Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 5.8, Problem 12PPC
Interpretation Introduction
Interpretation:
The molecular mass of the given compound should be identified.
Concept introduction:
A molecule is neutral group of two or more atoms joined together by
To find: The molecular mass of Caffeine.
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
29.0
41.0
50.0
52.0
55.0
57.0
100
57.5
58.0
58.5
62.0
63.0
64.0
65.0
74.0
40
75.0
76.0
20
20
40
60
80
100
120
140
160
180
200 220
m/z
99.5
68564810898409581251883040
115.0
116.0
77404799
17417M
117.0
12.9
118.0
33.5
119.0
36
133 0
1.2
157.0
2.1
159.0
16
169.0
219
170.0
17
171.0
21.6
172.0
17
181.0
1.3
183.0
197.0
100.0
198.0
200.
784
Relative Intensity
2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
Chapter 5 Solutions
Chemistry: Atoms First
Ch. 5.2 - Write Lewis dot symbols for (a) fluoride ion (F),...Ch. 5.2 - Write Lewis dot symbols for (a) Ca2+, (b) N3 and...Ch. 5.2 - Indicate the charge on each of the ions...Ch. 5.2 - Prob. 1PPCCh. 5.2 - Using only a periodic table, determine the correct...Ch. 5.2 - Using only a periodic table, determine the correct...Ch. 5.2 - Prob. 5.2.3SRCh. 5.2 - To which group does the element Y belong if the...Ch. 5.3 - Arrange MgO, CaO, and SrO in order of increasing...Ch. 5.3 - Prob. 2PPA
Ch. 5.3 - Arrange the compounds NaF, MgO, and AlN in order...Ch. 5.3 - Prob. 2PPCCh. 5.3 - Will the lattice energy of KF be larger or smaller...Ch. 5.3 - Lattice energies are graphed for three series of...Ch. 5.4 - Prob. 5.3WECh. 5.4 - Prob. 3PPACh. 5.4 - Prob. 3PPBCh. 5.4 - Prob. 3PPCCh. 5.4 - Prob. 5.4WECh. 5.4 - Prob. 4PPACh. 5.4 - Prob. 4PPBCh. 5.4 - Prob. 4PPCCh. 5.4 - Prob. 5.4.1SRCh. 5.4 - Prob. 5.4.2SRCh. 5.4 - Prob. 5.4.3SRCh. 5.4 - Prob. 5.4.4SRCh. 5.5 - Prob. 5.5WECh. 5.5 - Prob. 5PPACh. 5.5 - Draw (a) a space-filling molecular model of carbon...Ch. 5.5 - Prob. 5PPCCh. 5.5 - Prob. 5.6WECh. 5.5 - Prob. 6PPACh. 5.5 - Prob. 6PPBCh. 5.5 - Prob. 6PPCCh. 5.5 - Prob. 5.5.1SRCh. 5.5 - Prob. 5.5.2SRCh. 5.6 - Name the following binary molecular compounds: (a)...Ch. 5.6 - Prob. 7PPACh. 5.6 - Prob. 7PPBCh. 5.6 - Prob. 7PPCCh. 5.6 - Prob. 5.8WECh. 5.6 - Give the molecular formula for each of the...Ch. 5.6 - Prob. 8PPBCh. 5.6 - Draw a molecular model of sulfur trioxide.Ch. 5.6 - Prob. 5.6.1SRCh. 5.6 - Prob. 5.6.2SRCh. 5.6 - Prob. 5.6.3SRCh. 5.6 - What is the name of the compound shown? (a)...Ch. 5.7 - Prob. 5.9WECh. 5.7 - Name the following ionic compounds: (a) Na2SO4,...Ch. 5.7 - Prob. 9PPBCh. 5.7 - Prob. 9PPCCh. 