(a) Interpretation: The given groups are to be arranged in order of their decreasing priority. Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

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Answer 1

Question

Chapter 5, Problem 5.12P

Interpretation Introduction

(a)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Interpretation Introduction

(b)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Interpretation Introduction

(c)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Interpretation Introduction

(d)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

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Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**

11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5

О δα HO- H -Br δα HO-- + + -Br [B] 8+ HO- -Br δα न

Answer 2

Question

Chapter 5, Problem 5.12P

Interpretation Introduction

(a)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Interpretation Introduction

(b)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Interpretation Introduction

(c)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Interpretation Introduction

(d)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

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Answer 3

Question

Chapter 5, Problem 5.12P

Interpretation Introduction

(a)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Interpretation Introduction

(b)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Interpretation Introduction

(c)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Interpretation Introduction

(d)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

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Answer 4

Question

Chapter 5, Problem 5.12P

Interpretation Introduction

(a)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Interpretation Introduction

(b)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Interpretation Introduction

(c)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Interpretation Introduction

(d)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

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Answer 5

Chapter 5, Problem 5.12P

Interpretation Introduction

(a)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Interpretation Introduction

(b)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Interpretation Introduction

(c)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Interpretation Introduction

(d)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Answer 6

Chapter 5, Problem 5.12P

Interpretation Introduction

(a)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Answer 7

Chapter 5, Problem 5.12P

Interpretation Introduction

(a)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Answer 8

Interpretation Introduction

(b)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Answer 9

Interpretation Introduction

(b)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Answer 10

Interpretation Introduction

(c)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Answer 11

Interpretation Introduction

(c)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Answer 12

Interpretation Introduction

(d)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Answer 13

Interpretation Introduction

(d)

Interpretation: The given groups are to be arranged in order of their decreasing priority.

Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Draw the mirror image of each compound. Label each...Ch. 5 - Prob. 5.4P Ch. 5 - A molecule is achiral if it has a plane of...Ch. 5 - Problem 5.6 Locate the stereogenic centers in each...Ch. 5 - The facts in section 5.4A can be used to locate...Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

Solution Summary: The author explains that the groups are prioritized on the basis of atomic number of their atoms.

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