Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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Chapter 5.5, Problem 42PP
Use the sublevel blocks on the periodic table to write a complete electron configuration for an atom of each of the following:
a. calcium b. nickel
c. gallium d. cadmium
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NO(g) +Cl₂ (g) = 2NOC1 (g) AGº = -41. kJ
Now suppose a reaction vessel is filled with 8.90 atm of chlorine (C12) and 5.71 atm of nitrosyl chloride (NOC1) at 1075. °C. Answer the following questions
about this system:
rise
Under these conditions, will the pressure of NOCI tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO?
In other words, if you said the pressure of NOCI will tend to rise, can that
be changed to a tendency to fall by adding NO? Similarly, if you said the
pressure of NOCI will tend to fall, can that be changed to a tendency to
rise by adding NO?
yes
no
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO needed to reverse it.
Round your answer to 2 significant digits.
atm
☑
18
Ar
Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HCN is a weak acid.
acids:
0.29 mol of NaOH is added
to 1.0 L of a 1.2M HCN
solution.
bases:
☑
other:
0.09 mol of HCl is added to
acids:
1.0 L of a solution that is
bases:
0.3M in both HCN and
KCN.
other:
0,0,...
?
00.
18
Ar
日
Chapter 5 Solutions
Basic Chemistry
Ch. 5.1 - What is meant by the wavelength of UV light?Ch. 5.1 - How are the wavelength and frequency of light...Ch. 5.1 - What is the difference between "white” light and...Ch. 5.1 - Prob. 4PPCh. 5.1 - Ultraviolet radiation (UVB) used to treat...Ch. 5.1 - AM radio waves have a frequency of 8105s1, whereas...Ch. 5.1 - If orange light has a wavelength of 6105cm, what...Ch. 5.1 - A wavelength of 850 nm is used for fiber-optic...Ch. 5.1 - Prob. 9PPCh. 5.1 - Prob. 10PP
Ch. 5.1 - Prob. 11PPCh. 5.1 - Place the following types of electromagnetic...Ch. 5.1 - Prob. 13PPCh. 5.1 - Place the following types of electromagnetic...Ch. 5.2 - What feature of an atomic spectrum indicates that...Ch. 5.2 - How can we explain the distinct lines that appear...Ch. 5.2 - Prob. 17PPCh. 5.2 - Prob. 18PPCh. 5.2 - Prob. 19PPCh. 5.2 - Prob. 20PPCh. 5.3 - Describe the shape of each of the following...Ch. 5.3 - Describe the shape of each of the following...Ch. 5.3 - Match statements 1 to 3 with a to d: 1. They have...Ch. 5.3 - Match statements 1 to 3 with a to d: 1. They have...Ch. 5.3 - Prob. 25PPCh. 5.3 - Indicate the number of each in the following: a....Ch. 5.3 - Prob. 27PPCh. 5.3 - Prob. 28PPCh. 5.4 - Compare the terms electron configuration and...Ch. 5.4 - Compare the terms orbital diagram and electron...Ch. 5.4 - Draw the orbital diagram for each of the...Ch. 5.4 - Draw the orbital diagram for each of the...Ch. 5.4 - Prob. 33PPCh. 5.4 - Write the complete electron configuration for each...Ch. 5.4 - Prob. 35PPCh. 5.4 - Prob. 36PPCh. 5.4 - Prob. 37PPCh. 5.4 - Prob. 38PPCh. 5.4 - Prob. 39PPCh. 5.4 - Give the symbol of the element that meets the...Ch. 5.5 - Use the sublevel blocks on the periodic table to...Ch. 5.5 - Use the sublevel blocks on the periodic table to...Ch. 5.5 - Use the sublevel blocks on the periodic table to...Ch. 5.5 - Use the sublevel blocks on the periodic table to...Ch. 5.5 - Prob. 45PPCh. 5.5 - Use the periodic table to give the symbol of the...Ch. 5.5 - Prob. 47PPCh. 5.5 - Use the periodic table lo give the symbol of the...Ch. 5.5 - Prob. 49PPCh. 5.5 - Prob. 50PPCh. 5.6 - What do the group numbers from IA (1) to 8A (18)...Ch. 5.6 - Prob. 52PPCh. 5.6 - Write the group number using both A/B and 1 to 18...Ch. 5.6 - Write the group number using both A/B and 1 to 18...Ch. 5.6 - Write the valence electron configuration for each...Ch. 5.6 - Prob. 56PPCh. 5.6 - Prob. 57PPCh. 5.6 - Indicate the number of valence electrons in each...Ch. 5.6 - Prob. 59PPCh. 5.6 - Prob. 60PPCh. 5.6 - Prob. 61PPCh. 5.6 - Prob. 62PPCh. 5.6 - Prob. 63PPCh. 5.6 - Select the element in each pair with the higher...Ch. 5.6 - Prob. 65PPCh. 5.6 - Prob. 66PPCh. 5.6 - Prob. 67PPCh. 5.6 - Prob. 68PPCh. 5.6 - Prob. 69PPCh. 5.6 - Prob. 70PPCh. 5.6 - Prob. 71PPCh. 5.6 - Prob. 72PPCh. 5.6 - Which statements completed with a to e will be...Ch. 5.6 - Which statements completed with a to e will be...Ch. 5.6 - Prob. 75PPCh. 5.6 - a. What is the atomic number of Te? b. How many...Ch. 5 - The chapter sections to review are shown in...Ch. 5 - Prob. 78UTCCh. 