Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
8th Edition
ISBN: 9780134015187
Author: John E. McMurry, David S. Ballantine, Carl A. Hoeger, Virginia E. Peterson
Publisher: PEARSON
Question
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Chapter 5, Problem 5.72CP

(a)

Interpretation Introduction

Interpretation: The oxidation number for the elements Mn and I on both sides of the given reaction equation should be determined.

Concept introduction:

In a balanced equation the number of atoms of each element as a reactant is equal to the number of atoms of that element as a product.

Change in the oxidation number of atoms involved in the reaction is one of the special characteristic of reduction reaction.

The number of electrons an atom tends to give up or gain in a chemical reaction is called oxidation number.

Oxidation: Losing electrons, increasing oxidation number.

Reduction: Gaining electron, decreasing oxidation number.

Oxidizing agent is a substance that removes electrons from another reactant in a chemical reaction and so it is reduced by taking electron onto itself and the reactant is oxidized by having its electron taken away.

Reducing agent is the element or compound in a redox reaction that donate an electron to another species and so it is oxidized.

  • Rules for assigning oxidation number
    1. 1. The oxidation number of the atom of an uncombined element is zero.
    2. 2. The sum of the oxidation numbers of all atoms in a compound must equal to the total charge on the species.
    3. 3. Hydrogen has an oxidation number of +1 unless it is combined with metals, in which case it has an oxidation number of -1.
    4. 4. Oxygen has an oxidation number of -2, except in peroxides where it is -1 and in OF2 where it is +2.

(b)

Interpretation Introduction

Interpretation: The oxidizing and reducing agents in the given reaction should be determined.

Concept introduction:

Change in the oxidation number of atoms involved in the reaction is one of the special characteristic of reduction reaction.

The number of electrons an atom tends to give up or gain in a chemical reaction is called oxidation number.

Oxidation: Losing electrons, increasing oxidation number.

Reduction: Gaining electron, decreasing oxidation number.

Oxidizing agent is a substance that removes electrons from another reactant in a chemical reaction and so it is reduced by taking electron onto itself and the reactant is oxidized by having its electron taken away.

Reducing agent is the element or compound in a redox reaction that donate an electron to another species and so it is oxidized.

  • Rules for assigning oxidation number
    1. 1. The oxidation number of the atom of an uncombined element is zero.
    2. 2. The sum of the oxidation numbers of all atoms in a compound must equal to the total charge on the species.
    3. 3. Hydrogen has an oxidation number of +1 unless it is combined with metals, in which case it has an oxidation number of -1.
    4. 4. Oxygen has an oxidation number of -2, except in peroxides where it is -1 and in OF2 where it is +2.

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Chapter 5 Solutions

Fundamentals of General, Organic, and Biological Chemistry (8th Edition)

Ch. 5.5 - Prob. 5.9PCh. 5.6 - Prob. 5.3CIAPCh. 5.6 - The redox reaction that provides energy for the...Ch. 5.6 - Prob. 5.10PCh. 5.6 - Prob. 5.11PCh. 5.6 - For each of the reactions you identified as redox...Ch. 5.7 - Prob. 5.13PCh. 5.7 - Identify each of the tractions in Problem 5.13 as...Ch. 5.7 - For each traction in Problem 5.13 that you...Ch. 5 - Assume that the mixture of substances in drawing...Ch. 5 - Prob. 5.17UKCCh. 5 - Prob. 5.18UKCCh. 5 - Prob. 5.19UKCCh. 5 - Prob. 5.20UKCCh. 5 - Prob. 5.22APCh. 5 - Why is it not possible to balance an equation by...Ch. 5 - Write balanced equations for the following...Ch. 5 - Prob. 5.25APCh. 5 - Which of the following equations are balanced?...Ch. 5 - Prob. 5.27APCh. 5 - Balance the following equations:...Ch. 5 - Prob. 5.29APCh. 5 - When organic compounds are burned, they react with...Ch. 5 - Prob. 5.31APCh. 5 - Hydrofluoric acid (HF) is used to etch glass...Ch. 5 - Write a balanced equation for the reaction of...Ch. 5 - Identify each of the following reactions as a...Ch. 5 - Write balanced ionic equations and net ionic...Ch. 5 - Write balanced ionic equations and net ionic...Ch. 5 - Prob. 5.37APCh. 5 - Prob. 5.38APCh. 5 - Which of the following substances are likely to be...Ch. 5 - Which of the following substances are likely to be...Ch. 5 - Use the solubility guidelines in Section 5.3 to...Ch. 5 - Use the solubility guidelines in Section 5.3 to...Ch. 5 - Prob. 5.43APCh. 5 - Prob. 5.44APCh. 5 - Prob. 5.45APCh. 5 - Prob. 5.46APCh. 5 - Where in the periodic table are the best reducing...Ch. 5 - Prob. 5.48APCh. 5 - Prob. 5.49APCh. 5 - Prob. 5.50APCh. 5 - Prob. 5.51APCh. 5 - Assign an oxidation number to the metal in the...Ch. 5 - Prob. 5.53APCh. 5 - Which element is oxidized and which is reduced in...Ch. 5 - Prob. 5.55APCh. 5 - Prob. 5.56APCh. 5 - Prob. 5.57APCh. 5 - Identify the oxidizing agent and the reducing...Ch. 5 - Prob. 5.59CPCh. 5 - Prob. 5.60CPCh. 5 - Prob. 5.61CPCh. 5 - Prob. 5.62CPCh. 5 - Prob. 5.63CPCh. 5 - Prob. 5.64CPCh. 5 - Prob. 5.65CPCh. 5 - Prob. 5.66CPCh. 5 - Hard water contains magnesium and calcium ions...Ch. 5 - Prob. 5.68CPCh. 5 - Prob. 5.69CPCh. 5 - Prob. 5.70CPCh. 5 - Geologists identify carbonate minerals by reaction...Ch. 5 - Prob. 5.72CPCh. 5 - High temperature combustion processes, such as in...Ch. 5 - Milk of magnesia is an over-the-counter product...Ch. 5 - Prob. 5.75GP
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