(a) Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified. Concept introduction: Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

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Answer 1

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Chapter 5, Problem 5.54P

Interpretation Introduction

(a)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction: Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Interpretation Introduction

(b)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction:Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Interpretation Introduction

(c)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction: Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

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LTS Solid: AT=Te-Ti Trial 1 Trial 2 Trial 3 Average ΔΗ Mass water, g 24.096 23.976 23.975 Moles of solid, mol 0.01763 001767 0101781 Temp. change, °C 2.9°C 11700 2.0°C Heat of reaction, J -292.37J -170.473 -193.26J AH, kJ/mole 16.58K 9.647 kJ 10.85 kr 16.58K59.64701 KJ mol 12.35k Minimum AS, J/mol K 41.582 mol-k Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn & Show your calculations for: AH in J and then in kJ/mole for Trial 1: qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J qsin = qrxn = 292.35 292.37J AH in J = 292.375 0.2923kJ 0.01763m01 =1.65×107 AH in kJ/mol = = 16.58K 0.01763mol mol qrx Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con Kelvin.) AS=AHIT (1.65×10(9.64×103) + (1.0 Jimai

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Answer 2

Question

Chapter 5, Problem 5.54P

Interpretation Introduction

(a)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction: Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Interpretation Introduction

(b)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction:Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Interpretation Introduction

(c)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction: Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

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Answer 3

Question

Chapter 5, Problem 5.54P

Interpretation Introduction

(a)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction: Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Interpretation Introduction

(b)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction:Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Interpretation Introduction

(c)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction: Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

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Answer 4

Question

Chapter 5, Problem 5.54P

Interpretation Introduction

(a)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction: Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Interpretation Introduction

(b)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction:Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Interpretation Introduction

(c)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction: Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

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Answer 5

Chapter 5, Problem 5.54P

Interpretation Introduction

(a)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction: Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Interpretation Introduction

(b)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction:Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Interpretation Introduction

(c)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction: Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Answer 6

Chapter 5, Problem 5.54P

Interpretation Introduction

(a)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction: Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Answer 7

Chapter 5, Problem 5.54P

Interpretation Introduction

(a)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction: Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Answer 8

Interpretation Introduction

(b)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction:Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Answer 9

Interpretation Introduction

(b)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction:Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Answer 10

Interpretation Introduction

(c)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction: Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Answer 11

Interpretation Introduction

(c)

Interpretation: The maximum number of stereoisomers possible for the given compound is to be identified.

Concept introduction: Stereoisomers are the compounds in which molecular formula of a compound remains same but positions of different atoms or groups are changed to form new compounds. The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers.

Answer 12

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Answer 14

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Answer 15

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Draw the mirror image of each compound. Label each...Ch. 5 - Prob. 5.4P Ch. 5 - A molecule is achiral if it has a plane of...Ch. 5 - Problem 5.6 Locate the stereogenic centers in each...Ch. 5 - The facts in section 5.4A can be used to locate...Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

Solution Summary: The author concludes that the maximum number of stereoisomers is possible for the given compound.

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Chapter 5 Solutions