5 - Prob. 79UTCCh. 5 - Prob. 80UTCCh. 5 - The chapter sections to review are shown in...Ch. 5 - The chapter sections to review are shown in...Ch. 5 - The chapter sections to review are shown in...Ch. 5 - Prob. 84UTCCh. 5 - Prob. 85APPCh. 5 - Prob. 86APPCh. 5 - Prob. 87APPCh. 5 - Prob. 88APPCh. 5 - Prob. 89APPCh. 5 - Prob. 90APPCh. 5 - Prob. 91APPCh. 5 - Prob. 92APPCh. 5 - a. How many 3d electrons are in Fe? (5.4) b. How...Ch. 5 - a. How many 4d electrons are in Cd? (5.4) b. How...Ch. 5 - Write the abbreviated electron configuration and...Ch. 5 - Prob. 96APPCh. 5 - What do the elements Ca, Sr, and Ba have in common...Ch. 5 - Prob. 98APPCh. 5 - Prob. 99APPCh. 5 - Name the element that corresponds to each of the...Ch. 5 - Prob. 101APPCh. 5 - Prob. 102APPCh. 5 - Select the more metallic element in each pair....Ch. 5 - Select the more metallic element in each pair....Ch. 5 - Of the elements Na, P, CI, and F, which (5.6) a....Ch. 5 - Of the elements K, Ca, Br, and Kr, which (5.6) a....Ch. 5 - Prob. 107APPCh. 5 - Prob. 108APPCh. 5 - Prob. 109CPCh. 5 - Prob. 110CPCh. 5 - Prob. 111CPCh. 5 - Prob. 112CPCh. 5 - Prob. 113CPCh. 5 - The following problems are related to the topics...Ch. 5 - The following problems are related to the topics...Ch. 5 - The following problems are related to the topics...
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- Identifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: 0.2 mol of KOH is added to 1.0 L of a 0.5 M HF solution. bases: Х other: ☐ acids: 0.10 mol of HI is added to 1.0 L of a solution that is 1.4M in both HF and NaF. bases: other: ☐ 0,0,... ด ? 18 Ararrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that NH3 is a weak base. acids: ☐ 1.8 mol of HCl is added to 1.0 L of a 1.0M NH3 bases: ☐ solution. other: ☐ 0.18 mol of HNO3 is added to 1.0 L of a solution that is 1.4M in both NH3 and NH₁Br. acids: bases: ☐ other: ☐ 0,0,... ? 000 18 Ar B 1arrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NH3 (g) = N2 (g) +3H₂ —N2 (g) AGº = 34. kJ Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NH 3 tend to rise or fall? ☐ x10 fall Х Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of NH 3 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no atm 00. 18 Ar 무ㅎ ?arrow_forward
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- Identifying the major species in weak acid or weak base equilibria Your answer is incorrect. • Row 2: Your answer is incorrect. • Row 3: Your answer is incorrect. • Row 6: Your answer is incorrect. 0/5 The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: HF 0.1 mol of NaOH is added to 1.0 L of a 0.7M HF solution. bases: 0.13 mol of HCl is added to 1.0 L of a solution that is 1.0M in both HF and KF. Exponent other: F acids: HF bases: F other: K 1 0,0,... ? 000 18 Ararrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ararrow_forwardHighlight each glycosidic bond in the molecule below. Then answer the questions in the table under the drawing area. HO- HO- -0 OH OH HO NG HO- HO- OH OH OH OH NG OHarrow_forward
- € + Suppose the molecule in the drawing area below were reacted with H₂ over a platinum catalyst. Edit the molecule to show what would happen to it. That is, turn it into the product of the reaction. Also, write the name of the product molecule under the drawing area. Name: ☐ H C=0 X H- OH HO- H HO- -H CH₂OH ×arrow_forwardDraw the Haworth projection of the disaccharide made by joining D-glucose and D-mannose with a ẞ(1-4) glycosidic bond. If the disaccharide has more than one anomer, you can draw any of them. Click and drag to start drawing a structure. Xarrow_forwardEpoxides can be opened in aqueous acid or aqueous base to produce diols (molecules with two OH groups). In this question, you'll explore the mechanism of epoxide opening in aqueous acid. 2nd attempt Be sure to show all four bonds at stereocenters using hash and wedge lines. 0 0 Draw curved arrows to show how the epoxide reacts with hydronium ion. 100 +1: 1st attempt Feedback Be sure to show all four bonds at stereocenters using hash and wedge lines. See Periodic Table See Hint H A 5 F F Hr See Periodic Table See Hintarrow_forward
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