Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 5, Problem 5.20QP
Explain why the chemical formulas of ionic compounds are usually the same as their empirical formulas.
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
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Chapter 5 Solutions
Chemistry: Atoms First
Ch. 5.2 - Write Lewis dot symbols for (a) fluoride ion (F),...Ch. 5.2 - Write Lewis dot symbols for (a) Ca2+, (b) N3 and...Ch. 5.2 - Indicate the charge on each of the ions...Ch. 5.2 - Prob. 1PPCCh. 5.2 - Using only a periodic table, determine the correct...Ch. 5.2 - Using only a periodic table, determine the correct...Ch. 5.2 - Prob. 5.2.3SRCh. 5.2 - To which group does the element Y belong if the...Ch. 5.3 - Arrange MgO, CaO, and SrO in order of increasing...Ch. 5.3 - Prob. 2PPA
Ch. 5.3 - Arrange the compounds NaF, MgO, and AlN in order...Ch. 5.3 - Prob. 2PPCCh. 5.3 - Will the lattice energy of KF be larger or smaller...Ch. 5.3 - Lattice energies are graphed for three series of...Ch. 5.4 - Prob. 5.3WECh. 5.4 - Prob. 3PPACh. 5.4 - Prob. 3PPBCh. 5.4 - Prob. 3PPCCh. 5.4 - Prob. 5.4WECh. 5.4 - Prob. 4PPACh. 5.4 - Prob. 4PPBCh. 5.4 - Prob. 4PPCCh. 5.4 - Prob. 5.4.1SRCh. 5.4 - Prob. 5.4.2SRCh. 5.4 - Prob. 5.4.3SRCh. 5.4 - Prob. 5.4.4SRCh. 5.5 - Prob. 5.5WECh. 5.5 - Prob. 5PPACh. 5.5 - Draw (a) a space-filling molecular model of carbon...Ch. 5.5 - Prob. 5PPCCh. 5.5 - Prob. 5.6WECh. 5.5 - Prob. 6PPACh. 5.5 - Prob. 6PPBCh. 5.5 - Prob. 6PPCCh. 5.5 - Prob. 5.5.1SRCh. 5.5 - Prob. 5.5.2SRCh. 5.6 - Name the following binary molecular compounds: (a)...Ch. 5.6 - Prob. 7PPACh. 5.6 - Prob. 7PPBCh. 5.6 - Prob. 7PPCCh. 5.6 - Prob. 5.8WECh. 5.6 - Give the molecular formula for each of the...Ch. 5.6 - Prob. 8PPBCh. 5.6 - Draw a molecular model of sulfur trioxide.Ch. 5.6 - Prob. 5.6.1SRCh. 5.6 - Prob. 5.6.2SRCh. 5.6 - Prob. 5.6.3SRCh. 5.6 - What is the name of the compound shown? (a)...Ch. 5.7 - Prob. 5.9WECh. 5.7 - Name the following ionic compounds: (a) Na2SO4,...Ch. 5.7 - Prob. 9PPBCh. 5.7 - Prob. 9PPCCh. 5.7 - Name the following species: (a) BrO4, (b) HCO3,...Ch. 5.7 - Prob. 10PPACh. 5.7 - Prob. 10PPBCh. 5.7 - Prob. 10PPCCh. 5.7 - Prob. 5.11WECh. 5.7 - Prob. 11PPACh. 5.7 - Prob. 11PPBCh. 5.7 - Prob. 11PPCCh. 