Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
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Chapter 5, Problem 5.39P
Interpretation Introduction
Interpretation: The molecular orbitals of 1y1y
Concept introduction: The formation of molecular orbital takes place by mathematical combination of wave functions of atomic orbitals possessing nearly same energies of the atoms involved in bond formation. The number of molecular orbitals formed are always equal to the number of atomic orbitals involved. Thus, the orbitals which have lower energies compared to atomic orbitals are bonding orbital and those which have higher energies compared to atomic orbitals are antibonding orbitals.
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How is the resonance structure formed to make the following reaction product. Please hand draw the arrows showing how the electrons move to the correct position. Do not use an AI answer. Please draw it yourself or don't bother.
Part II Calculate λ max of the following compounds using wood ward- Fiecer rules
a)
b)
c)
d)
e)
OH
OH
dissolved in dioxane
Br
Br
dissolved in methanol.
NH₂
OCH 3
OH
6. Match each of the lettered items in the column on
the left with the most appropriate numbered
item(s) in the column on the right. Some of the
numbered items may be used more than once
and some not at all.
a.
Z = 37
1.
b.
Mn
2.
C.
Pr
element in period 5 and group
14
element in period 5 and group
15
d. S
e. [Rn] 7s¹
f.
d block
metal
3. highest metallic character of all
the elements
4. paramagnetic with 5 unpaired
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5. 4f36s2
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7.
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Chapter 5 Solutions
Inorganic Chemistry
Ch. 5.1 - Repeat the process in the preceding example for...Ch. 5.2 - Prob. 5.2ECh. 5.3 - Use a similar approach to the discussion of HF to...Ch. 5.4 - Sketch the energy levels and the molecular...Ch. 5.4 - Using the D2h character table shown, verify that...Ch. 5.4 - Using orbital potential energies, show that group...Ch. 5.4 - Prob. 5.7ECh. 5.4 - Prob. 5.8ECh. 5.4 - Prob. 5.9ECh. 5.4 - Use the projection operator method to derive...
Ch. 5.4 - Determine the types of hybrid orbitals that are...Ch. 5.4 - Determine the reducible representation for all the...Ch. 5 - Expand the list of orbitais considered in Figures...Ch. 5 - On the basis of molecular orbitals, predict the...Ch. 5 - On the basis of molecular orbitals, predict the...Ch. 5 - Compare the bonding in O22,O2 and O2 Include Lewis...Ch. 5 - Although the peroxide ion, O22 and the acetylide...Ch. 5 - High-resolution photoelectron spectroscopy has...Ch. 5 - a. Prepare a molecular orbital energy-level...Ch. 5 - a. Prepare a molecular orbital energy-level...Ch. 5 - NF is a known molecule a. Construct a molecular...Ch. 5 - The hypofluorite ion, OF can be observed only with...Ch. 5 - Prob. 5.11PCh. 5 - Although KrF+ and XeF+ have been studied, KrBr+...Ch. 5 - Prepare a molecular orbital energy level diagram...Ch. 5 - Methylene, CH2 plays an important role in many...Ch. 5 - Beryllium hydride, BeH2 is linear in the gas...Ch. 5 - In the gas phase, BeF2 forms linear monomeric...Ch. 5 - For the compound XeF2 do the following: a. Sketch...Ch. 5 - TaH5 has been predicted to have C4v symmetry, with...Ch. 5 - Describe the bonding in ozone, o3 on the basis of...Ch. 5 - Describe the bonding in SO3 by using group theory...Ch. 5 - The ion H3+ has been observed, but its structure...Ch. 5 - Use molecular orbital arguments to explain the...Ch. 5 - Prob. 5.23PCh. 5 - Prob. 5.24PCh. 5 - The isomenc ions NSO (thiazate) and SNO...Ch. 5 - Apply the projection operator method to derive the...Ch. 5 - Apply the projection operator method to derive the...Ch. 5 - A set of four group orbitals derived from four 3s...Ch. 5 - The projection operator method has applications...Ch. 5 - Although the cl2+ ion has not been isolated, it...Ch. 5 - BF3 is often described as a molecule in which...Ch. 5 - SF4 has C2v symmetry. Predict the possible...Ch. 5 - Consider a square pyramidal AB5 molecule. Using...Ch. 5 - Prob. 5.34PCh. 5 - For the molecule PCl5 : a. Using the character...Ch. 5 - Molecular modeling software is typically capable...Ch. 5 - Prob. 5.39PCh. 5 - Calculate and display the orbitals for the linear...Ch. 5 - Prob. 5.41PCh. 5 - Prob. 5.42PCh. 5 - Prob. 5.43PCh. 5 - Diborane, B2H6 , has the structure shown. a. Using...
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