Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN: 9781305960060
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Textbook Question
Chapter 5, Problem 5.41E
Calculate the number of grams of
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Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
in the
Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
-0.13
-0.12
-0.11
-0.10
-0.08
8
CI
Jane
1
-0.09
5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Chapter 5 Solutions
Chemistry for Today: General, Organic, and Biochemistry
Ch. 5 - Identify the reactants and products in each of the...Ch. 5 - Identify the reactants and products in each of the...Ch. 5 - Prob. 5.3ECh. 5 - Identify which of the following are consistent...Ch. 5 - Prob. 5.5ECh. 5 - Determine the number of atoms of each element on...Ch. 5 - Balance the following equations: a....Ch. 5 - Balance the following equations: a....Ch. 5 - Assign oxidation numbers to the blue element in...Ch. 5 - Assign oxidation numbers to the blue element in...
Ch. 5 - Find the element with the highest oxidation number...Ch. 5 - Find the element with the highest oxidation number...Ch. 5 - For each of the following equations, indicate...Ch. 5 - For each of the following equations, indicate...Ch. 5 - Assign oxidation numbers to each element in the...Ch. 5 - Assign oxidation numbers to each element in the...Ch. 5 - The tarnish of silver objects is a coating of...Ch. 5 - Prob. 5.18ECh. 5 - Prob. 5.19ECh. 5 - Classify each of the reactions represented by the...Ch. 5 - Classify each of the reactions represented by the...Ch. 5 - Prob. 5.22ECh. 5 - Prob. 5.23ECh. 5 - Prob. 5.24ECh. 5 - Prob. 5.25ECh. 5 - Prob. 5.26ECh. 5 - Prob. 5.27ECh. 5 - Consider all of the following ionic compounds to...Ch. 5 - Consider all of the following ionic compounds to...Ch. 5 - Prob. 5.30ECh. 5 - Reactions represented by the following equations...Ch. 5 - Prob. 5.32ECh. 5 - Prob. 5.33ECh. 5 - Prob. 5.34ECh. 5 - Prob. 5.35ECh. 5 - Prob. 5.36ECh. 5 - Prob. 5.37ECh. 5 - Prob. 5.38ECh. 5 - Prob. 5.39ECh. 5 - Prob. 5.40ECh. 5 - Calculate the number of grams of SO2 that must...Ch. 5 - Calculate the mass of limestone (CaCO3) that must...Ch. 5 - Calculate the number of moles of CO2 generated by...Ch. 5 - Calculate the number of grams of bromine (Br2)...Ch. 5 - Prob. 5.45ECh. 5 - Prob. 5.46ECh. 5 - Pure titanium metal is produced by reacting...Ch. 5 - An important metabolic process of the body is the...Ch. 5 - Caproic acid is oxidized in the body as follows:...Ch. 5 - A sample of 4.00g of methane (CH4) is mixed with...Ch. 5 - Nitrogen and oxygen react as follows:...Ch. 5 - Suppose you want to use acetylene (C2H2) as a...Ch. 5 - Ammonia, carbon dioxide, and water vapor react to...Ch. 5 - Prob. 5.55ECh. 5 - The actual yield of a reaction was 11.74g of...Ch. 5 - A product weighing 14.37g was isolated from a...Ch. 5 - Prob. 5.58ECh. 5 - A sample of calcium metal with a mass of 2.00g was...Ch. 5 - Upon heating, mercury (II) oxide undergoes a...Ch. 5 - Prob. 5.61ECh. 5 - Rewrite the following word equation using chemical...Ch. 5 - The element with an electron configuration of...Ch. 5 - Assuming a 100 reaction yield, it was calculated...Ch. 5 - The decomposition of a sample of a compound...Ch. 5 - Prob. 5.66ECh. 5 - Prob. 5.67ECh. 5 - Prob. 5.68ECh. 5 - Prob. 5.69ECh. 5 - Prob. 5.70ECh. 5 - Certain vegetables and fruits, such as potatoes...Ch. 5 - In an ordinary flashlight battery, an oxidation...Ch. 5 - Prob. 5.73ECh. 5 - Prob. 5.74ECh. 5 - Which of the following equations is balanced? a....Ch. 5 - Prob. 5.76ECh. 5 - Prob. 5.77ECh. 5 - What is the oxidation number of sodium in the...Ch. 5 - Prob. 5.79ECh. 5 - Prob. 5.80ECh. 5 - Prob. 5.81ECh. 5 - Prob. 5.82ECh. 5 - Prob. 5.83ECh. 5 - Which of the following species is being oxidized...Ch. 5 - Identify the oxidizing agent and the reducing...Ch. 5 - Prob. 5.86ECh. 5 - Identify the following as an oxidation, a...Ch. 5 - Prob. 5.88ECh. 5 - Prob. 5.89ECh. 5 - Prob. 5.90ECh. 5 - What is the net ionic equation of the following...Ch. 5 - Prob. 5.92ECh. 5 - Prob. 5.93ECh. 5 - The number of grams of hydroegn formed by the...Ch. 5 - In the reaction CaCl2+Na2CO3CaCO3+2NaCl, if...Ch. 5 - Prob. 5.96E
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- n Feb 3 A T + 4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how you confirmed the structure. 5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of Limonene. 6. (1 pts) Predict the 1H NMR spectral data of R-Limonene. Proton NMR: 5.3 pon multiplet (H Ringarrow_forwardPart VI. Ca H 10 O is the molecular formula of compound Tom and gives the in the table below. Give a possible structure for compound Tom. 13C Signals summarized C1 C2 C3 C4 C5 C6 C7 13C shift (ppm) 23.5 27.0 33.0 35.8 127 162 205 DEPT-90 + DEPT-135 + +arrow_forward2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at 373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.arrow_forward
- Part VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forwardPart IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward
- 13C NMR is good for: a) determining the molecular weight of the compound b) identifying certain functional groups. c) determining the carbon skeleton, for example methyl vs ethyl vs propyl groups d) determining how many different kinds of carbon are in the moleculearrow_forward6 D 2. (1 pt) Limonene can be isolated by performing steam distillation of orange peel. Could you have performed this experiment using hexane instead of water? Explain. 3. (2 pts) Using GCMS results, analyze and discuss the purity of the Limonene obtained from the steam distillation of orange peel.arrow_forwardPart III. Arrange the following carbons (in blue) in order of increasing chemical shift. HO B NH 2 A CIarrow_forward
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