5.7 - Prob. 5.7.1SRCh. 5.7 - Prob. 5.7.2SRCh. 5.7 - What is the correct name of the compound Hg2CrO4?...Ch. 5.7 - What is the formula of the compound iron(III)...Ch. 5.8 - Calculate the molecular mass or the formula mass,...Ch. 5.8 - Calculate the molecular or formula mass of each of...Ch. 5.8 - Prob. 12PPBCh. 5.8 - Prob. 12PPCCh. 5.8 - Prob. 5.8.1SRCh. 5.8 - Determine the formula mass of calcium citrate...Ch. 5.8 - Prob. 5.8.3SRCh. 5.8 - Prob. 5.8.4SRCh. 5.8 - Prob. 5.8.5SRCh. 5.9 - Prob. 5.13WECh. 5.9 - Prob. 13PPACh. 5.9 - Prob. 13PPBCh. 5.9 - Prob. 13PPCCh. 5.9 - Prob. 5.9.1SRCh. 5.9 - Prob. 5.9.2SRCh. 5.10 - Prob. 5.14WECh. 5.10 - Prob. 14PPACh. 5.10 - Prob. 14PPBCh. 5.10 - Prob. 5.15WECh. 5.10 - Prob. 15PPACh. 5.10 - Prob. 15PPBCh. 5.10 - Prob. 15PPCCh. 5.10 - Prob. 5.16WECh. 5.10 - Prob. 16PPACh. 5.10 - Prob. 16PPBCh. 5.10 - Prob. 16PPCCh. 5.10 - Prob. 5.10.1SRCh. 5.10 - How many moles of hydrogen are there m 6.50 g of...Ch. 5.10 - Prob. 5.10.3SRCh. 5.10 - Prob. 5.10.4SRCh. 5 - Define the term compound and explain how a...Ch. 5 - Prob. 5.2QPCh. 5 - Prob. 5.3QPCh. 5 - Prob. 5.4QPCh. 5 - Use the second member of each group from Group 1A...Ch. 5 - Without referring to Figure 5.1, write Lewis dot...Ch. 5 - Prob. 5.7QPCh. 5 - Indicate the charge on each of the ions...Ch. 5 - To what group of the periodic table does element X...Ch. 5 - Explain what ionic bonding is.Ch. 5 - Prob. 5.11QPCh. 5 - Prob. 5.12QPCh. 5 - Prob. 5.13QPCh. 5 - Prob. 5.14QPCh. 5 - Prob. 5.15QPCh. 5 - Prob. 5.16QPCh. 5 - Prob. 5.17QPCh. 5 - Prob. 5.18QPCh. 5 - Prob. 5.19QPCh. 5 - Explain why the chemical formulas of ionic...Ch. 5 - Prob. 5.21QPCh. 5 - Give the formulas and names of the compounds...Ch. 5 - Give the formulas and names of the compounds...Ch. 5 - Prob. 5.24QPCh. 5 - Prob. 5.25QPCh. 5 - Name the following compounds: (a) CdCl2, (b) FeI3,...Ch. 5 - Prob. 5.27QPCh. 5 - Prob. 5.28QPCh. 5 - Prob. 5.29QPCh. 5 - Prob. 5.30QPCh. 5 - Prob. 5.31QPCh. 5 - Prob. 5.32QPCh. 5 - Prob. 5.33QPCh. 5 - Sulfur reacts with fluorine to produce three...Ch. 5 - Prob. 5.35QPCh. 5 - Prob. 5.36QPCh. 5 - Prob. 5.37QPCh. 5 - Prob. 5.38QPCh. 5 - Give an example of a case in which two molecules...Ch. 5 - Prob. 5.40QPCh. 5 - Prob. 5.41QPCh. 5 - Prob. 5.42QPCh. 5 - Identify the following as elements or compounds:...Ch. 5 - Prob. 5.44QPCh. 5 - Prob. 5.45QPCh. 5 - Prob. 5.46QPCh. 5 - Write the empirical formulas of the following...Ch. 5 - Prob. 5.48QPCh. 5 - Prob. 5.49QPCh. 5 - Describe how the naming of molecular binary...Ch. 5 - Define the term acid.Ch. 5 - Prob. 5.52QPCh. 5 - Prob. 5.53QPCh. 5 - Prob. 5.54QPCh. 5 - Prob. 5.55QPCh. 5 - Prob. 5.56QPCh. 5 - Prob. 5.57QPCh. 5 - Prob. 5.58QPCh. 5 - Prob. 5.59QPCh. 5 - Prob. 5.60QPCh. 5 - Prob. 5.61QPCh. 5 - Prob. 5.62QPCh. 5 - Prob. 5.63QPCh. 5 - Prob. 5.64QPCh. 5 - Prob. 5.65QPCh. 5 - Prob. 5.66QPCh. 5 - Prob. 5.67QPCh. 5 - Prob. 5.68QPCh. 5 - Prob. 5.69QPCh. 5 - Prob. 5.70QPCh. 5 - Prob. 5.71QPCh. 5 - Prob. 5.72QPCh. 5 - Prob. 5.73QPCh. 5 - Prob. 5.74QPCh. 5 - Prob. 5.75QPCh. 5 - Prob. 5.76QPCh. 5 - Prob. 5.77QPCh. 5 - Prob. 5.78QPCh. 5 - All the substances listed here are fertilizers...Ch. 5 - Prob. 5.80QPCh. 5 - Molar mass is numerically equivalent to molecular...Ch. 5 - Prob. 5.82QPCh. 5 - Prob. 5.83QPCh. 5 - Prob. 5.84QPCh. 5 - Prob. 5.85QPCh. 5 - Prob. 5.86QPCh. 5 - Prob. 5.87QPCh. 5 - The density of water is 1.00 g/mL at 4C. How many...Ch. 5 - Cinnamic alcohol is used to add a pleasant scent...Ch. 5 - The chemical formula for rust can be represented...Ch. 5 - Prob. 5.91QPCh. 5 - Prob. 5.92QPCh. 5 - Prob. 5.93QPCh. 5 - Prob. 5.94QPCh. 5 - Equilin is an estrogen isolated from the urine of...Ch. 5 - Prob. 5.96QPCh. 5 - Prob. 5.97QPCh. 5 - Prob. 5.98QPCh. 5 - Prob. 5.99QPCh. 5 - Prob. 5.100QPCh. 5 - What is wrong with or ambiguous about the phrase...Ch. 5 - Prob. 5.102QPCh. 5 - Prob. 5.103QPCh. 5 - Prob. 5.104QPCh. 5 - Ethane and acetylene are two gaseous hydrocarbons....Ch. 5 - Prob. 5.106QPCh. 5 - Prob. 5.107QPCh. 5 - Prob. 5.108QPCh. 5 - Prob. 5.109QPCh. 5 - Prob. 5.110QPCh. 5 - Prob. 5.111QPCh. 5 - Determine the molecular and empirical formulas of...Ch. 5 - Prob. 5.113QPCh. 5 - Prob. 5.114QPCh. 5 - Prob. 5.115QPCh. 5 - Prob. 5.116QPCh. 5 - Prob. 5.117QPCh. 5 - Prob. 5.118QPCh. 5 - Prob. 5.119QPCh. 5 - Prob. 5.120QPCh. 5 - Prob. 5.121QPCh. 5 - Prob. 5.122QPCh. 5 - Prob. 5.123QPCh. 5 - Prob. 5.124QPCh. 5 - Prob. 5.125QPCh. 5 - Prob. 5.126QPCh. 5 - Prob. 5.127QPCh. 5 - The compound 2,3-dimercaptopropanol...Ch. 5 - Prob. 5.129QPCh. 5 - Prob. 5.130QPCh. 5 - Prob. 5.131QPCh. 5 - Prob. 5.132QPCh. 5 - Calculate the number of cations and anions in each...Ch. 5 - Calculate the percent composition by mass of all...Ch. 5 - Prob. 5.135QPCh. 5 - Prob. 5.136QPCh. 5 - Prob. 5.137QPCh. 5 - Prob. 5.138QP
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