Although the peroxide ion,
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- Some species with two oxygen atoms only are the oxygen molecule, O₂, the peroxide ion, O₂²⁻, the superoxide ion, O₂²⁻,and the dioxygenyl ion, O₂²⁺ Draw an MO diagram for each,rank them in order of increasing bond length, and find the num-ber of unpaired electrons in each.arrow_forwardDraw the molecular orbital diagrams for Ne(2), N(2) ^2- and Be(2). Are they stable or unstable?arrow_forwardSulfur forms oxides, oxoanions, and halides. What is the hy-bridization of the central S in SO₂, SO₃, SO₃²⁻, SCl₄, SCl₆, and S₂Cl₂(atom sequence Cl—S—S—Cl)?arrow_forward
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- High-resolution photoelectron spectroscopy has provided information on the energy levels and bond distance in the ion. Prepare a molecular orbital energy level diagram for this ion Ar2+. How would you expect the bond distance in to compare with 198.8 pm, the bond distance in Cl2arrow_forwardThe ionosphere lies about 100 km above Earth’s surface.This layer consists mostly of NO, O₂, and N₂, and photoioniza-tion creates NO⁺, O₂⁺, and N₂⁺. (a) Use MO theory to compare the bond orders of the molecules and ions. (b) Does the magnetic behavior of each species change when its ion forms?arrow_forwardThe existence of compounds of the noble gases was once a great surprise and stimulated a great deal of theoretical work. Sketch the molecular orbital energy level diagram for XeF and deduce its ground state electron configurations. Is XeF likely to have a shorter bond length than XeF+?arrow_forward
- The compound nitrogen oxide (NO) forms when the nitrogen and oxygen in air are heated. Predict whether the nitrosyl ion (NO+) will have a shorter or a longer bond than the NO molecule. Will NO+ be paramagnetic likeNO or diamagnetic?arrow_forwardWhich of the following molecular ions is paramagnetic and has a bond order equal to 2? (A) B22– (B) C22– (C) N22– (D) O22–arrow_forwardIn which of these two hydrides:NH3or SbH3,would you expect a greater distortion from the normal tetrahedral bond angle of 109°? And give reason for your answerarrow_forward
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