which among the four structures given are identical.

Answer 12

Answer to Problem 26VC

Structures a, b, and d are identical. Structure c is different.

Answer 13

Explanation of Solution

The chiral carbon in all the four structures given is attached to the same four groups, H, Cl, CH₃ and COOH but differently oriented. When the sequence rules are applied to these four groups, the order of priority obtained is Cl, COOH, CH₃ and H. Using this priorities the configuration of the four structures can be obtained. It is clear that a, b and d have R configuration and d has S configuration. Hence a, b and d represent identical structures and c represents a different configuration.

Answer 14

Conclusion

Structure a, b, and d are identical. Structure c is different.

Answer 15

Ch. 5.2 - Prob. 1P Ch. 5.2 - Prob. 2P Ch. 5.2 - Prob. 3P Ch. 5.2 - Prob. 4P Ch. 5.3 - Is cocaine (Worked Example 5-2) dextrorotatory or...Ch. 5.3 - Prob. 6P Ch. 5.5 - Prob. 7P Ch. 5.5 - Prob. 8P Ch. 5.5 - Prob. 9P Ch. 5.5 - Assign R or S configuration to the chirality...

Which of the following structures are identical? (Green = Cl.)

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Answer to Problem 26VC

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