(a) Interpretation: The stereogenic centers in the ball and stick model of lisinopril are to be identified. Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

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Answer 1

Question

Chapter 5, Problem 5.15P

Interpretation Introduction

(a)

Interpretation: The stereogenic centers in the ball and stick model of lisinopril are to be identified.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Interpretation Introduction

(b)

Interpretation: The stereogenic centers are to be labeled as R or S.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

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Eleostearic acid is an unsaturated fatty acid obtained from the seeds of the tung oii tree (Aleurites fordii), a deciduous tree native to China. (a) Draw the structure of a stereoisomer that has a higher melting point than eleostearic acid. (b) Draw the structure of a stereoisomer that has a lower melting point. CO,H eleostearic acid

Draw the structure of (S)-citalopram, a drug used to treat depression and anxiety that is much more potent than its R enantiomer.

(a) Label the carbon–carbon double bond in A as E or Z. (b) Draw the products (including stereoisomers) formed when A is treated with H2O in the presence of H2SO4.

Answer 2

Question

Chapter 5, Problem 5.15P

Interpretation Introduction

(a)

Interpretation: The stereogenic centers in the ball and stick model of lisinopril are to be identified.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Interpretation Introduction

(b)

Interpretation: The stereogenic centers are to be labeled as R or S.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

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Answer 3

Question

Chapter 5, Problem 5.15P

Interpretation Introduction

(a)

Interpretation: The stereogenic centers in the ball and stick model of lisinopril are to be identified.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Interpretation Introduction

(b)

Interpretation: The stereogenic centers are to be labeled as R or S.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

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Answer 4

Question

Chapter 5, Problem 5.15P

Interpretation Introduction

(a)

Interpretation: The stereogenic centers in the ball and stick model of lisinopril are to be identified.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Interpretation Introduction

(b)

Interpretation: The stereogenic centers are to be labeled as R or S.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

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Answer 5

Chapter 5, Problem 5.15P

Interpretation Introduction

(a)

Interpretation: The stereogenic centers in the ball and stick model of lisinopril are to be identified.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Interpretation Introduction

(b)

Interpretation: The stereogenic centers are to be labeled as R or S.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Answer 6

Chapter 5, Problem 5.15P

Interpretation Introduction

(a)

Interpretation: The stereogenic centers in the ball and stick model of lisinopril are to be identified.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Answer 7

Chapter 5, Problem 5.15P

Interpretation Introduction

(a)

Interpretation: The stereogenic centers in the ball and stick model of lisinopril are to be identified.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Answer 8

Interpretation Introduction

(b)

Interpretation: The stereogenic centers are to be labeled as R or S.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Answer 9

Interpretation Introduction

(b)

Interpretation: The stereogenic centers are to be labeled as R or S.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Draw the mirror image of each compound. Label each...Ch. 5 - Prob. 5.4P Ch. 5 - A molecule is achiral if it has a plane of...Ch. 5 - Problem 5.6 Locate the stereogenic centers in each...Ch. 5 - The facts in section 5.4A can be used to locate...Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

Solution Summary: The author explains that the stereogenic centers in the ball and stick model of lisinopril are labeled as R and S.

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