5.7 - Name the following species: (a) BrO4, (b) HCO3,...Ch. 5.7 - Prob. 10PPACh. 5.7 - Prob. 10PPBCh. 5.7 - Prob. 10PPCCh. 5.7 - Prob. 5.11WECh. 5.7 - Prob. 11PPACh. 5.7 - Prob. 11PPBCh. 5.7 - Prob. 11PPCCh. 5.7 - Prob. 5.7.1SRCh. 5.7 - Prob. 5.7.2SRCh. 5.7 - What is the correct name of the compound Hg2CrO4?...Ch. 5.7 - What is the formula of the compound iron(III)...Ch. 5.8 - Calculate the molecular mass or the formula mass,...Ch. 5.8 - Calculate the molecular or formula mass of each of...Ch. 5.8 - Prob. 12PPBCh. 5.8 - Prob. 12PPCCh. 5.8 - Prob. 5.8.1SRCh. 5.8 - Determine the formula mass of calcium citrate...Ch. 5.8 - Prob. 5.8.3SRCh. 5.8 - Prob. 5.8.4SRCh. 5.8 - Prob. 5.8.5SRCh. 5.9 - Prob. 5.13WECh. 5.9 - Prob. 13PPACh. 5.9 - Prob. 13PPBCh. 5.9 - Prob. 13PPCCh. 5.9 - Prob. 5.9.1SRCh. 5.9 - Prob. 5.9.2SRCh. 5.10 - Prob. 5.14WECh. 5.10 - Prob. 14PPACh. 5.10 - Prob. 14PPBCh. 5.10 - Prob. 5.15WECh. 5.10 - Prob. 15PPACh. 5.10 - Prob. 15PPBCh. 5.10 - Prob. 15PPCCh. 5.10 - Prob. 5.16WECh. 5.10 - Prob. 16PPACh. 5.10 - Prob. 16PPBCh. 5.10 - Prob. 16PPCCh. 5.10 - Prob. 5.10.1SRCh. 5.10 - How many moles of hydrogen are there m 6.50 g of...Ch. 5.10 - Prob. 5.10.3SRCh. 5.10 - Prob. 5.10.4SRCh. 5 - Define the term compound and explain how a...Ch. 5 - Prob. 5.2QPCh. 5 - Prob. 5.3QPCh. 5 - Prob. 5.4QPCh. 5 - Use the second member of each group from Group 1A...Ch. 5 - Without referring to Figure 5.1, write Lewis dot...Ch. 5 - Prob. 5.7QPCh. 5 - Indicate the charge on each of the ions...Ch. 5 - To what group of the periodic table does element X...Ch. 5 - Explain what ionic bonding is.Ch. 5 - Prob. 5.11QPCh. 5 - Prob. 5.12QPCh. 5 - Prob. 5.13QPCh. 5 - Prob. 5.14QPCh. 5 - Prob. 5.15QPCh. 5 - Prob. 5.16QPCh. 5 - Prob. 5.17QPCh. 5 - Prob. 5.18QPCh. 5 - Prob. 5.19QPCh. 5 - Explain why the chemical formulas of ionic...Ch. 5 - Prob. 5.21QPCh. 5 - Give the formulas and names of the compounds...Ch. 5 - Give the formulas and names of the compounds...Ch. 5 - Prob. 5.24QPCh. 5 - Prob. 5.25QPCh. 5 - Name the following compounds: (a) CdCl2, (b) FeI3,...Ch. 5 - Prob. 5.27QPCh. 5 - Prob. 5.28QPCh. 5 - Prob. 5.29QPCh. 5 - Prob. 5.30QPCh. 5 - Prob. 5.31QPCh. 5 - Prob. 5.32QPCh. 5 - Prob. 5.33QPCh. 5 - Sulfur reacts with fluorine to produce three...Ch. 5 - Prob. 5.35QPCh. 5 - Prob. 5.36QPCh. 5 - Prob. 5.37QPCh. 5 - Prob. 5.38QPCh. 5 - Give an example of a case in which two molecules...Ch. 5 - Prob. 5.40QPCh. 5 - Prob. 5.41QPCh. 5 - Prob. 5.42QPCh. 5 - Identify the following as elements or compounds:...Ch. 