(a)
Interpretation:
The response of equilibrium described in given equation
Concept Introduction:
Le Chatelier's principle:
When a change is applied to a system at equilibrium, the equilibrium will shift against the change. The equilibrium of a system will be affected by the change in temperature, pressure, and concentration.
(b)
Interpretation:
The response of equilibrium described in given equation
Concept Introduction:
Refer part (a).
(c)
Interpretation:
The response of equilibrium described in given equation
Concept Introduction:
Refer part (a).
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CHEMICAL PRINCIPLES PKG W/SAPLING
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- In a solution with carbon tetrachloride as the solvent, the compound VCl4. undergoes dimerization: 2VCl4V2Cl8 When 6.6834 g VCl4. is dissolved in 100.0 g carbon tetrachloride, the freezing point is lowered by 5.97C. Calculate the value of the equilibrium constant for the dimerization of VCl4 at this temperature. (The density of the equilibrium mixture is 1.696 g/cm3, and Kf = 29.8C kg/mol for CCl4.)arrow_forwardWhat is the law of mass action? Is it true that the value of K depends on the amounts of reactants and products mixed together initially? Explain. Is it true that reactions with large equilibrium constant values are very fast? Explain. There is only one value of the equilibrium constant for a particular system at a particular temperature, but there is an infinite number of equilibrium positions. Explain.arrow_forwardSuppose a reaction has the equilibrium constant K = 1.3 108. What does the magnitude of this constant tell you about the relative concentrations of products and reactants that will be present once equilibrium is reached? Is this reaction likely to be a good source of the products?arrow_forward
- Write a chemical equation for an equilibrium system that would lead to the following expressions (ad) for K. (a) K=(PH2S)2 (PO2)3(PSO2)2 (PH2O)2 (b) K=(PF2)1/2 (PI2)1/2PIF (c) K=[ Cl ]2(Pcl2)[ Br ]2 (d) K=(PNO)2 (PH2O)4 [ Cu2+ ]3[ NO3 ]2 [ H+ ]8arrow_forwardWrite the expression for the equilibrium constant and calculate the partial pressure of CO2(g), given that Kp is 0.25 (at 427 C) for NaHCO3(s) NaOH(s) + CO2(g)arrow_forwardA 1.00-L flask was filled with 2.00 moles of gaseous SO2 and 2.00 moles of gaseous NO2 and heated. After equilibrium was reached, it was found that 1.30 moles of gaseous NO was present. Assume that the reaction SO2 (g) + NO2 (g) ⇌ SO3 (g) + NO (g) occurs under these conditions. Calculate the value of the equilibrium constant, K, for this reaction.arrow_forward
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