5 - Prob. 5.44QPCh. 5 - Prob. 5.45QPCh. 5 - Prob. 5.46QPCh. 5 - Write the empirical formulas of the following...Ch. 5 - Prob. 5.48QPCh. 5 - Prob. 5.49QPCh. 5 - Describe how the naming of molecular binary...Ch. 5 - Define the term acid.Ch. 5 - Prob. 5.52QPCh. 5 - Prob. 5.53QPCh. 5 - Prob. 5.54QPCh. 5 - Prob. 5.55QPCh. 5 - Prob. 5.56QPCh. 5 - Prob. 5.57QPCh. 5 - Prob. 5.58QPCh. 5 - Prob. 5.59QPCh. 5 - Prob. 5.60QPCh. 5 - Prob. 5.61QPCh. 5 - Prob. 5.62QPCh. 5 - Prob. 5.63QPCh. 5 - Prob. 5.64QPCh. 5 - Prob. 5.65QPCh. 5 - Prob. 5.66QPCh. 5 - Prob. 5.67QPCh. 5 - Prob. 5.68QPCh. 5 - Prob. 5.69QPCh. 5 - Prob. 5.70QPCh. 5 - Prob. 5.71QPCh. 5 - Prob. 5.72QPCh. 5 - Prob. 5.73QPCh. 5 - Prob. 5.74QPCh. 5 - Prob. 5.75QPCh. 5 - Prob. 5.76QPCh. 5 - Prob. 5.77QPCh. 5 - Prob. 5.78QPCh. 5 - All the substances listed here are fertilizers...Ch. 5 - Prob. 5.80QPCh. 5 - Molar mass is numerically equivalent to molecular...Ch. 5 - Prob. 5.82QPCh. 5 - Prob. 5.83QPCh. 5 - Prob. 5.84QPCh. 5 - Prob. 5.85QPCh. 5 - Prob. 5.86QPCh. 5 - Prob. 5.87QPCh. 5 - The density of water is 1.00 g/mL at 4C. How many...Ch. 5 - Cinnamic alcohol is used to add a pleasant scent...Ch. 5 - The chemical formula for rust can be represented...Ch. 5 - Prob. 5.91QPCh. 5 - Prob. 5.92QPCh. 5 - Prob. 5.93QPCh. 5 - Prob. 5.94QPCh. 5 - Equilin is an estrogen isolated from the urine of...Ch. 5 - Prob. 5.96QPCh. 5 - Prob. 5.97QPCh. 5 - Prob. 5.98QPCh. 5 - Prob. 5.99QPCh. 5 - Prob. 5.100QPCh. 5 - What is wrong with or ambiguous about the phrase...Ch. 5 - Prob. 5.102QPCh. 5 - Prob. 5.103QPCh. 5 - Prob. 5.104QPCh. 5 - Ethane and acetylene are two gaseous hydrocarbons....Ch. 5 - Prob. 5.106QPCh. 5 - Prob. 5.107QPCh. 5 - Prob. 5.108QPCh. 5 - Prob. 5.109QPCh. 5 - Prob. 5.110QPCh. 5 - Prob. 5.111QPCh. 5 - Determine the molecular and empirical formulas of...Ch. 5 - Prob. 5.113QPCh. 5 - Prob. 5.114QPCh. 5 - Prob. 5.115QPCh. 5 - Prob. 5.116QPCh. 5 - Prob. 5.117QPCh. 5 - Prob. 5.118QPCh. 5 - Prob. 5.119QPCh. 5 - Prob. 5.120QPCh. 5 - Prob. 5.121QPCh. 5 - Prob. 5.122QPCh. 5 - Prob. 5.123QPCh. 5 - Prob. 5.124QPCh. 5 - Prob. 5.125QPCh. 5 - Prob. 5.126QPCh. 5 - Prob. 5.127QPCh. 5 - The compound 2,3-dimercaptopropanol...Ch. 5 - Prob. 5.129QPCh. 5 - Prob. 5.130QPCh. 5 - Prob. 5.131QPCh. 5 - Prob. 5.132QPCh. 5 - Calculate the number of cations and anions in each...Ch. 5 - Calculate the percent composition by mass of all...Ch. 5 - Prob. 5.135QPCh. 5 - Prob. 5.136QPCh. 5 - Prob. 5.137QPCh. 5 - Prob. 5.138QP
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